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Synthesis and electrochemical properties of LiNi0.8Co 0.2O2 nanopowders for lithium ion battery applications

Jouybari, Y.H ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1016/j.jpowsour.2010.06.097
  3. Abstract:
  4. Nitrates of lithium, cobalt and nickel are utilized to synthesize LiNi 0.8Co0.2O2 cathode material through sol-gel technique. Various synthesis parameters such as calcination time and temperature as well as chelating agent are studied to determine the optimized condition for material processing. Using TG/DTA techniques, the optimized calcination temperatures are selected. Different characterization techniques such as ICP, XRD and TEM are employed to characterize the chemical composition, crystal structure, size and morphology of the powders. Micron and nano-sized powders are produced using citric/oxalic and TEA as chelating agent, respectively. Selected powders are used as cathode material to assemble batteries. Charge-discharge testing of these batteries show that the highest discharge capacity is 173 mAh g-1 at a constant current of 0.1 mA cm-2, between 3.0 and 4.2 V. This is obtained in a battery assembled with the nanopowder produced by TEA as chelating agent
  5. Keywords:
  6. Cathode materials ; Lithium ion batteries ; Nano-sized lithium-nickle-cobalt oxide ; Sol-gel method ; Calcination temperature ; Calcination time ; Characterization techniques ; Charge-discharge ; Chelating agent ; Chemical compositions ; Constant current ; Discharge capacities ; Lithium-ion battery ; Material processing ; Nano powders ; Nano-sized ; Nano-sized powder ; Optimized conditions ; Sol-gel methods ; Sol-gel technique ; Synthesis parameters ; TEM ; XRD ; Calcination ; Cathodes ; Cobalt ; Crystal structure ; Electrochemical properties ; Gels ; Ions ; Lithium ; Lithium alloys ; Lithium compounds ; Nanostructured materials ; Optimization ; Powders ; Sol-gel process ; Sol-gels ; Sols ; Chelation
  7. Source: Journal of Power Sources ; Volume 196, Issue 1 , 2011 , Pages 337-342 ; 03787753 (ISSN)
  8. URL: http://www.sciencedirect.com/science/article/pii/S0378775310010840