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chelating-agent
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Synthesis of bridged bithiazoles
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 19, Issue 2 , 2000 , Pages 65-66 ; 10219986 (ISSN) ; Sharif University of Technology
2000
Abstract
Bridged bithiazoles (5,5′-ethylene-4,4′-bithiazoles) are synthesized as a good chelating agent
The Effect of Metal Ion Chelation on Formation of Perovskite Versus Perovskite-Related Compounds and The Study of Their Photocatalytic Activity
, M.Sc. Thesis Sharif University of Technology ; Ghanbari, Bahram (Supervisor)
Abstract
In this study, effect of chelate ligands containing carboxylic, phenolic, and amine functional groups on the synthesis of related-perovskite Ca2Fe2O5 versus perovskite CaFeO3 structures have been investigated. Herein, the application of chelating-agent method, e.g. EDTA, Citric Acid, NTA, malonic acid, maleic acid, catechol, acetylaceton, p-tert-butycatechol, aminophenolic derivative ligand, and 2-hydroxyiminodiacetic acid, in comparison to co-precipitation method was also undertaken. The crystalline structure of the obtained perovskites were compared with those of co-participation method in solid state. Experimentally, it was found that the related XRD bands for CaFeO3 were appeared in the...
Comments on the " A comparative study of chelating and cationic ion exchange resins for the removal of palladium (II) complexes from acidic chloride media"
, Article Journal of Hazardous Materials ; Volume 229-230 , 2012 , Pages 461-462 ; 03043894 (ISSN) ; Khanchi, A. R ; Outokesh, M ; Tayebi, A ; Sharif University of TechnologyComparison of oxygen permeation through some perovskite membranes synthesized with EDTNAD
, Article Reaction Kinetics, Mechanisms and Catalysis ; Volume 100, Issue 2 , August , 2010 , Pages 459-469 ; 18785190 (ISSN) ; Nazari, K ; Seyed Matin, N ; Safekordi, A. A ; Ghanbari, B ; Zarrinpashne, S ; Ahmadi, R ; Sharif University of Technology
Abstract
Three dense membranes of types SrCo0.8Fe0.2O 3-δ (SCF(82)), La0.6Sr0.4Co 0.8Fe0.2O3-δ (LSCF(6482)) and La 0.8Sr0.2Co0.6Fe0.4O 3-δ (LSCF(8264)) perovskites were prepared by complexation applying a chelating agent, ethylene diamine N,N,N′,N′-tetra-N- acetyl-diamine (EDTNAD). The oxygen permeation flux through the perovskite membranes was measured as a function of temperature within 1,073-1,223 K as well as the oxygen partial pressure of 0.1-1.0 bar. The oxygen permeation fluxes for the membranes, SCF(82), LSCF(6482), LSCF(8264) with the thickness of 0.85 mm were observed as 9.2×10-7 (mol/cm2 s), 1.7×10-7 (mol/cm2 s), and 1.0×10-7 (mol/cm2 s) in these cases at 1,153 K. The results indicated the...
Sol-gel synthesis of Mn1.5Co1.5O4 spinel nano powders for coating applications
, Article Materials Research Bulletin ; Volume 102 , 2018 , Pages 180-185 ; 00255408 (ISSN) ; Dayaghi, A. M ; Askari, M ; Gannon, P. E ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
Mn1.5Co1.5O4 oxide spinels are widely used as protective coatings for stainless steel interconnects within planar solid oxide fuel cell stacks. Containing both cubic and tetragonal crystalline phases, these Mn/Co oxide spinels exhibit favorable thermal stability and electronic conductivity for the SOFC interconnect application. Slurry-based coating applications of Mn/Co oxides require precursor powders, which can benefit from being nano-structured. In this study, the sol-gel synthesis of nanocrystalline Mn1.5Co1.5O4 spinel is investigated. The decomposition of sol-gel precursors, as well as the crystalline phase structures and microstructures of the product Mn1.5Co1.5O4 are characterized by...
Synthesis and characterization of LiNiO2 nanopowder with various chelating agents
, Article Journal of Nanomaterials ; Volume 2010 , March , 2010 ; 16874110 (ISSN) ; Asgari, S ; Sharif University of Technology
2010
Abstract
LiNiO2 powders were synthesized with acrylic acid, citric acid, oxalic acid, and triethanolamine (TEA) as a chelating agent. Crystallized LiNiO2 was synthesized in air at a calcinations temperature of 500 °C for 12 hours, when the molar ratio of chelating agents to total metal ion (RPM) was 1.0. The TEA-assisted method had the highest intensity ratio of (003)/(104) peaks of X-ray diffraction (XRD) spectrum. The transmission electron microscopy (TEM) analysis indicates that the sample prepared with triethanolamine obtained the smallest particle size with average particle size of only 12nm. The results indicate that chelating agents have an important role in the intensity ratio of (003)/(104)...
Immersed single-drop microextraction-electrothermal vaporization atomic absorption spectroscopy for the trace determination of mercury in water samples
, Article Journal of Hazardous Materials ; Volume 165, Issue 1-3 , 2009 , Pages 353-358 ; 03043894 (ISSN) ; Naderi, M ; Sharif University of Technology
2009
Synthesis and electrochemical properties of LiNi0.8Co 0.2O2 nanopowders for lithium ion battery applications
, Article Journal of Power Sources ; Volume 196, Issue 1 , 2011 , Pages 337-342 ; 03787753 (ISSN) ; Asgari, S ; Sharif University of Technology
Abstract
Nitrates of lithium, cobalt and nickel are utilized to synthesize LiNi 0.8Co0.2O2 cathode material through sol-gel technique. Various synthesis parameters such as calcination time and temperature as well as chelating agent are studied to determine the optimized condition for material processing. Using TG/DTA techniques, the optimized calcination temperatures are selected. Different characterization techniques such as ICP, XRD and TEM are employed to characterize the chemical composition, crystal structure, size and morphology of the powders. Micron and nano-sized powders are produced using citric/oxalic and TEA as chelating agent, respectively. Selected powders are used as cathode material...
Characterization of LiCoO2 nanopowders produced by sol-gel processing
, Article Journal of Nanomaterials ; Volume 2010 , 2010 ; 16874110 (ISSN) ; Soltanmohammad, S ; Sharif University of Technology
2010
Abstract
LiCoO2 nanopowders, one of the most important cathode materials for lithium-ion batteries, were synthesized via a modified sol-gel process assisted with triethanolamine (TEA) as a complexing agent. The influence of three different chelating agents including acrylic acid, citric acid, and oxalic acid on the size and morphology of particles was investigated. Structure and morphology of the synthesized powders were characterized by thermogravimetric/ differential thermal analyses (TG/DTA), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Results indicate that the powder processed with TEA and calcinated at 800 °C had an excellent hexagonal ordering of α-NaFeO2 -type (space...
An improved synthesis and preliminary biodistribution study of a technetium-99m-labeled2-amino-2-deoxy(thioacetyl)-D-glucose complex ([ 99mTc]-TA-DG) as a tumor imaging agent
, Article Iranian Journal of Nuclear Medicine ; Volume 15, Issue 28 , 2007 , Pages 43-48 ; 16812824 (ISSN) ; Sadeghzadeh, M ; Charkhlooie, G ; Haghir Ebrahimabadi, K ; Saeedi, M. R ; Sharif University of Technology
2007
Abstract
Introduction: This report describes the synthesis of 2-Amino-2-deoxy(S- benzoylthioacetyl)-D-glucose (S-Bz-TA-DG), radiolabeled with [ 99mTc(CO)3(OH2)3]+ complex with a procedure including deprotection of the benzoyl group, characterization by HPLC using a C18 reverse phase column and preliminary biodistribution study in normal mice. Methods: [99mTc(CO) 3(H2O)3]+ complex was used to label TA-DG with 99mTc. This complex was prepared using up to 46 mCi of Na99mTcO4 in 1mL saline. The radiochemical purity (>95%) was determined by TLC in normal saline solution as the mobile phase. Radio-HPLC analysis of [99mTc]-(TA-DG) at pH=9.5-10, revealed that labeling with 99mTc resulted in the formation of...
Design, modeling and optimization of a piezoelectric pressure sensor based on thin-film PZT diaphragm contain of nanocrystalline powders
, Article 2009 6th International Symposium on Mechatronics and its Applications, ISMA 2009, Sharjah, 23 March 2009 through 26 March 2009 ; 2009 ; 9781424434817 (ISBN) ; Sheikhi, M. H ; Torkian, S ; Barzegar, A ; Masumi, E ; Mohammadi, S ; Sharif University of Technology
2009
Abstract
In this paper fabrication of a 0-3 ceramic/ceramic composite lead zirconate titanate, Pb(Zr0.52Ti0.48)O3 thin film has been presented and then a pressure sensor based on multilayer thin-film PZT diaphragm contain of Lead Zirconate Titanate nanocrystalline powders was designed, modeled and optimized. This multilayer diaphragm in general acts as sensor or actuator. ANSYS was used for simulation of diaphragm. Dynamics characteristics of this multilayer diaphragm have been investigated. By this simulation the effective parameters of the multilayer PZT diaphragm for improving the performance of a pressure sensor in different ranges of pressure are optimized. The optimized thickness ratio of PZT...
Recent advances in the design and applications of amyloid-β peptide aggregation inhibitors for Alzheimer’s disease therapy
, Article Biophysical Reviews ; Volume 11, Issue 6 , 2019 , Pages 901-925 ; 18672450 (ISSN) ; Khazaei, S ; Behnammanesh, H ; Shamloo, A ; Erfani, M ; Beiki, D ; Bavi, O ; Sharif University of Technology
Springer
2019
Abstract
Alzheimer’s disease (AD) is an irreversible neurological disorder that progresses gradually and can cause severe cognitive and behavioral impairments. This disease is currently considered a social and economic incurable issue due to its complicated and multifactorial characteristics. Despite decades of extensive research, we still lack definitive AD diagnostic and effective therapeutic tools. Consequently, one of the most challenging subjects in modern medicine is the need for the development of new strategies for the treatment of AD. A large body of evidence indicates that amyloid-β (Aβ) peptide fibrillation plays a key role in the onset and progression of AD. Recent studies have reported...