Sharif Digital Repository

The Cd (3 wt%)-doped ZnTe nanoparticles with average size of 5 nm and band gap energy of 3.15 eV were synthesized by sol-gel method. The optical properties (such as band gap energy) and the size distribution of the nanoparticles have been investigated by using UV-Vis spectroscopy and transmission electron microscopy, respectively. Then, thermoluminescence property of the nanoparticles exposed to various doses of gamma radiation of Cs137 has been studied. The thermoluminescence glow peak of the nanoparticles showed a displacement from 290 to 230°C by increasing the dose of gamma radiation from 7.5 to 67.5 mSv. The thermoluminescence intensity of the synthesized Cd-doped ZnTe nanoparticles... 

In this work the titanium dioxide powder was prepared by the optimized and simple Sol-Gel method and then characterized. The gelling pH was set to values of 3 (TiO2-A), 7 (TiO2-N) and 9 (TiO2-B) to observe the effect on the properties of the material. In these three cases nanoparticulated materials were obtained with particle sizes between 10nm and 20nm. The larger surface areas were obtained at pH 3, which is several times larger than the others. Furthermore, with the gelling condition pH 3, it was possible to synthesize pure anatase phase titania. Some preliminary results on the test of the photocatalytic activity of the synthesized materials in the reduction of nitric oxide are presented.... 

Zeolite-based photocatalysts were prepared by the sol-gel and deposition methods. The photocatalysts were characterised by X-ray diffraction, nitrogen adsorption-desorption isotherms, FTIR spectroscopy, scanning electron microscopy and energy-dispersive X-ray spectrometry. The activity of the prepared photocatalysts was evaluated by the UV-induced degradation of acid blue 92, a textile dye in common use. The effect of various parameters, such as catalyst concentration, initial dye concentration, thiosulphate concentration and pH, on the rate and efficiency of the photocatalytic degradation of acid blue 92 was investigated. The results showed that each parameter influenced the degradation... 

Zeolite-based Ag/AgBr and Ag/AgBr/TiO2 photocatalysts were prepared by sol–gel and deposition methods and were characterized. Their photocatalytic activities were evaluated by inactivation of Escherichia (E.) coli and the photodegradation of Acid Blue 92 and potassium permanganate. The composites containing Ag/AgBr showed the antibacterial activity in the dark by releasing Ag+ ions into the medium. The results for inactivation of E. coli indicated that Ag/AgBr/TiO2 modified photocatalyst had better antibacterial activity than Ag/AgBr/zeolite, while zeolite and TiO2/zeolite did not show any antibacterial activity under visible light and dark conditions. Photodecolarization rate was affected... 

The application of bioglass coatings on metallic implants provides link between bone and materials and prevents corrosion of metallic implants in body fluid. Therefore, in this research, 45S5 bioglass-silica coatings on 316L stainless steel were prepared by the sol-gel method and were characterized by different techniques. According to X-ray diffraction (XRD) results, by sintering 45S5 bioglass at 600 C for 5 h, coatings containing both amorphous phase and Na2Ca2Si3O9 crystalline phase were obtained. Scanning electron microscopy (SEM) results showed that coatings prepared via appropriate sol aging and substrate preparations are crack-free. Potentiodynamic polarization tests in simulated body... 

In the present study, bioceramic composites based hydroxyapatite (HAp) reinforced with carbon nanotubes (CNTs) was synthesized via sol-gel technique. The dried gels were individually heated at a rate of 5°C/min up to 600°C for 2 h in a muffle furnace in order to obtain HAp-MWCNTs mixed powder. Composites were characterized by XRD, FT-IR, SEM, TEM/SAED/EDX and Raman spectroscopy techniques. Results showed the synthesis of HAp particles in the MWCNTs sol which was prepared in advance, leads to an excellent dispersion of MWCNTs in HAp matrix. Apparent average size of crystallites increased by increasing the percentage of MWCNTs. The average crystallite size of samples (at 600°C), estimated by... 

The dynamical scattered light intensity and multiplicative cascade model was employed to characterize the anisotropic charged colloidal particles suspension during the so-called Sol-Gel transition. Generally we looked for finding a criterion to distinguish the properties of Sol and Gel states systematically. The probability density function (PDF) of the light scattering intensity shows an obvious change with proceeding of the sample aging process (during of gelation state). Our results confirmed that in the so-called Sol state, the value of non-Gaussian parameter, kW, as a function of time is larger than that of for weak-Gel or in coexistence Sol-Gel state. The number of cascades in the... 

In this researchC-N-Y tri-doped TiO2 nanopowders were synthesized by the sol-gel method. TheC- N-Y Ti O2 photo-catalyst was prepared using hexamine and yttrium nitrate Hexahydrate as the dopant precursors. Methyl-orange (MO) was used to study the photocatalytic performance of the doped Ti O2 underUVirradiation. The synthesized samples were characterized by x-ray diffraction, x-ray photoelectron spectroscopy,UV-vis diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy, Transmission electron microscopy, Photoluminescence and Field emission scanning electron microscopy. The tri-doped sample with8%N, 0.4% Y and 1.5%Cexhibited enhanced photocatalytic efficiencies. After 100... 

Li2FeSiO4 was synthesized through Sol–Gel method and the effect of calcination temperature, time and chelating agent concentration were investigated. Appropriate calcination temperature above 550 °C was determined by TG/DTA analysis. Afterward, the dried gel powder was calcined at each temperature of 650 °C, 700 °C and 750 °C for 1, 2 and 3 h. XRD studies illustrated the most appropriate calcination temperature of 700 °C for 1 h. To compare the effect of chelating agent concentration, citric acid with molar ratio of 1/3, 2/3 and 1 were used which 1/3 was determined as the best concentration. FE-SEM observation showed that mean grain is size lower than 100 nm. By using this material, a three... 

Nanostructured aluminum titanate (AT) was synthesized by the sol-gel method. The calcination temperature was selected as a processing variable to obtain different phase ratios of AT and its parent phases i.e. TiO2 and Al2O3. The main aim behind the present work was to cast light on the photocatalytic performance of AT-based nanocomposites and evaluate their capability to serve as a novel photocatalyst. X-ray diffraction (XRD) analysis and field-emission scanning electron microscopy (FE-SEM) studies were conducted to evaluate the microstructure-sensitive properties of the synthesized powders. Diffuse reflectance spectroscopy (DRS) and the methylene blue degradation test were carried out to... 

Sol-gel based solid-phase microextraction fibers supported by a stainless steel wire were fabricated and employed for GC-MS determination of oxadiargyl in real samples. The fibers were based on four compounds with different polarity: polar and non-polar (end-capped) poly(dimethylsiloxane) (PDMS), polyethylene glycol (PEG), and poly(ethylene-propyleneglycol)-monobutyl ether (UCON). For this purpose, the surface of the stainless steel was initially modified by (3-mercaptopropyl) trimethoxysilane. The results of the modification procedure were evaluated by cyclic voltammetry and energy dispersive X-ray (EDX) spectroscopy. After the modification, four different sol-gel based SPME fibers with... 

In this research, a modified, cost effective sol-gel procedure applied to synthesize BaTiO3 nanoparticles. XRD and electron microscopy (SEM and TEM) applied for microstructural characterization of powders. The obtained results showed that the type of precursors, their ratio and the hydrolysis conditions had a great effect on time, temperature and therefore the costs of the synthesis process. By selection, utilization of optimized precursor's type, hydrolysis conditions, fine cubic BaTiO3 nanoparticles were synthesized at low temperature and in short time span (1 h calcination at 800 °C). The proposed procedure seems to be more preferable for mass production. The result indicated that the... 

In this paper, the combination of dry reforming and partial oxidation of methane on nickel catalysts supported on mesoporous MgAl2O4 was investigated. The support was prepared by a facile sol-gel route using propylene oxide as a gelation agent. The characterizations of the catalysts were performed by BET, XRD, TPR, TPO, TPH, UV–vis, CO-dispersion, SEM and TEM techniques. In addition, the effects of nickel content, reaction and reduction temperatures, feed ratio and the GHSV value on the physicochemical and catalytic properties were studied. The results revealed that the nickel content had an optimum value of 7.5 wt% and the catalyst with this content of nickel exhibited the highest activity.... 

As a refractory ceramic, the thermal instability of aluminium titanate (AT or Al2TiO5) has been in the crosshairs of research works in recent years. The studies have indicated that different parameters such as atmosphere, grain size, additives, oxygen pressure, and synthesis method can bilaterally affect the thermal decomposition of AT ceramic and resultant physicomechanical properties. In the present study, the AT nanostructure was synthesized by a citrate sol-gel method and influence of nanostructuring nature on its thermal instability and reaction pathway was explored in some details. It was shown that the reduction of grain size down to 30 nm can destabilize AT, so that the reaction... 

In this work, we compared formation and properties of heat-treated Ag nanoparticles in silica matrix synthesized by RF- reactive magnetron cosputtering and sol-gel methods separately. The sol-gel and sputtered films were annealed at different temperatures in air and in a reduced environment, respectively. The optical UV-visible Spectrophotometry have shown that the absorption peak appears at 456 and 400 nm wavelength indicating formation of silver nanoparticles in SiO2 matrix for both the sol -gel and sputtering methods at 100 and 800 °C, respectively. XPS measurements showed that the metallic Ag0 nanoparticles can be obtained from both the techniques at these temperatures. According to XPS... 

Nanocrystalline and nanostructured TiO2-Cr2O3 thin films and powders were prepared by a facile and straightforward aqueous particulate sol-gel route at low temperature of 400°C. The prepared sols showed a narrow particle size distribution with hydrodynamic diameter in the range of 17.7 nm to 19.0 nm. Moreover, the sols were stable over 4 months, with constant zeta potential measured during this period. The effect of the Cr:Ti molar ratio on the crystallization behavior of the products was studied. X-ray diffraction (XRD) analysis revealed that the powders crystallized at low temperature of 400°C, containing anatase-TiO2, rutile-TiO2, and Cr2O3 phases, depending on the annealing temperature... 

A molecularly imprinted xerogel (MIX) for fentanyl was successfully prepared on the inner surface of a copper tube by sol-gel technology. Primarily, the tube was treated by self-assembly monolayers of 3-(mercaptopropyl) trimethoxysilane and then [3-(2,3-epoxypropoxy)-propyl]-trimethoxysilane was employed as a precursor for imprinting the template molecule in acidic conditions. During the sol-gel process influential parameters including volume and concentration of fentanyl were carefully investigated to obtain the most efficient and appropriate xerogel. In parallel, a non-imprinted xerogel (NIX) was synthesized in the absence of fentanyl. The extraction efficiencies achieved from MIX and NIX,... 

TiO 2 and Pd-modified TiO 2 photocatalysts were prepared by sol-gel method. X-ray diffraction (XRD) data showed that the presence of Pd in TiO 2 catalyst decreases the crystalline size of TiO 2 and stabilizes anatase phase. The study of the photocatalytic activity of the films via Linear Sweep Voltametry (LSV) plots and antibacterial test against Escherichia coli ATCC 25922-a gram negative bacterium-showed that Pd increases the photocatalytic activity of the coatings. Besides, the sequence of layer deposition (TiO 2 and Pd-modified TiO 2) influences the photocatalytic properties. In other words, more photocatalytic activity is obtained when Pd-modified layer is deposited first  

Nanocrystalline Y3-xMMxFe5O12 powders (MM denotes Misch-metal, x = 0.0, 0.25, 0.5, 0.75, and 1.0) were synthesized by a sol-gel combustion method. Magnetic properties and crystalline structures were investigated using X-ray diffraction (XRD), a vibrating sample magnetometer (VSM), and a scanning electron microscope. The XRD patterns showed that the single-phase garnet of Y3-xMMxFe5O12 was formed at x values ≤ 1.0. The saturation magnetization of powders increased with decreasing MM content and reached the maximum value at Y3 Fe5O12. The crystallite size of powders calcined at 800°C for 3 h was in the range of 38-53 nm. © 2008 American Ceramic Society  

High specific surface area (SSA) nanocrystalline powders and dip-coated TiO2 films have been prepared by particulate sol-gel route aided with polymeric fugitive agents (PFA), namely trehalose dihydrate (THD), polyethylene glycol (PEG6000) and hydroxypropyl cellulose (HPC). Powders obtained without PFA, heat-treated at 160 °C show a SSA of 181 m2/g, a value that could be increased up to 271 and 223 m2/g for samples heat-treated at 300 °C when PEG6000 and HPC were used, respectively, whereas SSA of 201 m2/g were achieved by using THD and subsequence heat-treating at 500 °C. Such surface area is one of the highest reported in the literature under these conditions. Crystallite sizes vary from 1...