Sharif Digital Repository

The interfacial properties of crude oil are highly complex and are not yet well understood. This study aimed to evaluate the effect of temperature (30-80°C) and pressure (3.44-27.58MPa) on the dynamic interfacial tension (IFT) of crude oil/aqueous solutions consisting of 15000ppm of salt containing different chloride anions, e.g. NaCl, KCl, MgCl2, and CaCl2. To reach this goal, several parameters, such as dynamic and equilibrium IFT, adsorption time, diffusivity of resin, and asphaltene as surface-active agents from bulk of crude oil towards fluid/fluid interface and surface excess concentration of them at the interface, were compared as a function of temperature, pressure, and ion type. The... 

The interfacial properties of crude oil are highly complex and are not yet well understood. This study aimed to evaluate the effect of temperature (30–80 °C) and pressure (3.44–27.58 MPa) on the dynamic interfacial tension (IFT) of crude oil/aqueous solutions consisting of 15 000 ppm of salt containing different chloride anions, e.g. NaCl, KCl, MgCl2, and CaCl2. To reach this goal, several parameters, such as dynamic and equilibrium IFT, adsorption time, diffusivity of resin, and asphaltene as surface-active agents from bulk of crude oil towards fluid/fluid interface and surface excess concentration of them at the interface, were compared as a function of temperature, pressure, and ion type.... 

Asphaltene precipitation and deposition is a serious issue in all facets of petroleum production and processing. Despite the numerous experimental efforts concerning asphaltenes, the effect of temperature on asphaltene precipitation and aggregation in live oils remains an elusive and controversial subject in the available literature. In this work, a series of high pressure-high temperature depressurization experiments were designed to assess the effect of temperature on asphaltene precipitation and aggregation in light live oils. Asphaltene related experiments were performed using a high pressure microscope and high pressure-high temperature filtration setup on a light live oil with a low... 

Catalytic partial oxidation of methane in short residence time rhodium coated monolithic reactors offers an attractive route for syngas production. The plug flow and boundary layer flow approximations are considered as computationally efficient substitutes for the full Navier-Stokes model of the reactor while including detailed heterogeneous and homogeneous chemistry. The one dimensional plug flow model has trivial computational demands but only a limited range of application. The boundary layer model provides an excellent, computationally manageable substitute for the full Navier-Stokes model over a wide range of operating conditions. Using the 38-step elementary surface reaction mechanism... 

An approach composed of the thermodynamics-based dislocation model and the Taylor theory is used to investigate the evolution of microstructure and flow stress during high-pressure torsion (HPT). The incremental temperature rise is considered through the modelling of HPT. The temperature can affect the annihilation of dislocations and thus the dislocation density. The model predicts the dislocation density, sub-grain size and flow stress during HPT. The modelling results are compared with the experimental data and the modelling results without considering the incremental temperature rise. A remarkable agreement is observed between the modelling results with considering the temperature rise... 

The paper presents a numerical finite difference model of self-boring pressuremeter test (SBPM) using FLAC software. Different cavity expansion theories in sand have been compared to the results of numerical analyses carried out in this study. Limit pressure is believed to be used as a key parameter for the estimation of soil parameters from pressuremeter tests. In practice, SBPM tests are conducted up to 10–15% cavity strains, and the strain level associated with the limit pressure state is not reached. Therefore, determination of limit pressure usually needs extrapolation. In this paper, the authors suggest to use cavity pressure at 10% strain (P10) for the interpretation of in situ... 

Abstract: Well testing is one of the important methods to provide information about the reservoir heterogeneity and boundary limits by analyzing reservoir dynamic responses. Despite the significance of well testing data, misinterpreted data can lead us to a wrong reservoir performance prediction. In this study, we focus on cases ignoring the adjacent well’s production history, which may lead to misinterpretation. The analysis was conducted on both homogeneous and naturally fractured reservoirs in infinite-acting and finite-acting conditions. The model includes two wells: one is “tested well” and the other is “adjacent one.” By studying different scenarios and focusing on derivative plots, it... 

The effects of fluorine doping on the electronic structure of LaO1−xFxFeAs superconductor have been investigated by ab initio density functional theory using pseudopotential quantum espresso code. Firstly, we have studied the role of fluorine doping on the electronic structure of LaO1−xFxFeAs by calculation of band structure, density of states, and Fermi surfaces at various doping levels x = 0.00, 0.25, and 0.50. The lattice parameters and ionic position have been determined by optimizing crystal structure. Our results show that doping decreases cell volume similar to mechanical pressure and shifts the bands and states near the Fermi level toward the lower energies. According to the Fermi... 

In this study, crosslinked and non-crosslinked carboxymethylcellulose (CMC) membranes were prepared with different concentrations of polymer. Then, the permeability of pure CO2, N2, and CH4 was measured through these membranes in dry state to investigate the influence of polymer concentration and applied feed pressure on permeability and permselectivity. The permeability of CO2 through membranes was higher than the other gases. A comparison of permeabilities revealed that the permeability of N2, CO2, and CH4 increased on an average of 33, 40 and 20 percent, respectivly, by increasing the feed pressure from 6 to 10... 

Abutments of concrete arch dams are usually crossed by several joints, which may create some rock wedges. Abutment stability analysis and controlling the probable wedge movements is one of the main concerns in the design procedure of arch dams that should be investigated. For decades, the quasi-static method, due to its simple approach, has been used by most of dam designers. In this study, the dynamic method is presented and the obtained time history of sliding safety factors is compared with the quasi-static results. For this purpose, all three components of Kobe (1979) and Imperial Valley (1940) earthquakes are applied to the wedge, simultaneously, and the magnitude and direction of wedge... 

In this study, the effect of moving pressure source and channel parameters on the generated waves in a channel was numerically investigated; draught, angle of attack, and profile shape as parameters of pressure source, and water depth and blockage factor as channel parameters for wave height. Firstly, the chosen Computational Fluid Dynamics (CFD) approach was validated with the experimental data over a range of speeds. Then, the CFD study was conducted for further investigations. It was shown that that by enlarging draught, angle of attack, and beam of the pressure source, the wave height generated would be increased. Channel study showed that it was possible to increase the wave height... 

The present study is undertaken to calculate the rate of change of pressure and residual air mass in die casting for vacuum venting under choked flow conditions. In these calculations, the influence of friction factor, due to roughness and vent air velocity change through the Mach number, has been taken into account. The results show that there is a critical area ratio below which the pressure and vent inlet Mach number increase with time and above which decrease with time. In addition, for an area ratio less than the critical area, the rate of change of residual air mass seems to be more changed at the late stages than at the early stages of the filling time. The picture is reversed for a... 

A new nanocomposite polymer gel is synthesized for reduction of excess water production in petroleum reservoirs at real operating conditions. This new nanocomposite gel contains SiO2 nanoparticles, partially hydrolyzed polyacrylamide (HPAM) and chromium triacetate. High pressure and high temperature tests using porous carbonate core are carried out to evaluate the effects of nanoparticles on the synthesized polymer gel performance. It is shown that the residual resistance factor ratio of water to oil using the synthesized polymer gel nanocomposite in this work is much higher than that of the ordinary polymer gels. The presented results confirm the high performance of the synthesized... 

In this research, effects of excess air ratio and waste gate opening pressure threshold on NOx emission and performance in a turbocharged CNG SI engine are studied experimentally at 13-mode ECE-R49 test cycle. The engine power, boost ratio and charge air temperature are investigated experimentally at the cycle for different waste gate pressure thresholds. A code is developed in MATLAB environment for predicting engine performance and NOx and the results are validated with the research experiments. The effects of excess air ratio on the engine indicated power and specific fuel consumption as well as NOx emission are numerically investigated at WOT by the code. NOx emission of WOT is max at... 

Medium-pore (diameter - 6A) zeolites such as ZSM-5 and silicalite impregnated with Group VIII metals provide selective catalytic pathways for the conversion of synthesis gas to gasoline or olefins. Mössbauer and magnetic studies on these catalysts containing iron or iron plus cobalt are reported. The zeolites were impregnated with metal nitrate solutions, reduced, and carbided to yield showed Fe3+ type spectra. The ZSM-5 (14.7 % Fe) and Silicalite (13.6 % Fe) samples exposed to H2 (450 C) showed an approximate 85% reduction to the metallic state. The carbided ZSM-5 (14.7 % Fe) revealed a spectrum of Hagg carbide (Fe5C2), an active component of the catalyst. The used catalysts showed mixtures...