Sharif Digital Repository

Fire events and the related toxicants such as CO are responsible for many fatalities in the current century. These hazardous events are much more dangerous when they occur in enclosed spaces. In the present study, a theoretical relation is developed for horizontal distribution of CO in a large tunnel fire. Then, the developed criterion is used to study the effect of some rudimentary parameters such as the heat release rate (HRR) of fire and tunnel's aspect ratio (AR) on CO and temperature stratification. Theoretical results of various heat release rates and aspect ratios for horizontal distribution of CO are compared with numerical results using fire dynamics simulator (FDS5.5). It is found... 

Reduction of air pollutants formation from hydrocarbon combustion process requires improvements in combustion systems. The moderate and intense low oxygen dilution (MILD) combustion technique is an opportunity to achieve such a goal. MILD combustion is a combustion regime which can be attained by high temperature preheating and high level dilution. In this paper, the mechanism of CO and CO2 formation for a CH4/H2 fuel mixture is studied under MILD combustion condition of a jet in hot coflow (JHC) burner. This investigation is done using the computational fluid dynamics (CFD) and also zero dimensional well-stirred reactor (WSR) analysis. The RANS equations with modified k-ε equations are... 

Recent progress in developing artificial neural network (ANN) metamodels has paved the way for reliable use of these models in the prediction of air pollutant concentrations in urban atmosphere. However, improvement of prediction performance, proper selection of input parameters and model architecture, and quantification of model uncertainties remain key challenges to their practical use. This study has three main objectives: to select an ensemble of input parameters for ANN metamodels consisting of meteorological variables that are predictable by conventional weather forecast models and variables that properly describe the complex nature of pollutant source conditions in a major city, to... 

Polyaniline fiber (PANI) was synthesized by chemical interfacial method and doped with para toluene sulfonic acid (PTSA) through a sequential doping-dedoping-redoping process resulting in PANI-PTSA. The doped material was utilized to fabricate Vulcan-polyaniline composite of C-PANI-PTSA. Next, through reduction, Pt particles were deposited on to this composite to produce a Pt/C-PANI-PTSA electrocatalyst. To investigate the PANI-PTSA interaction with the carbon support as well as, to consider its effect upon the catalytic activity of Pt/C-PANI-PTSA, electrocatalysts with different ratios of 10, 15, 20, 25 and 30 wt% were synthesized and their activity was compared with the Pt/C (Electrochem).... 

In this paper, a Polymer Electrolyte Membrane (PEM) fuel cell power system including burner, steam reformer, heat exchanger, and water heater has been considered. A PEM fuel cell system is designed to meet the electrical, domestic hot water, heating, and cooling loads of a residential building located in Tehran. Operating conditions of the system with consideration of the electricity cost has been studied. The cost includes social cost of the environmental pollutants (e.g. CO 2, CO and NO). The results show that the maximum energy needs of the building can be met by 12 fuel cell stacks with nominal capacity of 8.5 kW. Annual average electricity cost of thissystem is equal to 0.39 US$/kWh and... 

In this experimental study, a kinetic model has been developed for Fischer-Tropsch synthesis reactions by using sol-gel technique and Fe/Ni/Al 2O 3 as the catalyst (40% Fe/60% Ni/40 wt.%Al 2O 3) in a differential fixed-bed micro reactor assuming no internal or external diffusion. Operating conditions of the reactor were as follows: total pressure 1-12 atm; Temperature 220-260 °C; H 2/CO feed ratio 1.5-2; gas hourly space velocity 2100-7000 cm 3(STP)/h/ g cat and conversions of 6-37% of hydrogen and 7-21% of carbon monoxide. Mass transfer limitations were investigated by changing synthesis gas velocity in reactors which differ in size. Based on the hypothesis that water inhibits the intrinsic... 

Gasification of biomass in supercritical water is a successful technology for hydrogen production especially by using wet biomass. The whole process, from feeding to purification of hydrogen, consists of a lot of equipment, such as pumps, heat exchangers, heaters, reactors, etc. Because the main reactions take place in the gasification reactor, the gasifier is the most important equipment of the process. In this article, a thermodynamic model, including chemical equilibrium in the reactor that is based on Gibbs free energy minimization, is developed to estimate equilibrium composition for gasification of biomass in supercritical water for hydrogen production. For this analysis, we use three... 

A field sampling campaign was implemented to evaluate the variation in air pollutants levels near a highway in Tehran, Iran (Hemmat highway). The field measurements were used to estimate road link-based emission factors for average vehicle fleet. These factors were compared with results of an in tunnel measurement campaign (in Resalat tunnel). Roadside and in-tunnel measurements of carbon monoxide (CO) and size-fractionated particulate matter (PM) were conducted during the field campaign. The concentration gradient diagrams showed exponential decay, which represented a substantial decay, more than 50-80%, in air pollutants level in a distance between 100 and 150meters (m) of the highway. The... 

A gaseous-kerosene/air turbulent nonpremixed flame in a combustion chamber is simulated to investigate the effects of fuel-injector cone-angle on the pollutions of soot nano-particles, carbon monoxide, and carbon dioxide. We use a two-equation soot model in our studying, consider a detailed chemical scheme consisting of 121 species and 2613 elementary reactions, use the flamelet model, employ the presumed-shape probability density functions PDFs, apply the two-equation κ-ε turbulence model with round-jet corrections, and take into account the radiation effects assuming optically-thin flame in our numerical modeling. This research concentrates on investigating the impacts of kerosene injector... 

Background: Exposure-response information about particulate air-pollution constituents is needed to protect sensitive populations. Particulate matter <2.5 mm (PM 2.5) components may induce oxidative stress through reactive-oxygen-species generation, including primary organics from combustion sources and secondary organics from photochemically oxidized volatile organic compounds. We evaluated differences in airway versus systemic inflammatory responses to primary versus secondary organic particle components, particle size fractions, and the potential of particles to induce cellular production of reactive oxygen species. Methods: A total of 60 elderly subjects contributed up to 12 weekly... 

Theoretical study of carbon monoxide adsorption on SixGe4 - x(x = 0-4) nano-clusters has been carried out using advanced hybrid meta density functional method of Truhlar (MPW1B95). MG3 semi-diffuse (MG3S) and correlation consistent valence basis sets with relativistic core potential were employed to improve the results. The agreement of the calculated ionization and dissociation energies with experimental values validates the reported structures of nano-clusters and justifies the use of hybrid meta density functional method. The geometry, adsorption energy, charge distribution, and vibrational frequency of CO adsorption on all possible structures were investigated. The maximum vibrational... 

In this paper, the effects of a baffle plate on flame deflection and its throttling are investigated numerically in a combustor consuming jet propellant JP. We study the plate effects on the resulting soot volume fraction, soot particles diameter, mass fractions of carbon monoxide (CO), carbon dioxide (CO2), and benzene (C6H6). We use a two-equation turbulence model, a PAH-inception two-equation soot model imposing oxidation due to OH agents, a detailed chemical kinetic consisting of 121 species and 2613 elementary reactions, and the flamelet combustion model to perform the current study. We also take into account the turbulence-chemistry interaction using the presumed-shape probability... 

This study mainly aims to investigate the effect of reformer gas (RG) addition on the performance of homogeneous charge compression ignition (HCCI) engines using a multi zone model. The developed model is validated using a wide range of experimental data of a cooperative fuel research engine. Blended fuels of isooctane and n-heptane, known as primary reference fuels, with different octane numbers are used as the main engine fuel. A semi detailed chemical-kinetic mechanism containing 101 species and 594 reactions is used to simulate the combustion of blended fuels. The study is performed with different percentages of RG (0–30%). The results show that RG reduces the rate of some H abstraction... 

The effect of operation variables, such as the H2/CO molar feed ratio, gas hourly space velocity (GHSV), temperature, and pressure, on the catalytic performance of the Co/Mn/TiO2 catalyst prepared at the Research Institute of the Petroleum Industry (RIPI) was investigated, and optimum reactor conditions were obtained to produce the maximum amount of light olefins. The catalyst was prepared by co-precipitation of Co and Mn phases in the presence of commercial TiO2 with maximum selectivity for ethylene and propylene production. It was found that the [H2]/[CO]=2/1, space velocity (GHSV) of 1800 h-1, 280°C temperature and 4 bar pressure were optimum operating conditions for the modified catalyst... 

Kinetic modeling of CO hydrogenation over Fe-Co-Mn catalyst was investigated; a ternary catalyst was prepared using incipient wetness impregnation. The kinetic parameters were determined from experiments carried out in a fixed bed micro-reactor under the following process conditions: T = 523.15-533.15 K, P = 1-10 bar, H2/CO = 1/1-3/1 and space velocity = 4500 h-1. Seventeen rate expressions were derived from five different mechanisms according to Langmuir-Hinshelwood-Hougen-Watson (LHHW) and Eley-Rideal (ER) mechanisms and were tested against the experimental data. Non-linear regression method was used to estimate different kinetic parameters; according to the obtained experimental results... 

(Lanthanum, Cerium)(Iron, Manganese, Cobalt, Palladium)(Oxygen)3- Perovskite catalyst was prepared by the citrate route and deposited on ceramic monoliths via dip coating procedure. The catalyst was applied on a car with XU7 motors and the amount of emission was monitored with vehicle emission test systems in Sapco company. The results were compared with the imported catalyst with noble metals such as palladium, platinum and rhodium by Iran Khodro company based on the Euro III standards. The catalysts were characterized by specific surface area measurements, scanning electron microscopy, X-ray diffraction, line scan and map. In the results, obtained in the home made sample, the amount of... 

A gas-phase heterogeneous kinetics is described over perovskite with formula La0.6Sr0.4Co0.8Fe0.2O3-δ (LSCF) for the oxidative coupling of methane under differential conversion conditions in a microcatalytic fixed-bed reactor. The ethane (C2H6) and carbon oxides (COX) formation and methane conversion rates were obtained as a function of methane and oxygen partial pressure under experimental conditions of: 0.20 < PC H4 < 0.82 atm, 0.04 < PO2 < 0.15 atm, and 1073 < T < 1173 K. The different kinetic models were examined and two Eley-Rideal mechanisms (a and b) were successfully performed to fit the experimental data into the theoretical relations from which two mechanisms having a first step of...