Sharif Digital Repository

In the last two decades, quantum dots nanomaterials have garnered a great deal of scientific interest because of their unique properties. Quantum dots (QDs) are inorganic fluorescent nanocrystals in the size range between 1 and 20 nm. Due to their structural properties, they possess distinctive properties and behave in different way from crystals in macro scale, in many branches of human life. Cadmium telluride quantum dots (CdTe QDs) were labeled with 68Ga radio nuclide for fast in vivo targeting and coincidence imaging of tumors. Using instant paper chromatography, the physicochemical properties of the Cadmium telluride quantum dots labeled with 68Ga NPs (68Ga@ CdTe QDs) were found high... 

A large amount of research in computational mechanics has biased toward atomistic simulations. This trend, on one hand, is due to the increased demand to perform computations in nanoscale and, on the other hand, is due to the rather simple applications of pairwise potentials in modeling the interactions between atoms of a given crystal. The Cauchy–Born (CB) hypothesis has been used effectively to model the behavior of crystals under different loading conditions, in which the comparison with molecular dynamics simulations presents desirable coincidence between the results. A number of research works have been devoted to the validity of CB hypothesis and its application in post-elastic limit.... 

Heterogeneous nanoscale catalyst was successfully synthesized via anchoring of oxoperoxo molybdenum(VI) complex on the chloro-functionalized SBA-15. The mesoporous nanomaterials, MoO3(sal-phz)/SBA-15 (where sal-phz is salicylidene 2-picoloyl hydrazine) were identified by several characterization techniques. MoO3(sal-phz)/SBA-15 and MoO3(sal-phz) were also treated as catalysts in the olefins epoxidation reactions. Both homogenous and heterogeneous catalysts exhibit outstanding activity and selectivity for epoxide with tert-BuOOH in decane as oxidant at 95 °C. In addition, the heterogeneous nanocatalyst was chemically stable and can be efficiently reused for at least six cycles without a... 

Graphitic carbon nitride (g-C3N4) is a metal-free conjugated polymer constructed from two-dimensional sheets with a bandgap energy of 2.7 eV, which makes it an applicable and efficient visible-active photocatalyst for H2 production. In the present study, the basic concepts and principles of photocatalytic water splitting have been discussed, and a guide for the selection of appropriate photocatalysts, focusing on the g-C3N4 nanomaterials, has been proposed. Our approach is mainly concentrated on evaluating two factors, namely the solar-to-hydrogen (STH) conversion and apparent quantum yield (AQY) for different photocatalysts, to provide an in-depth analysis and a framework for solar H2... 

In this paper, thermal buckling and free/forced vibration characteristics of size-dependent composite cylindrical nanoshell reinforced with graphene platelets (GPLs) is presented. Also, the nanoshell is embedded in an elastic pasternak medium, which is obtained by adding a shear layer to the Winkler model. The present nano-resonator is based on a vibrating first order nanoscale cylindrical shell subjected to transverse pressure. The temperature-dependent material properties of piece-wise functionally graded graphene-reinforced composites (FG-GRCs) are assumed to be graded in the thickness direction of a cylindrical nanoshell and are estimated through a nanomechanical model. Also, Halpin–Tsai... 

Despite the promise of hydrogel-based stem cell therapies in orthopedics, a significant need still exists for the development of injectable microenvironments capable of utilizing the regenerative potential of donor cells. Indeed, the quest for biomaterials that can direct stem cells into bone without the need of external factors has been the "Holy Grail" in orthopedic stem cell therapy for decades. To address this challenge, we have utilized a combinatorial approach to screen over 63 nanoengineered hydrogels made from alginate, hyaluronic acid, and two-dimensional nanoclays. Out of these combinations, we have identified a biomaterial that can promote osteogenesis in the absence of... 

Gene proliferation is vital for infectious and genetic diseases diagnosis from a blood sample, even before birth. In addition, DNA sequencing, genetic finger-print analyzing, and genetic mutation detecting can be mentioned as other procedures requiring gene reproduction. Polymerase chain reaction, briefly known as PCR, is a convenient and effective way to accomplish this task; where the DNA containing sample faces three temperature phases alternatively. These phases are known as denaturation, annealing, and elongation/extension which in this study -regarding the type of the primers and the target DNA sequence- are set to occur at 95, 58, and 72 degrees of Celsius. In this study, a PCR device... 

Perovskite solar cells (PSCs) have attracted significant attention due to their excellent efficiency reaching 22.1% in just the past few years. Despite their high efficiency, the limited long-term stability of PSCs has to be overcome. Moisture environments has been recognized as a main degradation pathway of perovskite materials. This review summarizes recent studies about relationship of the stability of PSCs with moisture environment. We also discuss the current standard strategies for enhancing the stability of PSCs by modifying the properties of either the perovskite material itself or its interfaces. © 2018  

We numerically solve the Navier-Stokes equations to study the rarefied gas flow in short micro-and nanoscale channels. The inlet boundary conditions play a critical role in the structure of flow in short channels. Contrary to the classical inlet boundary conditions, which apply uniform velocity and temperature profiles right at the real channel inlet, we apply the same inlet boundary conditions, but at a fictitious position far upstream of the real channel inlet. A constant wall temperature incorporated with suitable temperature jump is applied at the channel walls. Our solutions for both the classical and extended inlet boundary conditions are compared with the results of other available... 

Due to rapid development of process manufacturing, composite materials with porosity have attracted commercial attention in promoting engineering applications. For this regard, in this research wave propagation-thermal characteristics of a size-dependent graphene nanoplatelet-reinforced composite (GNPRC) porous cylindrical nanoshell in thermal environment are investigated. The effects of small scale are analyzed based on nonlocal strain gradient theory (NSGT). The governing equations of the laminated composite cylindrical nanoshell in thermal environment have been evolved using Hamilton’s principle and solved with the assistance of the analytical method. For the first time, wave... 

In this paper, thermal buckling and free/forced vibration characteristics of size-dependent composite cylindrical nanoshell reinforced with graphene platelets (GPLs) is presented. Also, the nanoshell is embedded in an elastic pasternak medium, which is obtained by adding a shear layer to the Winkler model. The present nano-resonator is based on a vibrating first order nanoscale cylindrical shell subjected to transverse pressure. The temperature-dependent material properties of piece-wise functionally graded graphene-reinforced composites (FG-GRCs) are assumed to be graded in the thickness direction of a cylindrical nanoshell and are estimated through a nanomechanical model. Also, Halpin–Tsai... 

Nanodiamond (ND)is an allotrope of carbon nanomaterials which exhibits many outstanding physical, mechanical, thermal, optical and biocompatibility characteristics. Meanwhile, ND particles possess unique spherical shape containing diamond-like structure at the core with graphitic carbon outer shell which intuitively contains many oxygen-containing functional groups at the outer surface. Such superior properties and unique structural morphology of NDs are essentially attractive to develop polymer composites with multifunctional properties. However, despite a long history from the discovery of NDs, which is dated back to the1960s, this nanoparticle has been less explored in the field of... 

This article investigates the influence of porosity on free and forced vibration characteristics of a nanoshell reinforced by graphene platelets (GPL). The material properties of piece-wise graphene-reinforced composites (GPLRCs) are assumed to be graded in the thickness direction of a cylindrical nanoshell and estimated using a nanomechanical model. In addition, because of imperfection of the current structure, three kinds of porosity distributions are considered. The nanostructure is modeled using modified strain gradient theory (MSGT) which is a size-dependent theory with three length scale parameters. The novelty of the current study is to consider the effects of porosity, GPLRC and MSGT... 

Perovskite solar cells (PSCs) have attracted significant attention due to their excellent efficiency reaching 22.1% in just the past few years. Despite their high efficiency, the limited long-term stability of PSCs has to be overcome. Moisture environments has been recognized as a main degradation pathway of perovskite materials. This review summarizes recent studies about relationship of the stability of PSCs with moisture environment. We also discuss the current standard strategies for enhancing the stability of PSCs by modifying the properties of either the perovskite material itself or its interfaces  

Used lubricating oil (ULO) is a heavy mixture of various hydrocarbons and needs to be treated before discharging. Considering ULO nature, it is more favorable to recover lighter hydrocarbon cuts from ULO, which not only improves the whole process economically, but also prevents the emission of hardly decomposable hydrocarbons into the environment. In this research, the potential of pyrolysis method for ULO recovery was studied. Furthermore, graphene nanoplatelets (GNP), γ- Fe2O3 and ZnO nanoparticles were used to improve the kinetics of the process and their impacts on the final product quality were evaluated. Based on the results, adding nanomaterials increased the tendency to produce gas... 

In this study, conductive sodium alginate/polyaniline/graphene (PAG) NGCs were fabricated utilizing a straightforward solution extrusion method. The 4 point-probe test revealed that the addition of PAG has increased the conductivity of the NGCs up to 9.7 × 10−3 S.cm−1. The results also showed a remarkable increase in the Young modulus and SEM images revealed that the suggested process could produce NGCs continuously and uniformly with desirable porosity. The Fourier-transform infrared spectroscopy spectrum proved a good interaction between PAG and the polymeric matrix. Furthermore, the addition of PAG slightly prevented biodegradation of the NGCs. Finally, the cell viability assay confirmed... 

In this research, thermal buckling and forced vibration characteristics of the imperfect composite cylindrical nanoshell reinforced with graphene nanoplatelets (GNP) in thermal environments are presented. Halpin–Tsai nanomechanical model is used to determine the material properties of each layer. The size-dependent effects of GNPRC nanoshell is analyzed using modified couple stress theory. For the first time, in the present study, porous functionally graded multilayer couple stress (FMCS) parameter which changes along the thickness is considered. The novelty of the current study is to consider the effects of porosity, GNPRC, FMCS and thermal environment on the resonance frequencies, thermal... 

In the past few years, laser-assisted methods have greatly influenced biomedical studies due to less invasive ways of treatment and higher precision. New stimuli-responsive drug carriers are still explored by scientists to achieve a better spatiotemporal control of drug carriers by using visible to NIR light instead of phototoxic ultra-violet irradiation. Due to their biocompatibility and high loading capacity of hydrophilic drugs, hydrogels have been used extensively in this area. However, poor cellular uptake and restricted loading of hydrophobic drugs are challenges that should be addressed. In this study, a previously known nanogel system based on chitosan and poly(N-isopropylacrylamide)... 

Molecular structural mechanics is implemented to investigate the vibrational characteristics of defect-free single-layered graphene sheets (SLGSs), which have potential applications as strain sensors. The effect of strain on the fundamental frequencies of the defect-free zigzag and armchair models with clamped-clamped boundary condition is studied. The atomistic modeling results reveal while sensitivities of the strain sensors are not influenced significantly by chirality, they can be slightly increased by decreasing aspect ratios of the sheets. It is further shown that the SLGSs-based strain sensors are more sensitive to the applied stretch than the SWCNTs versions. © 2008 Elsevier Ltd. All... 

Gold nanoparticles are potentially very attractive components for therapeutic delivery since they can be synthesized with any diameter from 1 to 200 nm to carry a payload of therapeutic molecules into a cell without triggering an immune response. Gold nanoparticles must undergo surface transformations before coupling to therapeutic molecules to become eligible for this purpose. It is now more understood that amine groups can bind to gold nanoparticles strongly, which has enabled surface modification of gold nanoparticles with amino acid lysine through its amine group. These lysine capped gold nanoparticles can further be coupled to therapeutic molecules for delivery purposes. In this study...