Sharif Digital Repository

In precipitation hardenable materials, it is desirable to determine the precipitate dissolution temperature for homogenizing the microstructure by controlling the size and distribution of the precipitates. In this research, the influence of various heat treatment and hot deformation conditions on the kinetics of γ ′ dissolution and its morphological evolution in Nimonic 115 was studied. In addition, hot deformation behavior of the material was investigated using hot compression experiments at varying temperature (between 1,050°C and 1,175°C) and strain rates (between 0.01 and 1 s-1) up to a true strain of 0.8. The values obtained for the solvus temperature of γ ′ precipitates by two methods... 

Acidizing of carbonate oil-wet rocks saturated with oil and saline formation water is subjected failure in some cases due to acid-induced damage such as sludge and emulsion formations. This condition may also lead to mineral precipitation, oil film barrier between acid and rock and diversion chemical malfunctions. Therefore, pre-flush process has been proposed as one of the most efficient stage for oil-wells matrix acidizing to reduce these challenges significantly. Besides, the pre-flush stage would result in more clean rock as the reservoir fluids are pushed back from the near wellbore regions, restoring rock wettability to more water wet state, preventing direct acid-oil contact and... 

Hydrolysis kinetics of the lead silicate glass (LSG) with 40 mol% PbO in 0.5 N HNO3 aqueous acid solution was investigated. The surface morphology and the gel layer thickness were studied by scanning electron microscopy (SEM) micrographs. Energy dispersive X-ray spectroscopy (EDS) and inductively coupled plasma spectroscopy (ICP) were used to determine the composition of the gel layer and the aqueous solution, respectively. The silicon content of the dissolution products was determined by using weight-loss data and compositions of the gel layer and the solution. The kinetic parameters were determined using the shrinking-core-model (SCM) for rate controlling step. The activation energy... 

The current study proposes a simple constitutive model that integrates the kinetics of precipitation during static aging and the kinetics of precipitate dissolution during preheating to deformation temperature to predict the hot flow behavior of AA6063 alloy. The model relates the flow behavior of the age-hardenable alloy to the alloy chemistry, thermal history as well as deformation temperature, strain, and strain rate by means of a physically based model. Different aging conditions, including supersaturated solid solution and overaging conditions with different deformation parameters, were assessed. Each part of the model was in good agreement with those of experimental and other model... 

Platinum extraction from spent reforming catalysts in iodine solutions under atmospheric pressure and at temperatures up to 95°C was previously investigated in our group. In this system, platinum is oxidized from the spent catalyst with tri-iodide. In some of the experiments, it was observed that platinum extraction peaked and then decreased. This indicates that a precipitation reaction slowly occurs that removes the dissolved Pt ions from the solution. Power-law rate equation for the Pt extraction to PtI6 2- and the precipitation of the dissolved platinum to PtI 4(s) was implemented to model the experimental Pt extraction data. The activation energies for the platinum dissolution reaction... 

Effects of cooling slope angle and the temperature of molten metal on the globular structure of M2 high speed steel after holding at the semisolid state have been investigated. The globular structure was achieved by pouring the molten metal at 1595 °C on the ceramic cooling slope with the length of 200 mm and the angle of 25°. The globular structure of M2 high speed steel in the form of rolled-annealed and as cast condition after holding at semisolid state has been achieved. The size of globular grains of cooling slope sample was smaller than that of the rolled-annealed and as cast samples. Solid particles of rolled-annealed sample after holding at semisolid state had better roundness... 

Diversion in heterogeneous carbonate reservoirs plays the most important role to the success of acidizing. Without the use of diversion, more acid preferentially flows into the high-permeability region and leaves the low-permeability region underreacted. But a clear understanding of diverting agents, such as polymer-based in-situ-gelled acids, can help uniformly stimulate the near-wellbore region. In this paper, we correct the rheological model that was developed by Ratnakar et al. (2013) according to experimental data from Gomaa and Nasr-El-Din (2010b) by considering shear-rate effect in a two-scale continuum model. It is found that the rheology parameters and shear rate are influential... 

Traditionally, solid-liquid mixing has always been regarded as an empirical technology with many aspects of mixing, dispersing and contacting were related to power draw. One important application of solid-liquid mixing is the preparation of brine from sodium formate. This material has been widely used as a drilling and completion fluid in challenging environments such as the Barents Sea. In this paper, large-eddy simulations of a turbulent flow in a solid-liquid baffled cylindrical mixing vessel with large number of solid particles are performed to obtain insight into the fundamental aspects of a mixing tank. The impeller-induced flow at the blade tip radius is modeled by using the... 

By using the planar laser induced florescence experiment (PLIF), a resorufin (RSRF) dye solution was tested as an oxygen probe. The photoreaction of RSRF dye was investigated and the oxidation process of this fluorescent probe molecule was demonstrated. The effect of the oxygen bubbles on tracing dissolved oxygen was also investigated in this study. Results obtained for this sensitive molecular probe dye are very interesting and verify that such an agent can be used effectively for investigating different interesting phenomena affecting the fluorescence. The temporal and spatial behaviors of the oxidation and fluorescence processes were described in this report. For a delay time of 4500 ms... 

The effect of pulse reverse current (PRC) method on Ni-Mo coatings electroplated from chloride solution was investigated by various plating parameters such as plating duration, the anodic duty cycle, the anodic current density and the cathodic current density. By increasing the anodic duty cycle and anodic current density, the Mo content of coatings reached 68wt.% and 78wt.%, respectively at cathodic current densities of 500 and 300mAcm-2. The Mo content of coatings increases by the preferential dissolution of Ni on the anodic pulse and also by the replenishment of Mo complexes in the diffusion layer near the substrate surface during the anodic pulse. In comparison with the direct current... 

One of the key factors in drug's efficacy is the value of their bioavailability that increases by the reduction of particle size through improvement of dissolution rate. In this study, raloxifene particle size was reduced by Rapid Expansion of Supercritical Solution (RESS). The effect of extraction temperature (40-80 °C), extraction pressure (10-18 MPa) and spray distance (5-10 cm) were investigated on size and particle size distribution of the nanoparticles. Particles were characterized using X-ray diffraction (XRD), Fourier Transform Infrared Analysis (FTIR), Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM) and Dynamic Light Scattering (DLS). The average size of... 

In precipitation hardenable materials, it is desirable to determine the precipitate dissolution temperature for homogenizing the microstructure by controlling the size and distribution of the precipitates. In this research, differential thermal analysis, dilatometry technique, heat treatments followed by microstructure evaluation were used to determine the -γ' dissolution temperature of Nimonic 115. It is assumed that the variation of enthalpy is governed by the changes in y volume fraction and γ concentration with time and temperature, and any contribution of the coarsening of γ' is neglected. The values obtained for the solvus temperature of γ precipitates by the three methods are all in... 

Lead silicate glasses (LSGs) have high gamma-ray attenuation but low chemical durability properties. In this work, LSGs with (55.5-68.5 wt%) PbO content containing ZrO2 and TiO2 additions were produced. The chemical corrosion of various produced LSGs in 0.5 N HNO3 aqueous solution and determination of their gamma-ray attenuation coefficients for 60Co and 137Cs sources were investigated. The weight loss measurements, the SEM micrographs, the EDS analysis of the sample surfaces and the ICP analysis of solution were used to characterize the dissolution process. The effects of PbO content, ZrO2 and TiO2 additives on chemical corrosion, and also the effect of PbO on gamma-ray attenuation... 

Carbon dioxide (CO2) storage in geologic formations is an attractive means of reducing greenhouse gas emissions. The main processes controlling the migration of CO2 in geological formations are related to convective mixing and geochemical reactions. The effects of heterogeneity on these coupled processes have been widely discussed in the literature. Recently, special attention has been devoted to fractured geological formations that can be found in several storage reservoirs. However, existing studies on the effect of fractures on the fate of CO2 neglect the key processes of geochemical reactions. This work aims at addressing this gap. Based on numerical simulations of a hypothetical... 

Abstract: The convection–diffusion process of carbon dioxide (CO2) dissolution in a saline reservoir is investigated to shed light on the effects of the permeability heterogeneity. Using sequential Gaussian simulation method, random permeability fields in two and three-dimension (2D and 3D) structures are generated. Quantitative (average amount of the dissolved CO2 and dissolution flux) and qualitative (pattern of the dissolved CO2 and velocity streamlines) measurements are used to investigate the results. A 3D structure shows a slightly higher dissolution flux than a 2D structure in the homogeneous condition. Results in the random permeability fields in 2D indicates an increase in the... 

In this paper, the dissolution and mobilization of non-aqueous phase liquid (NAPL) blobs in the Surfactant-Enhanced Aquifer Remediation (SEAR) process were upscaled using dynamic pore network modeling (PNM) of three-dimensional and unstructured networks. We considered corner flow and micro-flow mechanisms including snap-off and piston-like movement for two-phase flow. Moreover, NAPL entrapment and remobilization were evaluated using force analysis to develop the capillary desaturation curve (CDC) and predict the onset of remobilization. The corner diffusion mechanism was also applied in the modeling of interphase mass transfer to represent NAPL dissolution as the dominant mass transfer...