Sharif Digital Repository

In this work, a pore-scale analysis of nonaqueous phase liquid (NAPL) flow, transport, dissolution, and mobilization in heterogeneous and homogeneous porous media was presented. First, dissolution processes and distribution of NAPL phase were investigated using micromodel experiments. The tests were conducted at different injection rates in NAPL-saturated porous media using distilled water, surfactant, and nanoparticles-assisted surfactant. Changes in residual NAPL volume and interfacial area were measured using image analysis method to calculate the mass transfer coefficient, k, and the lumped mass transfer rate coefficient, K. Based on the experimental results, empirical Sherwood... 

Uranium conversion process is one of the most important stages in nuclear fuel cycle. The Uranium Conversion Facilities (UFC) of Iran is located in Isfahan. In this plant, the Yellowcake (impure uranium oxide, U3O8) is converted to Uranium hexa-fluoride, UF6. During the process, considerable amounts of uranium-containing liquid waste are generated. This liquid waste was collected in evaporation pools inside the UCF Plant. In the course of time, a thick layer of precipitated salt form in bottom of the pools which are collected and stored in drums inside a building. This solid waste contains uranium at concentration levels much higher than that permitted for land disposal of the waste.... 

Injection of acid into the carbonate rock dissolves the rock, and the porous medium is constantly changing. As a result, the boundaries between the acid and the porous medium, which are in fact the interface between the solid phase and the liquid phase, are constantly changing. Therefore, on the issue of acid injection into carbonate rock, we are facing dynamic boundary conditions. Also, due to the simultaneous solution of transfer and reaction phenomena, modeling acid injection into carbonate rock faces many challenges.In such problems, the ALE method, which is a combination of the best features of the Lagrangian method and the Eulerian method, offers a very precise solution and is used as... 

Reactive flow through porous media is a phenomenon of high importance in various study subjects i.e. groundwater, mining, geology, and petroleum reservoirs. In petroleum engineering, a related topic to this phenomenon is the dissolution of the rock matrix due to acidizing. Near_wellbore carbonate rock acidizing has been used for decades in the petroleum industry to enhance the productivity of the well. Optimal injection rate is a key question in such operations. Various models have been used to simulate reactive flow in porous media many of which are continuum-scale that face significant uncertainty regarding the pore-scale nature of the flow, mass transfer, reaction, and subsequent changes... 

In recent decades, various studies have performed on leaching of sulphide ores in ammoniacal thiosulphate solution for the recovery of precious metals such as gold and silver and significant results have been gained. In this study, the ammonia thiosulfate solution utilized to dissolve copper sulfide concentrate, which contained chalcopyrite. The effect of various parameters such as grain size, thiosulfate and ammonia concentration, solid to liquid ratio, temperature and pH in turbulent leaching process were considered to obtain the optimum conditions in the laboratory scale. The outcomes obtained by chemical analysis were evaluated. The results demonstrate that maximum dissolution (26.72%)... 

Nuclear energy is one of the most important sources of energy from the economical point of view and also in terms of cleanliness and safety. Hence, strategically, uranium is one of the most basic elements of the earth and nowadays, the importance of this element is more marked due to the nuclear industry developement. Therefore, uranium recovery from the wastes generated during nuclear fuel production in Isfahan’s uranium conversion plant- in which yellow cake is converted to uranium hexafluoride- is quite pivotal. In this experimental research, we have to remove Fluoride from waste after dissolution by several methods like precipitation. After that uranium is extracted from the sludge of... 

Silver nanopowder is of great importance for various medical and industrial applications. Due to the significance of the solubility of silver nanoparticles in these applications as well as the high impact of the nanophysical morphology of the powder on their solubility, we prepared nanoparticles with plate morphology by the chemical reduction of silver nitrate in a soluble phase. Then we measure its solubility in a phosphate buffer salt, which greatly resembles the human blood chemically. The size and shape of the resulting nanosilver powder and also the use of non-toxic materials in their synthesis are important factors in the production of nanosilver powder.We confirmed the successful... 

Evaporation is the most important water loss from terminal lakes which can influence the chemistry of lakes. In large lakes, the spatial distributions of meteorological and water quality variables affect the evaporation rates. Therefore, it is crucial to consider such variations in estimating evaporation rates from large lakes. This study aims at developing an evaporation estimation model for saline lakes considering salinity and spatial distribution of variables in/over the lakes and investigating the interaction between meteorological, hydrological and water quality variables in natural saline systems. To accomplish these objectives, first a distributed model was developed for estimating... 

The 2024 aluminum alloy is deformed by two passes of multi-directional forging at room temperature, 180 oC, 250 oC, 320 oC and 380 oC with initial state of solid solution. Microstructure, mechanical properties and the state of precipitates are investigated via optical and scanning electron microscopies, hardness test, shear punch test and differential scanning calorimetry. Fragmentation and distribution of the precipitates are observed after straining at different temperatures. Dynamic precipitation of GPB zones at room temperature and 180 oC are studied by DSC analysis. The increase of both hardness and strength and the formation of shear bands are related to the presence of GPB zones.... 

In the present work,the effect of solidification rate on the electrochemical behavior of copperanodes of Sarcheshmeh copper complex has been studied.Inthis regard, three cylindrical coppers pecimens with different solidificationrates casted into water-cooled metal mold (A specimen), metal mold (B specimen) and sand mold (C specimen). Cylinders for microstructural and electrochemical investigation, alongthickness dividedinto several specimens. To investigate themicrostructure of the specimens, opticalmicroscopyand scanning electron microscopy(SEM)were used. ICP testhasbeen usedforelemental analysis of each specimen; and eventuallytoinvestigate theelectrochemical behavior ofeach of... 

The enormous benefits of hydrometallurgical processes have led to the progressive metals extraction industry. Many studies are carried out on the application of these processes in the copper extraction industry. In this research, the oxygen pressure leaching of chalcopyrite concentrate was studied. Experiments were carried out under conditions of the solid-liquid ratio of 0.1, agitation speed of 750 rpm, and sulfuric acid concentration of 2M in a stainless-steel autoclave system. Central composite design (CCD) was used to design experiments, and three factors of temperature, time, and pressure of oxygen, were selected as design variables. The obtained model for %Cu includes parameters of... 

Mineral scale precipitation and carbonate rock dissolution are among the most important reactions that usually occur during water injection in oil reservoirs. These reactions happen due to incompatibility between formation water and injection water as well as deviation from equilibrium conditions. These reactions must be considered precisely because of the fact that they result in variation of reservoir porosity and permeability which affects recovery factor. In this study, the effect of injection pressure on these variations during single-phase water flooding is examined accurately. Additionally, the changes of ion concentration and the amount of dissolved or precipitated calcite or... 

The leaching process is the first stage in the process of extracting uranium out of the ore. The leaching, based on the used material is divided into two main methods of acidic and alkali leaching. Each of these two techniques have their own pros and cones. It is notable that due to lower costs, and faster kinetics, the acid leaching is the first option of the mines unless the percentage of carbonates (and the other acid-soluble materials) in the ore are too high that makes this process uneconomical because of higher acid consumption. The kinetics of the acid leaching of the uranium depends on various parameters such as acid concentration, the particle size, exposure time and the temperature... 

In this work, the recovery of rhenium from ferromolybdenum furnace outgoing dust in semi industrial scale was conducted. The ferromolybdenum furnace outgoing dust contains rhenium as major part and large amounts of molybdenum plus Iron and copper as impurities. An overall flow sheet, consist of leaching, solvent extraction and precipitation methods, was design to recovery and purification of rhenium. Firstly, ferromolybdenum furnace outgoing dust was subjected to leaching treatment by 10 g/L sulfuric as solvent at 85 C. Secondly, solvent extraction method was employed, using LIX984N 10 %vol, to separate copper from rhenium containing solution. The results of MacCab thiele diagram for... 

In Iran, titanium dioxide is still not produced and imports of titanium dioxide are required by various industries, including dyeing, electrodeposition, plastics and Therefore, according to the Ministry of Industries and Mines objectives, to obtain the technology of extraction Ti and TiO2, a research was carried out on titanomagnetite concentrate, extracted from the minerals of the plancher titanumitent and low-grade kahnoj. In this research, titanium dioxide is produced by sulfate method. Solid state recovery and magnetic separation were used to isolate titanium and iron. The dissolution process was then performed to achieve maximum dissolution. At this stage, the effects of temperature,...