Sharif Digital Repository

Fiber Reinforced Polymer (FRP) tendons are suitable to be used in concrete beams exposed to aggressive environments. This study proceeds the design and it presents the flexural capacity (in relation to the moment-curvature) for composite sections (reinforced with steel bars and pre-stressed FRP) rectangular, T-section which has been bent and broken. The failure is in attending with strain softening, stress hardening of fiber reinforced concrete (FRC) and reinforcing with steel bars and polymer. Using the predicted moment-curvature relationship, a numerical method is used to estimate the load deflection response at sample beams under concentrated and uniform loads. A parametric study will be... 

This thesis cantain two section. In the first section a novel extracting medium based on magnetic molecularly imprinted polymers (MIPs) nanoparticles was synthesized by chemical polymerization for micro-solid phase extraction. In this work, the modified chitosan magnetite nanoparticles (MNP-CS) was synthesized by co-precipitating Fe2+ and Fe3+ in the chitosan solution [1,2]. The characteristic properties of Fe3O4@MIPs nanoparticles were determined using Fourier transform infrared spectrometer. Extraction efficiency of the novel extracting medium was compared with MNP-CS sorbents for the determination of RhB in aqueous samples, via quantification by spectrofluorimetry. The obtained results... 

Ionic polymer metal nanocomposites (IPMNCs) are among the advance materials which have been widely used recently as smart materials. These nanocomposites, which are made of polymeric layers (Nafion) plated by metallic or non-metallic conductive electrodes, show large deformations under low applied voltages. The advance materials like these nanocomposites have resolved the problems of the conventional actuators and helped in producing accurate systems.
Several methods have been used to predict the behavior of IPMNCs which any of them consider some simplifying assumptions. In these materials physical phenomena happen at the molecular scale and deformations observed at the large scale.... 

In this thesis, we investigate the effects of topological constraints in catenanes composed of interlinked ring polymers on their size in a good solvent as well as on the location of their θ-point when the solvent quality is worsened. We mainly focus on poly[n]catenanes consisting of n ring polymers each of length m interlocked in a linear fashion. We study the scaling of the poly[n]catenane’s radius of gyration assuming that R ~ m^μ n^ν with µ = 16/25 and ν = 3/5 in a good solvent, with these values of µ and ν obtained by means of a Flory-like theory and further confirmed by numerical simulations. We show that individual rings within catenanes feature a surplus swelling due to the presence... 

This paper aims at investigating the seismic behavior of strengthened reinforced concrete (RC) shear walls using a 3D finite element analysis. A series of four different configurations of carbon fiber reinforced polymer (CFRP) composites, four different schemes of steel elements and two different schemes of concrete jacket are utilized to compare the two methods of retrofitting RC shear walls with similar dimensions and reinforcement ratios. Nonlinear simulations of the RC shear walls are conducted under the action of lateral cyclic loading in ABAQUS Explicit software. In addition, the numerical modeling for RC walls strengthened by CFRP composites as well as steel elements are validated... 

Recently, to improve the dynamic behavior of Reinforced Concrete (RC) slabs under impact load, the methods of externally bonding Glass Fiber Reinforced Polymer (GFRP) sheets to slab and internally reinforcing concrete by steel fibers have been proposed. Nevertheless, it is required to investigate the comparison between these two methods on response of RC slabs under impact loads. In this study, the influence of volume fraction of steel fibers, the number of GFRP sheet layers (one or two) and the arrangement of GFRP sheets (covering the whole or parts of surface), are examined. Performance of fourteen mm concrete slabs including one plain slab, one steel RC slab, three steel RC slabs... 

Previous researches has established that retrofitting RC (reinforced concrete) columns with FRP (fiber reinforced polymer) jackets is an effective means of providing external confinement to the column cross section. In an effort to evaluate FRP jacketing technology, this study focused on the confinement effectiveness of FRP jackets for rectangular building-type RC columns. Variables investigated include the following: the type of fibers (AFRP, CFRP), the thickness of the jacket, the shape (rectangular or circular) and aspect ratio of the cross section, and the sharpness of the corners of the rectangular cross sections. The sample structures were designed initially without lateral forces and... 

Although considerable researches have been conducted on strengthening RC structures using FRP method during past years, a few researches have been reported on RC arch or curved structures strengthened by FRP. In this study, behavior of RC arches strengthened by FRP strips is investigated. The behavior of strengthened RC arches under gravitational load is analyzed using finite elements method. The arches are modeled by appropriate software in order to evaluate the behavior. The structural behavior of arches is more complicated. So, the estimation of the effect of strengthening using FRP technique on such structures is hard in comparison with traditional RC beams. In this study, the effect of... 

Shear walls are commonly used in tall concrete buildings to resist lateral loads. Due to the presence of regular door or window openings, a shear wall is often divided into smaller wall units coupled together by coupling beams. In any case, the earthquake resistance of a coupled shear wall structure is highly dependent on the nonlinear behaviour, especially the strength and ductility, of the coupling beams. Many existing building structures without provisions for resisting earthquake loads might no longer be considered to be up to the new standard due to increased-load specifications in the seismic code. A large number of RC coupling beams might require rehabilitation or retrofitting to... 

In recent years, the development of the plate bonding repair technique has been shown to be applicable to many existing strengthening problems in the building industry. This technique may be defined as one in which composite sheets or plates of relatively small thickness are bonded with an epoxy adhesive to, in most cases, a concrete structure to improve its structural behaviour and strength. The sheets or plates do not require much space and give a composite action between the adherents. The old structure and the new bonded-on material create a new structural element that has a higher strength and stiffness than original one. According to the available methods of analysis and design for... 

Understanding and defining mechanical behavior of engineering materials play an important role in the prediction of material response as well as analysis and design of engineering structures. In this investigation, polymer concrete (PC) with three different epoxy resin contents, ordinary cement concrete (OCC), lightweight concrete (LWC) and lime-mortar soil (LMS) have been studied under uniaxial and triaxial compression tests to determine their mechanical behavior by measuring axial stress-strain and volumetric strain versus axial strain curves. According to the results, PC showed higher strength, ductility and energy absorption than that of OCC and LWC. Nowadays, waste tire rubber is used... 

With the rapid development of biotechnology, peptide and protein drugs are now playing an increasingly important role in therapeutics. Compared with chemical drugs, peptide and protein drugs have some limitations such as low stability and rapid deactivation. Biodegradable and biocompatible polymeric micro carriers have been shown to have a high potential for the delivery of peptides and proteins. Among these polymers, alginate has been widely investigated as a biomaterial. Alginates are natural polysaccharide polymers isolated from brown seaweed. Bovine serum albumin (BSA) loaded calcium alginate microspheres produced in this study by a modified w/o emulsification method. The influence of... 

In recent years, liquid resin injection processes for aviation applications have been considered an alternative to conventional autoclave-based processes. At present, these processes have challenges that have been denied industry trust due to their inability to be objectively reproducible. In the last decade, some software has been developed to simulate the vacuum injection process, but this software does not have enough capability to predict the injection network, and an operator with sufficient empirical knowledge must use this software. In recent years, researchers have used this softwares to simulate the process, but so far no software has been developed that can offer injection... 

Various composite friction materials containing 40 vol.% organic binder (phenolic resin plus styrene-butadiene-rubber (SBR)) with varying phenolic-resin/SBR ratio were prepared. The content of phenolic resin in each composite was indicated by the resin value (RV) index ranging between 0-100%. The composites with RVs greater than 50% form resin-based friction materials in which the primary binder is the phenolic resin. For RVs less than 50%, the composites become the rubber-based materials where the primary binder is the SBR. The analysis of mechanical properties exhibited that the conformability of the composites increases upon incorporation of SBR. The frictional analysis revealed that type... 

In the world today, biological materials widely used are which requires proper packaging, the types of enzymes are used in various industries: food, pharmaceutical, cosmetics. Shelf Life of enzymes Limited and affected by internal and external factors a maximum of one year. Internal factors include water activity, pH, microbial flora, oxidation-reduction potential, chemistry and biochemistry products, product formulation, additives and the reaction with package. External factors such as relative humidity, light, gas atmosphere within the package, the storage conditions and temperature. Water activity and relative humidity are important factors in spoilage. Avoid drying, lipid reaction,... 

It is about half century passed from the invention and application of the polymer flooding. Although there are successful reports from the using polymer flooding, but there are problems that in some cases this process fails. For more insight on the problems and in order to improve
the efficiency of this process the conceptual understanding of the process is required. More conceptual understanding from this process, requires investigation in pore scale. In the presenting investigation, the flow of Newtonian and non-Newtonian fluids in the single phase and two phase form and in pore scale are simulated using finite volume method. Because, the finite volume method is used in very... 

In the experimental approach, graphene and Graphene Oxide (GO) were synthesized through a chemical method. In order to study the quality of GO, characterization tests were performed. Then, reinforced polymer with GO and graphene was made. Moreover, tension, compression and Split- Hopkinson pressure bar tests were performed on standard samples of reinforced polymer nanocomposite. The experimental data show that nanoparticles have a destructive effect in very low and high percentages for extension test as well as in high percentages for compression test. On the other hand, graphene is more effective than GO on improving material properties. Furthermore, comparison of compression results in... 

Ultrasonically assisted machining process has been introduced as an effective solution to improve machining quality of mechanical parts. This study aims to reduce the drilling induced delamination to increase mechanical properties of CFRP laminates. Delamination decreases the strength of laminates under static and dynamic loads. Drilling parameters (feed and spindle speed) and ultrasonic vibrations amplitude are chosen as design experiment factors. Taguchi design of experiments method is used to study the effect of input factors on drilling thrust force, delamination factor and residual strength of drilled laminates. Input factors are in three levels and Taguchi L9 array is utilized. To... 

A set of azacrown macrocyclic ligands bearing pyridine moiety (bp, 1p, 2p) were synthesized and characterized by single-crystal X-ray diffraction (SCXRD), elemental analysis, FT-IR, 1H and 13C NMR methods. The complexes of zinc tetraphenylporphyrin (ZnTPP) with the bp and 1p as the axial ligand were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, 1H and 13C NMR, fluorescence, UV-vis, cyclic voltammetry, together with TD DFT calculations. By employing this method for ZnTPPbenz and ZnTPPH complexes elucidated that the pyridine moiety was bonded through the fifth- coordination site on the zinc metal atom. In the following study, the coordination... 

Heavy oil reservoirs include a major part of the world’s oil reservoirs. Therefore consideration to their enhanced oil recovery (EOR) aspects has a great importance. In heavy oil reservoirs secondary and tertiary EOR methods, have an insignificant effect on oil recovery and so we’d better to use chemical methods to improve mobility and oil recovery. One of the appropriate EOR methods which has attracted a lot of attention is alkaline – surfactant – polymer (ASP) flooding which has a considerable impact on EOR from heavy oil reservoirs. In this EOR method, the low concentration of surfactant in the injecting fluid, results in a low or ultra-low interfacial tension (IFT) between residual oil...