Sharif Digital Repository

In the present research, the conversion of methanol to hydrocarbons was studied over a new series of mesoporous low-silica HZSM-5 (Si/Al=11) catalysts impregnated with cations such as Fe, Zn, Mo and Cr. A systematic study on the effect of stepwise modification of the catalysts for the conversion of methanol to gasoline (MTG) was undertaken in a fixed-bed tubular reactor under ambient pressure at 375 °C, feeding with weight hourly space velocity (WHSV) of 2 h−1. The catalysts were prepared in the absence and presence of cationic promoted factors, in both alkaline and neutral aqueous solutions. The final catalysts characterized by using Fourier-transform infrared, X-ray diffraction, X-ray... 

Dimethyl Ether (DME) is a pure and economic fuel which can be used as a suitable alternative for diesel fuels. Two processes are traditionally used for DME synthesis: producing methanol from synthesis gas and then dehydrating it to DME (direct process), and converting methanol into DME in a catalytic dehydration reactor over a solid-acid catalyst (indirect process), in which the indirect process seems to have economical advantage. In this research, the γ-Al2O3 catalyst was synthesized through precipitation process and then characterized by powder X-ray diffraction (XRD) and porosimetry analysis. Afterwards this catalyst was utilized in methanol dehydration reaction in a slurry reactor. Next,... 

In this study, different metal oxides were impregnated on the surface of ZSM-5 employed as photocatalysis for degradation of methylene blue dye used in the presence of ultraviolet light. The final products were characterized by powder X-ray diffraction (XRD) and fourier transform infrared (FT-IR) method. According to the proposed mechanism for the photocatalytic degradation of methylene blue based on these results, it was found that the reaction followed from the first-order mechanism. The results indicated that rate constant for pure ZSM-5 was 9.3〖 ₓ10〗^(-3) (min-1). Furthermore the impregnated ZSM-5 having 12% zinc oxide demonstrated the highest photocatalytic activity with rate constant... 

Methanol to Olefin (MTO) process is a part of the Methanol to Gasoline (MTG) production in a catalytic bed. Usually for this process, HZSM-5 or SAPO-n catalyst is used. In this research, dynamic modeling and simulation of the methanol to olefin catalytic reactor using HZSM-5 as the catalyst is done. The system is modeled based on the kinetic model for HZSM-5 presented by Castilla in 1999 [22]. Since the reaction is exothermic, taking use of a cooling system is essential. According to the high reactor temperature, a molten salt environment is used as the cooling media. In this cooling system, the molten salt absorbs heat of reaction from the reactor tubes and transfers it to a coil connected... 

A two-dimensional, two-phase, nonisothermal model was developed in this work to investigate the water transport characteristic and water distribution in a direct methanol fuel cell (DMFC). Emphasis is placed on exploring the water distribution in different layers of DMF. The water and methanol crossover through the membrane were considered with the effect of diffusion, electro-osmotic drag, and convection. Governing equations including the prton and electron transport, continuity, momentum, species transport for methanol, water, and gases species, and the auxiliary equations are coupled to determine the output parameters. These parameters are the concentration distribution of the species,... 

Catalytic cracking of iso and normal butane over HZSM-5 at several temperatures and a variety of contact time and different partial pressures of hydrocarbon feed was conducted. Experiments indicate that the operating conditions have considerable effects on final product distribution and feed conversion. Results show that high temperatures, low contact time and partial pressure of paraffin feed favor the light olefin production, particularly propylene production. Results obtained for iso-butane show a similar conversion values in comparison to n-butane but a higher olefin and propylene selectivity. Finally kinetic modeling of both iso and normal butane cracking was performed based on a lump... 

Nowadays, with respect to environmental pollution and energy supply, producing gasoline from methanol or syngas is one of the most interesting research subjects. Gasoline production from methanol is a catalytic process that produces high-quality gasoline with minimum unwanted compounds. So this gasoline is a clean fuel and it can be replaced to petroleum gasoline. Because of that, it can be a valuable process in the petrochemical industry. One of the most important aspects of this process is catalyst deactivation with respect to time on stream. Catalyst deactivation is usually caused by poisoning, sintering, blocking pores, and coking. In this research, material and energy balance equations... 

Emission of CO2 and its diffusion into atmosphere is associated with negative effects on the environmental such as Green House Gases effect. Various techniques of CO2 Capture in energy conversion and processing plant are investigated. A method of CO2 Capture could be based on utilization of solar energy for producing methanol. Basic design of such a system and feasibility analysis of developing that system has been considered on the subject of the present research work. Basic design and commercial feasibility of the system producing methanol through capturing CO2 from exhaust gases of a power plant and hydrogen produced by using solar energy have done such an integrated system. The main... 

In this research, self-optimizing method has been used to design a plant-wide control structure for processes containing purge and recycle streams. The method is based on the concept of self-optimizing variables to maximize the process profitability in the presence of possible disturbances. The purpose of this thesis is to perform this procedure on ammonia and methanol processes containing purge and recycle streams.Using the results obtained for the ammonia process and considering the constraints and operating conditions of the problem, the active constraints of this process were detected which were cooling water flow rates to exchangers. According to local analysis method, self-optimizing... 

Considering the supply and demand market of natural gas, methanol, propylene and ethylene and the propylene value chain, it is expected that the design of the propylene production process from methanol produced from natural gas and its implementation in Iran country can significantly flourish the production of polypropylene, acrylonitrile and Etc. On the other hand, with the industrialization of this process, the uncontrolled export of methanol from Iran to countries such as China and the devaluation of methanol will be prevented. In this report, the process of producing synthetic gas from natural gas using autothermal reactor and heat exchange reforming, separation and storage of carbon... 

Cell of fuel methanol can store fuel easily, because they can suitable for resources of energy with ambulant applications. As for with the extensive of electrical haul instruments, they attention to the use of fuel cell methanol. In this project a fuel cell methanol consist of different branches such as cathode, Anode, substrates of membrane and influx, has modeled with the form of flat three dimensional. This model consist of ambulant theorems, transfer of mass, chemistry theorems and reflexes of electro chemistry in spongy environment. As for with a little knowledge that is related to the oxidation of methanol, the first research is related to this reflex and the knowledge of mathematic... 

Titanium nitride-carbon nanocomposites are synthesized by the reaction of TiCl4 and NaN3 in supercritical benzene medium that also serves as a carbon source. In order to improve the crystallinity of the as-prepared precursor (SI), it is further heat-treated at 1000 ˚C for 3-10 h using anhydrous ammonia and UHP nitrogen atmospheres at 1000 ˚C (SIII-SV). Moreover, to improve electrochemical behavior, the synthesized nanocomposite (SIV) is modified with Pt nanoparticles using a polyol process. For better understanding of synthesized catalyst nature and justifying their variant ORR activity several analyses are done. X-ray diffraction (XRD), Raman spectrum, field emission scanning electron... 

This thesis encompasses two parallel, but independent subjects as follow: The first part of the thesis deals with synthesis of bimetallic Ni-Au nanoparticles (Bi Ni-Au), and application of them as electrodes in the methanol fuel cells. The Bi Ni-Au nanoparticles for this purpose were synthesized by controlled reduction of HAuCl3 and NiCl3 in the aqueous medium using NaBH4 as reductant and PVP as stabilizer, and immobilized on the surface of a glassy carbon (GC) electrode by means of Nafion polymer. The obtained electrode then was conditioned in an alkaline solution by cyclic voltammetric method in potential range 100 -700 mV (vs. Ag/AgCl). Physicochemical characterizations of the... 

Nano and microsize H-ZSM-5 were synthesized by hydrothermal crystallization method with same batch composition to investigate the effect of crystallite size of H-ZSM-5 in the methanol conversion to propylene (MTP) process. The average particle size of nano and microsize H-ZSM-5 were obtained in the range of 0.15- 0.2 and 1- 2 µm, respectively. Also, optimized catalyst of Petrochemical Research and Technology Company was synthesized using terapropylammonium bromide as template. Nowadays, terapropylammonium bromide (TPABr) is cheeper than terapropylammonium hydroxide (TPAOH); therefore we used it as tamplate. Activity tests were conducted at operating conditions of T= 460˚C, P=1 atm and WHSV... 

In this study, we synthesized ZSM-5 and doped ZSM-5 applying cations such as Zn(II) and Fe(II). Furthermore, we synthesized [Zn,Fe]-ZSM-5 using similar method for the first time. The final products were characterised by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. On the other hand, the hierarchical mesoporous Zn-ZSM-5 zeolite catalyst was prepared by alkali treatment by NaOH and Zn impregnation, and its application in the conversion of methanol to gasoline (MTG) process was studied. The modified zeolite samples after modification were also characterized by FT-IR and XRD methods. Zn impregnated mesoporous catalyst Zn-Alk-Z5 exhibited dramatic improvements in... 

We have studied binary structures contain; as grown thin film of carbon nanotubes (CNTs) , CNT rich polymeric composite, Pd doped WO3 thin film, and also hybrid thin film which was mixed CNTs and WO3 nanoparticles and ternary structure which was obtained by adding Pd to hybrid structure as a hydrogen gas sensor. The structure, morphology, chemical composition and quality of as–grown and functionalized CNTs and sensitive films were studied by SEM, TEM, XRD, XPS, DLS, FTIR and Raman spectroscopy methods. Variation of film’s electrical resistance after exposure gases is utilized as the principle of gas sensing. Multi-Walled Carbon Nanotube (MWCNTs) films were obtained by Thermal Chemical Vapor... 

The hydrogenation of carbon dioxide to methanol represents a promising route for the efficient use of an anthropogenic greenhouse gas, in which catalysts play a key role in carbon dioxide conversion and methanol selectivity. In this study, firstly, CuO-ZnO-Al2O3, CuO-ZnO-ZrO2, CuO-ZnO-ZrO2-Al2O3, CuO-ZnO-Al2O3-CeO2 and CuO-ZnO-ZrO2-CeO2 catalysts were made using co-precipitation method, then these catalysts were characterized by inductively coupled plasma optical emission spectrometry, specific surface area and pore size distribution, X-ray diffraction, Field Emission Scanning Electron Microscopy, temperature programmed reduction. Finally, in order to compare the performance of the catalysts... 

Dimethyl ether (DME) as a clean fuel is a suitable alternative for diesel fuel. It has a high cetane number and does not contain any sulfur or metal compounds. Furthermore, DME does not form any soot and has a potential to reduce NOx emissions. In addition, it is not corrosive to any metal and not harmful to the human body. Two approaches are currently used for the production of DME from synthesis gas. The first is an indirect two-step process involving methanol synthesis followed by catalytic dehydration of methanol to DME over solid-acid catalysts, while the second method enables direct synthesis of DME using a bifunctional catalyst. At present, indirect synthesis of DME is a more... 

Information and Communication Technology and Artificial Intelligence (AI) can support the transition from traditional practices toward smart supply chain coordination schemes. Such a direction allows for integrating organizational levels of natural gas transportation enterprises, comprising Location, Inventory, and Routing Problem (LIRP) decisions. Specific works have investigated the LIRP of natural gas-to-product and energy networks. However, due to the absence of a systematic ICT-assisted mindset, no study has been oriented from the perspective of the dynamic inventory management and geographic data-driven features of land resources. To handle these challenges, this study partially... 

The development of computers and their related software packages provided engineers with the ability to simulate complex chemical processes. These simulations were the stepping stone for in-depth knowledge of the processes and also a prerequisite for the chemical process optimizations. From then, realistic simulation and optimization were always a primary concern for chemical engineers. To address this concern, they go beyond the one-dimensional design approach toward the two-dimensional design-operation systems, and the design-control interaction of the chemical processes afterward. Moreover, optimizing chemical processes from the aspect of energy and water, separately, gained lots of...