Sharif Digital Repository

Iran with the second largest gas reserves in the world makes the importance of Kish Island more vital. Kish gas field, with a capacity of 67 trillion cubic meters gas, is one of the main hubs of Iran gas production. One of the uses of natural gas is to produce petrochemical goods such as Methanol. In this thesis the focus is on economical evaluation of producing Methanol for amount of 5,000 tons per day from Kish gas field. As a result, the required feed has been estimated about 150 million cubic feet per day and the net capital investment calculated to be 941 million US dollars. The initial estimate of Direct Permanent Investment (DPI) was calculated to be $590.8 million. Having considered... 

We have studied binary structures contain; as grown thin film of carbon nanotubes (CNTs) , CNT rich polymeric composite, Pd doped WO3 thin film, and also hybrid thin film which was mixed CNTs and WO3 nanoparticles and ternary structure which was obtained by adding Pd to hybrid structure as a hydrogen gas sensor. The structure, morphology, chemical composition and quality of as–grown and functionalized CNTs and sensitive films were studied by SEM, TEM, XRD, XPS, DLS, FTIR and Raman spectroscopy methods. Variation of film’s electrical resistance after exposure gases is utilized as the principle of gas sensing. Multi-Walled Carbon Nanotube (MWCNTs) films were obtained by Thermal Chemical Vapor... 

This thesis encompasses two parallel, but independent subjects as follow: The first part of the thesis deals with synthesis of bimetallic Ni-Au nanoparticles (Bi Ni-Au), and application of them as electrodes in the methanol fuel cells. The Bi Ni-Au nanoparticles for this purpose were synthesized by controlled reduction of HAuCl3 and NiCl3 in the aqueous medium using NaBH4 as reductant and PVP as stabilizer, and immobilized on the surface of a glassy carbon (GC) electrode by means of Nafion polymer. The obtained electrode then was conditioned in an alkaline solution by cyclic voltammetric method in potential range 100 -700 mV (vs. Ag/AgCl). Physicochemical characterizations of the... 

By combustion, waste toxic, flammable and corrosive materials are changed to less inviromental problems by combustion. It also creats environmental problems (the most serios problem is caused by burning gases), as well as economic resources are wasted. So several ways was investigated to reduce combustion gases. Mini-methanol plant is one of varios possible ways that can convert these gases in to methanol. So methanol plant was simulated and then pinch analysis was performed on the simulated plant. Performing of pinch analysis caused 94.5 percent and 25 percent reduction in amaunt of hot and cold utility respectively. Before and after pinch analysis, the exergy analysis was performed on... 

The Increasing trend of gas flaring over oil fields and gas process systems in Iran not only causes several environmental problems, but makes the economical resources useless as well. Considering the high amount of flaring and old facilities, one of the best solutions is the recovery of the flare gas in Iran. It seems that collecting the flare gas is not possible in different sectors. Therefore, using a plant for converting flare gas to other products must be logical. In this project, the feasibility study of converting flare gas to other products is studied. For this reason, a methanol plant is simulated; whose input feed is the content of flare gas of the South of Iran (Marun and Siri).... 

One of the different methods of heat transfer, is pool boiling process. In this method, the operating fluid starts to boil on a hot surface whose temperature is more than boiling point of the fluid. Based on difference between between surface temperature and fluid boiling point, amount of heat flux from hot surface to fluid and fluid behavior will be different. In recent years, many researchers have tried to improve the amount of heat transfer in the boiling process by using various methods such as nanoparticle addition or using magnetic field.Latent heat is thermal energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process, usually a first-order... 

Emission of CO2 and its diffusion into atmosphere is associated with negative effects on the environmental such as Green House Gases effect. Various techniques of CO2 Capture in energy conversion and processing plant are investigated. A method of CO2 Capture could be based on utilization of solar energy for producing methanol. Basic design of such a system and feasibility analysis of developing that system has been considered on the subject of the present research work. Basic design and commercial feasibility of the system producing methanol through capturing CO2 from exhaust gases of a power plant and hydrogen produced by using solar energy have done such an integrated system. The main... 

Titanium nitride-carbon nanocomposites are synthesized by the reaction of TiCl4 and NaN3 in supercritical benzene medium that also serves as a carbon source. In order to improve the crystallinity of the as-prepared precursor (SI), it is further heat-treated at 1000 ˚C for 3-10 h using anhydrous ammonia and UHP nitrogen atmospheres at 1000 ˚C (SIII-SV). Moreover, to improve electrochemical behavior, the synthesized nanocomposite (SIV) is modified with Pt nanoparticles using a polyol process. For better understanding of synthesized catalyst nature and justifying their variant ORR activity several analyses are done. X-ray diffraction (XRD), Raman spectrum, field emission scanning electron... 

Titania is semiconductor material and have many applications including photocatalysis, photochromic, air and water purification, sensors, and solar cell. In electrophoretic deposition, charged particles dispersed in a stable suspension move towards an oppositely charged electrode, and form dense layer of deposit on it. In this investigation electrophoretic deposition of titania nano-particles in suspensions prepared by different solvents (methanol, ethanol and butanol) with and without dispersant (triethanolamine and polyethylenimine), was studied. Well stabilized suspensions, prepared for electrophoretic deposition. The effects of solvent type, additive concentration, mechanism of particles... 

Information and Communication Technology and Artificial Intelligence (AI) can support the transition from traditional practices toward smart supply chain coordination schemes. Such a direction allows for integrating organizational levels of natural gas transportation enterprises, comprising Location, Inventory, and Routing Problem (LIRP) decisions. Specific works have investigated the LIRP of natural gas-to-product and energy networks. However, due to the absence of a systematic ICT-assisted mindset, no study has been oriented from the perspective of the dynamic inventory management and geographic data-driven features of land resources. To handle these challenges, this study partially... 

The hydrogenation of carbon dioxide to methanol represents a promising route for the efficient use of an anthropogenic greenhouse gas, in which catalysts play a key role in carbon dioxide conversion and methanol selectivity. In this study, firstly, CuO-ZnO-Al2O3, CuO-ZnO-ZrO2, CuO-ZnO-ZrO2-Al2O3, CuO-ZnO-Al2O3-CeO2 and CuO-ZnO-ZrO2-CeO2 catalysts were made using co-precipitation method, then these catalysts were characterized by inductively coupled plasma optical emission spectrometry, specific surface area and pore size distribution, X-ray diffraction, Field Emission Scanning Electron Microscopy, temperature programmed reduction. Finally, in order to compare the performance of the catalysts... 

The development of computers and their related software packages provided engineers with the ability to simulate complex chemical processes. These simulations were the stepping stone for in-depth knowledge of the processes and also a prerequisite for the chemical process optimizations. From then, realistic simulation and optimization were always a primary concern for chemical engineers. To address this concern, they go beyond the one-dimensional design approach toward the two-dimensional design-operation systems, and the design-control interaction of the chemical processes afterward. Moreover, optimizing chemical processes from the aspect of energy and water, separately, gained lots of... 

Considering the supply and demand market of natural gas, methanol, propylene and ethylene and the propylene value chain, it is expected that the design of the propylene production process from methanol produced from natural gas and its implementation in Iran country can significantly flourish the production of polypropylene, acrylonitrile and Etc. On the other hand, with the industrialization of this process, the uncontrolled export of methanol from Iran to countries such as China and the devaluation of methanol will be prevented. In this report, the process of producing synthetic gas from natural gas using autothermal reactor and heat exchange reforming, separation and storage of carbon... 

In this research, self-optimizing method has been used to design a plant-wide control structure for processes containing purge and recycle streams. The method is based on the concept of self-optimizing variables to maximize the process profitability in the presence of possible disturbances. The purpose of this thesis is to perform this procedure on ammonia and methanol processes containing purge and recycle streams.Using the results obtained for the ammonia process and considering the constraints and operating conditions of the problem, the active constraints of this process were detected which were cooling water flow rates to exchangers. According to local analysis method, self-optimizing... 

Nowadays, with respect to environmental pollution and energy supply, producing gasoline from methanol or syngas is one of the most interesting research subjects. Gasoline production from methanol is a catalytic process that produces high-quality gasoline with minimum unwanted compounds. So this gasoline is a clean fuel and it can be replaced to petroleum gasoline. Because of that, it can be a valuable process in the petrochemical industry. One of the most important aspects of this process is catalyst deactivation with respect to time on stream. Catalyst deactivation is usually caused by poisoning, sintering, blocking pores, and coking. In this research, material and energy balance equations... 

Cell of fuel methanol can store fuel easily, because they can suitable for resources of energy with ambulant applications. As for with the extensive of electrical haul instruments, they attention to the use of fuel cell methanol. In this project a fuel cell methanol consist of different branches such as cathode, Anode, substrates of membrane and influx, has modeled with the form of flat three dimensional. This model consist of ambulant theorems, transfer of mass, chemistry theorems and reflexes of electro chemistry in spongy environment. As for with a little knowledge that is related to the oxidation of methanol, the first research is related to this reflex and the knowledge of mathematic... 

Nowadays, one of the most basic human problem is how to manage energy resources for sustainable development and how to deal with problems caused by growing energy consumption. Various scenarios are being discussd that the most important of them can be considered research on finding alternative energy sources that are renewable and do not have common pollution. Thus, according to researches carried out until now, using sources such as wind, water, solar biomass, etc. have been proposed. However, due to problems in the development of each of these sources, biomass as the primary option has been introduced. because biomass has several subsidiaries, research shows microalgaes (as a subset) are... 

Propylene is one of the key material in petrochemical industries. In recent years, as propylene demand increases, development of new methods alongside traditional ways in production of propylene seems essential. The production of propylene from methanol using zeolitic catalysts is as one of this new methods. This method in recent years has got attention. H-ZSM-5 zeolite is one of the best catalysts appropriate for this process. However, rapid deactivation is the main problem this catalyst at the present time. Therefore, more research in order to increase stability and lifetime has been performed. The uses of promoters are as one of the simplest improvement methods of H-ZSM-5 zeolite.... 

A two-dimensional, two-phase, nonisothermal model was developed in this work to investigate the water transport characteristic and water distribution in a direct methanol fuel cell (DMFC). Emphasis is placed on exploring the water distribution in different layers of DMF. The water and methanol crossover through the membrane were considered with the effect of diffusion, electro-osmotic drag, and convection. Governing equations including the prton and electron transport, continuity, momentum, species transport for methanol, water, and gases species, and the auxiliary equations are coupled to determine the output parameters. These parameters are the concentration distribution of the species,... 

Methanol to Olefin (MTO) process is a part of the Methanol to Gasoline (MTG) production in a catalytic bed. Usually for this process, HZSM-5 or SAPO-n catalyst is used. In this research, dynamic modeling and simulation of the methanol to olefin catalytic reactor using HZSM-5 as the catalyst is done. The system is modeled based on the kinetic model for HZSM-5 presented by Castilla in 1999 [22]. Since the reaction is exothermic, taking use of a cooling system is essential. According to the high reactor temperature, a molten salt environment is used as the cooling media. In this cooling system, the molten salt absorbs heat of reaction from the reactor tubes and transfers it to a coil connected...