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    Fracture Toughness of Geopolymer Concrete Containing Blast Furnace Slag in Corrosive Environments

    , M.Sc. Thesis Sharif University of Technology Ziamiavaghi, Behanm (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Fracture Toughness of Geopolymer Concrete Containing Blast Furnace Slag in Corrosive Environments  

    Phenomenological Study of Granulation by Investigating the Effects of Operating Parameters on Granule Properties

    , Ph.D. Dissertation Sharif University of Technology Ranjbarian, Sima (Author) ; Farhadi, Fathollah (Supervisor)
    Abstract
    The present thesis has provided more fundamental understanding of granulation rate processes (such as coalescence, attrition and breakage) by investigating the effects of operating parameters on product properties. The studied process was wet granulation carried out in two high shear mixer granulators. Granulation duration, binder mass and impeller speed were considered as operating parameters and granule size distribution (measured by sieving) and granule binder distribution (measured by thermogravimetery method) were regarded as product properties. Experiments were conducted in two analogous cylindrical and conical high shear granulators. The obtained experimental and theoretical results... 

    Modeling of Spray Granulation

    , M.Sc. Thesis Sharif University of Technology Hashemi Amrei, Mohammad Hossein (Author) ; Molaei Dehkordi, Asghar (Supervisor)
    Abstract
    Fluidized bed spray granulation is an important powder production process with several key advantages compared to other powder production processes, such as spray drying. Moreover, in fluidized bed granulators, whole process takes place in just one apparatus and there is no need to side processing. Most important characteristics and essential part of fluidized bed granulation is the wetting of primary particles by atomized liquid binder to coating the primary particles and producing granules. To date, a lot of research has focused on modeling and understanding of the separate particle growth mechanisms which have been integrated into the population balance models. Although, these concepts... 

    Design and Construction of Aerobic Granulation Reactor in Order to Study the Effect of Cationic Polymer on Granular Formation

    , M.Sc. Thesis Sharif University of Technology Jalali Varnamkhasti, Sajjad (Author) ; Shaygan Salek, Jalaloddin (Supervisor)
    Abstract
    Despite many advantages of granular sludge in anaerobic reactors (e.g. UASB), over the past few years research attention had turned towards developing aerobic granular sludge. Although much research is carried out on the formation of aerobic granules, less work is reported on how to enhance granules characteristics such as increasing in granule size, concentration, durability and stability. The aims of this study are to investigate the effects of cationic polymer on granule formation and the way to improve granule characteristics. For this purpose two SBR reactors (0.15 m diameter and 1.8 m height, R1 and R2) were used by feeding synthetic wastewater (diluted molasses, COD ranging from 1400... 

    Environmental Impact of Seawater on GGBFS-Based Alkali-Activated Concrete

    , M.Sc. Thesis Sharif University of Technology Safavi, Alireza (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    This study seeks to compare the effect of curing conditions in the sea, coast, and middle of the island environment on five mix designs of alkali-activated concrete (AAC) based on ground granulated blast furnace slag (GGBFS) and fly ash (FA) and the effect of the ratio of sodium silicate (SS) to sodium hydroxide (SH) and alkali activated solutions (AAMS) to the binder on mechanical properties. The compressive strength and load-deflection test was conducted to obtain uniaxial compressive strengths (UCS), modulus of elasticity ("E" _"S" ), elastic and ultimate strain, and dissipated energy. The most significant decrease in strength was observed in the coastal area and the sea. Also, the... 

    Designing Granular Sequencing Batch Reactor for Investigating the Effect of Influent Feeding Alkalinity and Rreactor pH on Aerobic Granulation

    , M.Sc. Thesis Sharif University of Technology Rezasoltani, Samira (Author) ; Shaygan, Jalal (Supervisor)
    Abstract
    Laboratory experiments were carried out to investigate the effect of influent alkalinity and reactor pH on microbial species, morphology and performance efficiency of aerobic granules. The experiments were conducted in two L sequencing batch reactors (R1-R2) with different influent alkalinity and pH medium. pH in R1 ,with high influent alkalinity, was in the range of 7-7.5 and pH in R2 was adjusted in 4.5-5.5. The experimental results demonstrated that the dominated microbial species and structure of granules were different in two rectors. Acidic environment of R2 provide favorable condition for fungal growth and granules formed within first week of operation. On the other hand in R1,... 

    The Durability of Geopolymer Concrete Confined with Fiber Reinforced Polymer Materials

    , M.Sc. Thesis Sharif University of Technology Anvari Sakhvidi, Mohammad Amin (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Material durability is quite critical in corrosive environments. In this study, two hundred and seventy geopolymer concrete specimens with different mix designs were prepared and then wrapped with two different fiber reinforced polymer (FRP) materials. For 12960 hrs (eighteen months), the specimens were exposed to four different pHs (2.5, 7, 7.25, 12.5). The reliability and SEM analysis were performed after modeling the compressive strength over time. Based on the results, the reduction of the compressive strength was up to 22% in an acidic environment. The compressive strength of the specimens was increased up to 11 percent after alkaline solution exposure. The ductility of all specimens... 

    Investigation of Mechanical Properties and Durability of Alkali-activated Slag Concrete Lightened with Scoria and Its Microstructural Study

    , M.Sc. Thesis Sharif University of Technology Mahmoudzadeh Vaziri, Nima (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    Concrete has long been one of the most widely used materials in the world. Cement, as a major component of concrete, due to the use of fossil fuels in its production process, emitting greenhouse gases such as carbon dioxide, which cause air pollution and environmental issues such as climate change. On the other hand, the wastes of industrial factories such as slag of the Blast furnace, due to their large volume and lack of sufficient space for storage of these wastes, lead to the release of these wastes that have alkaline structures into enviroment, causing environmental pollution Such as embankment pollution. Alkali-activated concrete has prevented the release of these pollutant into the... 

    Feasibility Study of Manufacturing of Disposable Plant Containers

    , M.Sc. Thesis Sharif University of Technology Hosseini Vala, Hamid (Author) ; Mostafavi, Mostafa (Supervisor)
    Abstract
    The aim of the present research is to analyse feasibility study of manufacturing the disposable (Biodegradable) plant containers in Iran. The population of the research consists of the whole capacity for manufacturing this product and the similar product producers which have been registered in the Ministry of Industry, Mines and Commerce. First, in this research, the environmental and anti-environmental impacts of non-plant Disposable Containers like: plastic, foam, paper and aluminum have been discussed and also their disadvantages have been examined to be compared with advantages of using plant Disposable Containers. Thereafter, collecting the required data about today society and market,... 

    Evaluation of Granularity of Reconfigurable Architectures for Wireless Communication Applications

    , M.Sc. Thesis Sharif University of Technology Nazarieh, Masoumeh (Author) ; Hemmat yar, Afshin (Supervisor)
    Abstract
    Wireless communication applications need high computing power, flexibility and scalability. Although ASICs have the ability of high computing power but they are not flexible to changing or completing of communication protocols. On the other hand, general purpose microprocessors or DSPs are flexible, but do not provide sufficient computing power. Thus devices with reconfigurable architecture have been proposed as a compromise between ASICs and microperocessors. One of the main features of reconfigurable devices is the granularity. The granularity of a reconfigurable devices shows the amount of computing power incorporate in a processing element. In this thesis we have evaluated different... 

    Study of early-age creep and shrinkage of concrete containing Iranian pozzolans: An experimental comparative study

    , Article Scientia Iranica ; Volume 16, Issue 2 A , 2009 , Pages 126-137 ; 10263098 (ISSN) Ghodousi, P ; Afshar, M. H ; Ketabchi, H ; Rasa, E ; Sharif University of Technology
    2009
    Abstract
    This paper presents an experimental study on prediction of the early-age creep and shrinkage of concrete with and without silica fumes, trass, ground-granulated blast-furnace slag, combinations thereof, and influences of the proposed Iranian pozzolans. Experiments were carried out under a controlled ambient condition at a temperature of 40° C and a relative humidity (RH) of 50%, and a laboratory ambient condition at a temperature of 20° C and a relative humidity (RH) of 30% in order to collect the required data. Comparisons are made between ACI209-92, BS8110-1986 and CEB1970 prediction models, and an estimation model, based on 28-day results (short-term test method), using the same... 

    Removal of humic acid from aqueous solution using photocatalytic reaction on perlite granules covered by nano TiO2 particles

    , Article Journal of Molecular Liquids ; Volume 242 , 2017 , Pages 357-363 ; 01677322 (ISSN) Joolaei, H ; Vossoughi, M ; Rashidi Mehr Abadi, A ; Heravi, A ; Sharif University of Technology
    Abstract
    Humic acid (HA) constitutes a large portion of natural organic matter (NOM), and is the main precursor of toxic and cancerogenic Trihalomethanes compounds, formed during chlorination of drinking water. Therefore, it is essential that the humic acid be eliminated from water before treating it. The present study aims to investigate the photocatalytic degradation of humic acid (HA) using TiO2 nanoparticles immobilized on perlite granules (TIP), irradiated by UV light in a photoreactor. Samples of coated perlites were prepared by a dip coating method using a commercial powder of TiO2. Characteristics of the prepared samples were evaluated by X-ray and scanning electron microscope techniques.... 

    Rapid start-up and improvement of granulation in SBR

    , Article Journal of Environmental Health Science and Engineering ; Volume 13, Issue 1 , 2015 ; 2052336X (ISSN) Jalali, S ; Shayegan, J ; Rezasoltani, S ; Sharif University of Technology
    BioMed Central Ltd  2015
    Abstract
    Abstract Background: The aim of this study is to accelerate and improve aerobic granulation within a Sequencing Batch Reactor (SBR) by cationic polymer addition. Methods: To identify whether the polymer additive is capable of enhancing granule formation, two SBRs (R1 and R2, each 0.15 m in diameter and 2 m in height) are used by feeding synthetic wastewater. The cationic polymer with concentration of 30 to 2 ppm is added to R2, while no cationic polymer is added to R1. Results: Results show that the cationic polymer addition causes faster granule formation and consequently shorter reactor start-up period. The polymer-amended reactor contains higher concentration of biomass with better... 

    Photocatalytic degradation of furfural by titania nanoparticles in a floating-bed photoreactor

    , Article Chemical Engineering Journal ; Volume 146, Issue 1 , 2009 , Pages 79-85 ; 13858947 (ISSN) Faramarzpour, M ; Vossoughi, M ; Borghei, M ; Sharif University of Technology
    2009
    Abstract
    In this research, an attempt was made to investigate the potential of nanophotocatalysts for treatment of hazardous wastewater streams. Titanium dioxide nanoparticles (as photocatalyst) were immobilized on a porous and low-density support called "perlite" using a very simple and inexpensive method. TiO2-coated perlite granules were used in a "Floating-bed photoreactor" to study the photocatalytic purification process of a typical wastewater polluted by furfural. The effects of initial concentration, catalyst mass/solution volume ratio, oxidant molar flow, residence time, and light intensity on process removal efficiency, and kinetics of the reactions were studied. SEM analyses showed a... 

    Mathematical modeling and analytical solution of two-phase flow transport in an immobilized-cell photo bioreactor using the homotopy perturbation method (HPM)

    , Article International Journal of Hydrogen Energy ; Volume 41, Issue 41 , 2016 , Pages 18405-18417 ; 03603199 (ISSN) Zeibi Shirejinia, S ; Fattahi, M ; Sharif University of Technology
    Elsevier Ltd 
    Abstract
    In the present study, a theoretical model of a reaction–diffusion within an entrapped-cell photobioreactor packed with gel-granules containing immobilized photosynthetic bacterial cells is presented. The model is based on a system of two coupled nonlinear reaction–diffusion equations under steady-state condition for biochemical reactions occurring in the photobioreactor that describes the substrate and product concentration within the gel-granule. Simple analytical expressions for the concentration of substrate and product have been derived for all values of reaction–diffusion parameters, demonstrating competition between the diffusion and reaction in the gel-granule, using the homotopy... 

    Granulated copper oxide nano-catalyst: A novel and efficient catalyst for C-N cross-coupling of amines with iodobenzene

    , Article Monatshefte fur Chemie ; Volume 142, Issue 8 , 2011 , Pages 801-806 ; 00269247 (ISSN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Abdollahi, M ; Sharif University of Technology
    Abstract
    Nano-structured CuO granules catalyze the C-N cross-coupling of amines with iodobenzene in excellent yields. The reaction is simple, efficient, and operates in air under ligand-free conditions  

    Glass powder as a partial precursor in Portland cement and alkali-activated slag mortar: A comprehensive comparative study

    , Article Construction and Building Materials ; Volume 251 , 2020 Shoaei, P ; Ameri, F ; Reza Musaeei, H ; Ghasemi, T ; Cheah, C. B ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Prior studies were conducted in an isolated manner for the use of glass powder (GP) either as ordinary Portland cement (OPC) replacement material in blended cement or as a precursor in AAM material. There was no reported literature that made a direct comparison on the properties of blended cement and AAM containing GP with an equivalent mix composition. The present study was aimed to evaluate and compare the effects of GP as a partial precursor on properties of both OPC and alkali-activated slag (AAS) mortars. For this purpose, cement and ground granulated blast furnace slag (GGBFS) was partially replaced with 10%, 20%, 30%, and 40% (by weight) GP in OPC and AAS mortars, respectively. The... 

    Fabrication of granulated NaY zeolite nanoparticles using a new method and study the adsorption properties

    , Article Powder Technology ; Volume 231 , November , 2012 , Pages 1-6 ; 00325910 (ISSN) Charkhi, A ; Kazemeini, M ; Ahmadi, S. J ; Kazemian, H ; Sharif University of Technology
    2012
    Abstract
    NaY zeolite nanoparticles were synthesized and shaped into the uniform spherical granules using a developed novel and simple two-step granulation technique. First, the alginate/nanozeolite or alginate/nanozeolite-bentonite spherical hybrid was successfully fabricated, and then the alginate was decomposed by calcinations resulting uniform spherical granules. To improve the mechanical stability of the prepared granules, bentonite was added as an inorganic binder at different ratios of 20wt.% to 40wt.%. Moreover, the effect of binder on the ion exchange properties of the prepared granules was studied. Increasing of binder content from 20wt.% to 40wt.% linearly enhanced the mechanical stability... 

    Experimental studies on the effects of process parameters on granule properties in a conical high shear granulator

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 32, Issue 3 , 2013 , Pages 115-125 ; 10219986 (ISSN) Ranjbarian, S ; Farhadi, F ; Sharif University of Technology
    Jihad Danishgahi  2013
    Abstract
    Experimental work was carried out to investigate the influence of impeller speed, granulation time, binder mass and their interactions on granule size distribution, mean size and binder content distribution in a conical high shear granulator. It was observed that the response of high shear granulation to changes in process parameters varies significantly from one operating condition to another. For all quantities of binder, the granule mean size increased with time at lower impeller speeds, while the opposite trend was observed at higher impeller velocities. For long mixing times, increasing impeller speed decreased the granule average size constantly; whereas for other durations, an... 

    Experimental and probabilistic investigation on the durability of geopolymer concrete confined with fiber reinforced polymer

    , Article Construction and Building Materials ; Volume 334 , 2022 ; 09500618 (ISSN) Anvari, M ; Toufigh, V ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    This study investigates the durability of confined geopolymer concrete with fiber-reinforced polymer and compares the results with ordinary Portland cement concrete (OPCC). Two hundred and seventy geopolymer concrete (GPC) specimens with different mix designs (fly ash- and granulated blast furnace slag(GBFS)-based GPC) were prepared and then wrapped with two different fiber-reinforced polymers (carbon and glass FRPs). For 12,960 hrs (eighteen months), the specimens were exposed to four different pHs (2.5, 7 (water), 7.25 (saltwater), 12.5). The reliability analysis was performed after modeling the compressive strength over time. Based on the results, the ductility of all specimens decreased...