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    Environmental Impact of Seawater on GGBFS-Based Alkali-Activated Concrete

    , M.Sc. Thesis Sharif University of Technology Safavi, Alireza (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    This study seeks to compare the effect of curing conditions in the sea, coast, and middle of the island environment on five mix designs of alkali-activated concrete (AAC) based on ground granulated blast furnace slag (GGBFS) and fly ash (FA) and the effect of the ratio of sodium silicate (SS) to sodium hydroxide (SH) and alkali activated solutions (AAMS) to the binder on mechanical properties. The compressive strength and load-deflection test was conducted to obtain uniaxial compressive strengths (UCS), modulus of elasticity ("E" _"S" ), elastic and ultimate strain, and dissipated energy. The most significant decrease in strength was observed in the coastal area and the sea. Also, the... 

    Evaluation of Granularity of Reconfigurable Architectures for Wireless Communication Applications

    , M.Sc. Thesis Sharif University of Technology Nazarieh, Masoumeh (Author) ; Hemmat yar, Afshin (Supervisor)
    Abstract
    Wireless communication applications need high computing power, flexibility and scalability. Although ASICs have the ability of high computing power but they are not flexible to changing or completing of communication protocols. On the other hand, general purpose microprocessors or DSPs are flexible, but do not provide sufficient computing power. Thus devices with reconfigurable architecture have been proposed as a compromise between ASICs and microperocessors. One of the main features of reconfigurable devices is the granularity. The granularity of a reconfigurable devices shows the amount of computing power incorporate in a processing element. In this thesis we have evaluated different... 

    Fracture Toughness of Geopolymer Concrete Containing Blast Furnace Slag in Corrosive Environments

    , M.Sc. Thesis Sharif University of Technology Ziamiavaghi, Behanm (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Fracture Toughness of Geopolymer Concrete Containing Blast Furnace Slag in Corrosive Environments  

    The Durability of Geopolymer Concrete Confined with Fiber Reinforced Polymer Materials

    , M.Sc. Thesis Sharif University of Technology Anvari Sakhvidi, Mohammad Amin (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Material durability is quite critical in corrosive environments. In this study, two hundred and seventy geopolymer concrete specimens with different mix designs were prepared and then wrapped with two different fiber reinforced polymer (FRP) materials. For 12960 hrs (eighteen months), the specimens were exposed to four different pHs (2.5, 7, 7.25, 12.5). The reliability and SEM analysis were performed after modeling the compressive strength over time. Based on the results, the reduction of the compressive strength was up to 22% in an acidic environment. The compressive strength of the specimens was increased up to 11 percent after alkaline solution exposure. The ductility of all specimens... 

    Investigation of Mechanical Properties and Durability of Alkali-activated Slag Concrete Lightened with Scoria and Its Microstructural Study

    , M.Sc. Thesis Sharif University of Technology Mahmoudzadeh Vaziri, Nima (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    Concrete has long been one of the most widely used materials in the world. Cement, as a major component of concrete, due to the use of fossil fuels in its production process, emitting greenhouse gases such as carbon dioxide, which cause air pollution and environmental issues such as climate change. On the other hand, the wastes of industrial factories such as slag of the Blast furnace, due to their large volume and lack of sufficient space for storage of these wastes, lead to the release of these wastes that have alkaline structures into enviroment, causing environmental pollution Such as embankment pollution. Alkali-activated concrete has prevented the release of these pollutant into the... 

    Designing Granular Sequencing Batch Reactor for Investigating the Effect of Influent Feeding Alkalinity and Rreactor pH on Aerobic Granulation

    , M.Sc. Thesis Sharif University of Technology Rezasoltani, Samira (Author) ; Shaygan, Jalal (Supervisor)
    Abstract
    Laboratory experiments were carried out to investigate the effect of influent alkalinity and reactor pH on microbial species, morphology and performance efficiency of aerobic granules. The experiments were conducted in two L sequencing batch reactors (R1-R2) with different influent alkalinity and pH medium. pH in R1 ,with high influent alkalinity, was in the range of 7-7.5 and pH in R2 was adjusted in 4.5-5.5. The experimental results demonstrated that the dominated microbial species and structure of granules were different in two rectors. Acidic environment of R2 provide favorable condition for fungal growth and granules formed within first week of operation. On the other hand in R1,... 

    Phenomenological Study of Granulation by Investigating the Effects of Operating Parameters on Granule Properties

    , Ph.D. Dissertation Sharif University of Technology Ranjbarian, Sima (Author) ; Farhadi, Fathollah (Supervisor)
    Abstract
    The present thesis has provided more fundamental understanding of granulation rate processes (such as coalescence, attrition and breakage) by investigating the effects of operating parameters on product properties. The studied process was wet granulation carried out in two high shear mixer granulators. Granulation duration, binder mass and impeller speed were considered as operating parameters and granule size distribution (measured by sieving) and granule binder distribution (measured by thermogravimetery method) were regarded as product properties. Experiments were conducted in two analogous cylindrical and conical high shear granulators. The obtained experimental and theoretical results... 

    Modeling of Spray Granulation

    , M.Sc. Thesis Sharif University of Technology Hashemi Amrei, Mohammad Hossein (Author) ; Molaei Dehkordi, Asghar (Supervisor)
    Abstract
    Fluidized bed spray granulation is an important powder production process with several key advantages compared to other powder production processes, such as spray drying. Moreover, in fluidized bed granulators, whole process takes place in just one apparatus and there is no need to side processing. Most important characteristics and essential part of fluidized bed granulation is the wetting of primary particles by atomized liquid binder to coating the primary particles and producing granules. To date, a lot of research has focused on modeling and understanding of the separate particle growth mechanisms which have been integrated into the population balance models. Although, these concepts... 

    Design and Construction of Aerobic Granulation Reactor in Order to Study the Effect of Cationic Polymer on Granular Formation

    , M.Sc. Thesis Sharif University of Technology Jalali Varnamkhasti, Sajjad (Author) ; Shaygan Salek, Jalaloddin (Supervisor)
    Abstract
    Despite many advantages of granular sludge in anaerobic reactors (e.g. UASB), over the past few years research attention had turned towards developing aerobic granular sludge. Although much research is carried out on the formation of aerobic granules, less work is reported on how to enhance granules characteristics such as increasing in granule size, concentration, durability and stability. The aims of this study are to investigate the effects of cationic polymer on granule formation and the way to improve granule characteristics. For this purpose two SBR reactors (0.15 m diameter and 1.8 m height, R1 and R2) were used by feeding synthetic wastewater (diluted molasses, COD ranging from 1400... 

    Feasibility Study of Manufacturing of Disposable Plant Containers

    , M.Sc. Thesis Sharif University of Technology Hosseini Vala, Hamid (Author) ; Mostafavi, Mostafa (Supervisor)
    Abstract
    The aim of the present research is to analyse feasibility study of manufacturing the disposable (Biodegradable) plant containers in Iran. The population of the research consists of the whole capacity for manufacturing this product and the similar product producers which have been registered in the Ministry of Industry, Mines and Commerce. First, in this research, the environmental and anti-environmental impacts of non-plant Disposable Containers like: plastic, foam, paper and aluminum have been discussed and also their disadvantages have been examined to be compared with advantages of using plant Disposable Containers. Thereafter, collecting the required data about today society and market,... 

    A theoretical and experimental investigation of wastewater treatment for a polyethylene terephthalate production unit

    , Article Chemical Engineering Transactions ; Vol. 39, issue. Special Issue , 2014 , p. 751-756 ; 22839216 Vafajoo, L ; Mohammadpour, A ; Khorasheh, F ; Sharif University of Technology
    Abstract
    In this research, mathematical modelling of an anaerobic hybrid bioreactor for effluent treatment of a Poly-Ethylene Terephthalate (PET) unit in a petrochemical complex was performed. The developed model included a combination of a biofilm model for describing the substrate kinetics; a fluidized bed model for determination of species profiles along the reactor length and a bioreactor model for particle distribution inside the reactor. The reactions performed in the bioreactor included; i) the polymers hydrolysis; ii) fermentation of the resulting monomers; iii) the volatile fatty acids fermentation to Acetate and Hydrogen and iv) the Methane formation as the final product. The reactor was... 

    Discretized n-dimensional population balance for agglomeration

    , Article Industrial and Engineering Chemistry Research ; Volume 52, Issue 49 , December , 2013 , Pages 17487-17500 ; 08885885 (ISSN) Hashemi Amrei, S. M. H ; Molaei Dehkordi, A ; Sharif University of Technology
    2013
    Abstract
    In this article, a new method for solving multidimensional population balance (PB) equations for agglomeration is presented. First, discretized 2-dimensional PB (DPB) is derived and by applying probability approach, this method is extended to n-dimensional PB. The discretization of size intervals is in the form of v(j) = 2j-i v(i) and the volume based PB is used. Because of conservative nature of volume, all internal coordinates are converted to some independent volumes. A simple and clear procedure for solving multidimensional PB is proposed using probability concept. In addition, various types of birth and death mechanisms involved in PB are analyzed separately. Moreover, results of... 

    Evaluation of the effects of process parameters on granule mean size in a conical high shear granulator using response surface methodology

    , Article Powder Technology ; Volume 237 , 2013 , Pages 186-190 ; 00325910 (ISSN) Ranjbarian, S ; Farhadi, F ; Sharif University of Technology
    2013
    Abstract
    Response surface methodology was used to investigate the effects of operating parameters such as impeller speed, binder mass and granulation time on the average size of granules produced in a lab scale conical high shear granulator. Two quadratic models were proposed to express granule mean size as a function of impeller speed and binder mass as well as impeller speed and granulation time. It was found out that in the studied domain, the influence of each parameter on granule size differs from one another. While increasing binder mass at constant quantity of powder increased the average size linearly, increasing impeller speed changed the mean size in accordance with quadratic trend. The... 

    Experimental studies on the effects of process parameters on granule properties in a conical high shear granulator

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 32, Issue 3 , 2013 , Pages 115-125 ; 10219986 (ISSN) Ranjbarian, S ; Farhadi, F ; Sharif University of Technology
    Jihad Danishgahi  2013
    Abstract
    Experimental work was carried out to investigate the influence of impeller speed, granulation time, binder mass and their interactions on granule size distribution, mean size and binder content distribution in a conical high shear granulator. It was observed that the response of high shear granulation to changes in process parameters varies significantly from one operating condition to another. For all quantities of binder, the granule mean size increased with time at lower impeller speeds, while the opposite trend was observed at higher impeller velocities. For long mixing times, increasing impeller speed decreased the granule average size constantly; whereas for other durations, an... 

    Fabrication of granulated NaY zeolite nanoparticles using a new method and study the adsorption properties

    , Article Powder Technology ; Volume 231 , November , 2012 , Pages 1-6 ; 00325910 (ISSN) Charkhi, A ; Kazemeini, M ; Ahmadi, S. J ; Kazemian, H ; Sharif University of Technology
    2012
    Abstract
    NaY zeolite nanoparticles were synthesized and shaped into the uniform spherical granules using a developed novel and simple two-step granulation technique. First, the alginate/nanozeolite or alginate/nanozeolite-bentonite spherical hybrid was successfully fabricated, and then the alginate was decomposed by calcinations resulting uniform spherical granules. To improve the mechanical stability of the prepared granules, bentonite was added as an inorganic binder at different ratios of 20wt.% to 40wt.%. Moreover, the effect of binder on the ion exchange properties of the prepared granules was studied. Increasing of binder content from 20wt.% to 40wt.% linearly enhanced the mechanical stability... 

    Adsorption and diffusion of Xenon in a granulated nano-NaY zeolite

    , Article Adsorption ; Volume 18, Issue 2 , 2012 , Pages 75-86 ; 09295607 (ISSN) Charkhi, A ; Kazemeini, M ; Ahmadi, S. J ; Allahyar, S. A ; Sharif University of Technology
    Springer  2012
    Abstract
    Henry's law constant and crystal diffusivity of xenon in the granulated nano-NaY zeolite were measured by the pulse gas chromatography method. For this purpose the moments of response peaks of xenon were analyzed. The effect of extra column parts of the utilized chromatographic system was also considered by analyzing the moments of the response peak which was obtained by pulse injection of inert gas of helium into the carrier gas of nitrogen. In addition, the measurement of average velocity of the carrier gas regarding the pressure drop in the extra column parts of the system attributed to precise results. By carrying out the experiments at various temperatures in the range of 30-110 °C the... 

    Adsorption behavior of toxic metal Ions on nano-structured CuO granules

    , Article Separation Science and Technology (Philadelphia) ; Volume 47, Issue 7 , 2012 , Pages 1063-1069 ; 01496395 (ISSN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Sharif University of Technology
    2012
    Abstract
    In this study, copper oxide nano particles were synthesized by batchwise supercritical hydrothermal method. After preparation of CuO nano particles, they were immobilized into the porous matrix of sodium alginate. The drying process formed a very porous structure that is useful for enhancing of adsorption activity. Produced CuO particles were characterized by X-ray diffractometery (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and BET for measuring the surface area. The prepared materials were then used as adsorbent in the removal of toxic metal ions in aqueous solution. To optimize the adsorption system, the effect of various parameters such as adsorbent... 

    Effect of bentonite binder on adsorption and cation exchange properties of granulated nano NaY zeolite

    , Article Advanced Materials Research ; Volume 335-336 , 2011 , Pages 423-428 ; 10226680 (ISSN) ; 9783037852460 (ISBN) Amir, C ; Mohammad, K ; Javad, A. S ; Sareh, A. A ; Sharif University of Technology
    Abstract
    In order to investigate the effect of bentonite binder on adsorption and cation exchange properties of granulated nano NaY zeolite, the adsorption of Xe and N 2 and removal of Sr 2+ ion from aqueous solution was studied. The results showed that increase in bentonite content of granules from 20 to 40 weight percent caused increase in the rupture load of granules by 232%, decrease in BET surface area by 66% and lower the Sr 2+ uptake percentage by 35%. The Henry's law constant, heat of adsorption, effective crystal diffusivity as well as activation energy of diffusion of Xe over granulated nano NaY with 25% bentonite was also measured by pulse chromatography method. Obtained results were... 

    A simple granulation technique for preparing high-porosity nano copper oxide(II) catalyst beads

    , Article Particuology ; Volume 9, Issue 5 , 2011 , Pages 480-485 ; 16742001 (ISSN) Ahmadi, S. J ; Outokesh, M ; Hosseinpour, M ; Mousavand, T ; Sharif University of Technology
    Abstract
    A simple and efficient method was developed for fabricating spherical granules of CuO catalyst via a three-step procedure. In the first step, copper oxide nanoparticles were synthesized by hydrothermal decomposition of copper nitrate solution under supercritical condition. Then, they were immobilized in the polymeric matrix of calcium alginate, and followed by high-temperature calcination in an air stream as the third step, in which carbonaceous materials were oxidized, to result in a pebble-type catalyst of high porosity. The produced CuO nanoparticles were characterized by transmission electron microscopy (TEM) that revealed an average size of 5 nm, X-ray diffractometry (XRD), and thermo... 

    Granulated copper oxide nano-catalyst: A novel and efficient catalyst for C-N cross-coupling of amines with iodobenzene

    , Article Monatshefte fur Chemie ; Volume 142, Issue 8 , 2011 , Pages 801-806 ; 00269247 (ISSN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Abdollahi, M ; Sharif University of Technology
    Abstract
    Nano-structured CuO granules catalyze the C-N cross-coupling of amines with iodobenzene in excellent yields. The reaction is simple, efficient, and operates in air under ligand-free conditions