Sharif Digital Repository

In recent years, pozzolana are being increasingly used in different types of concretes and mortars. This investigation aims to evaluate the effect of replacing 7, 14, 21, and 28% cement (by weight) with silica fume (SF), granulated blast furnace slag (GBFS), zeolite, and fly ash (FA) under elevated temperatures. Forty mix designs were built with various water-to-cement ratios and plasticizers. Three hundred and six specimens were prepared, and the flexural, uniaxial compression and tensile tests were performed on specimens after exposure to elevated temperatures between 25°C and 900°C. The X-ray diffraction (XRD) test was then performed on the two series of specimens. Accordingly, the... 

This study investigates the durability of confined geopolymer concrete with fiber-reinforced polymer and compares the results with ordinary Portland cement concrete (OPCC). Two hundred and seventy geopolymer concrete (GPC) specimens with different mix designs (fly ash- and granulated blast furnace slag(GBFS)-based GPC) were prepared and then wrapped with two different fiber-reinforced polymers (carbon and glass FRPs). For 12,960 hrs (eighteen months), the specimens were exposed to four different pHs (2.5, 7 (water), 7.25 (saltwater), 12.5). The reliability analysis was performed after modeling the compressive strength over time. Based on the results, the ductility of all specimens decreased... 

This study was aimed at evaluating the effects of alkali activator solution and utilization of silica fume (SF) on durability and microstructural characteristics of alkali-activated ground granulated blast furnace slag (GGBFS) pastes. The pastes were activated with sodium silicate (SS) blended with NaOH (SH) solution with molar concentrations of 8 M, 12 M, and 16 M and SS:SH ratios of 1.0, 2.5, and 4.0. The same mixes were prepared with SF as partial replacement of GGBFS at a dosage of 10% by weight. The initial and final water absorption as well as the electrical resistivity of the specimens were measured. The optimal paste fabricated with 12 M NaOH solution and SS:SH ratio of 2.5 showed... 

This study was aimed at evaluating the effects of alkali activator solution and utilization of silica fume (SF) on durability and microstructural characteristics of alkali-activated ground granulated blast furnace slag (GGBFS) pastes. The pastes were activated with sodium silicate (SS) blended with NaOH (SH) solution with molar concentrations of 8 M, 12 M, and 16 M and SS:SH ratios of 1.0, 2.5, and 4.0. The same mixes were prepared with SF as partial replacement of GGBFS at a dosage of 10% by weight. The initial and final water absorption as well as the electrical resistivity of the specimens were measured. The optimal paste fabricated with 12 M NaOH solution and SS:SH ratio of 2.5 showed... 

Prior studies were conducted in an isolated manner for the use of glass powder (GP) either as ordinary Portland cement (OPC) replacement material in blended cement or as a precursor in AAM material. There was no reported literature that made a direct comparison on the properties of blended cement and AAM containing GP with an equivalent mix composition. The present study was aimed to evaluate and compare the effects of GP as a partial precursor on properties of both OPC and alkali-activated slag (AAS) mortars. For this purpose, cement and ground granulated blast furnace slag (GGBFS) was partially replaced with 10%, 20%, 30%, and 40% (by weight) GP in OPC and AAS mortars, respectively. The... 

In this paper, the optimum alkali activator solution properties in alkali-activated pastes based on ground granulated blast furnace slag (GGBFS) and micro-silica (MS) were investigated. For this purpose, sodium hydroxide (NH) solutions with molarities of 8 M, 12 M, and 16 M were prepared and mixed with sodium silicate (NS) solutions at NS:NH ratios of 1.0, 2.5, and 4.0 to produce the final activator solution. Two sets of pastes were manufactured: (1) pastes based on GGBFS, and (2) pastes in which 10% by weight of GGBFS was replaced with MS. The fresh density increased with increasing NH molarity and NS:NH ratio; whereas, the final setting time reduced with an increase in the aforementioned... 

Abstract Background: The aim of this study is to accelerate and improve aerobic granulation within a Sequencing Batch Reactor (SBR) by cationic polymer addition. Methods: To identify whether the polymer additive is capable of enhancing granule formation, two SBRs (R1 and R2, each 0.15 m in diameter and 2 m in height) are used by feeding synthetic wastewater. The cationic polymer with concentration of 30 to 2 ppm is added to R2, while no cationic polymer is added to R1. Results: Results show that the cationic polymer addition causes faster granule formation and consequently shorter reactor start-up period. The polymer-amended reactor contains higher concentration of biomass with better... 

Two sequencing batch reactors were operated to investigate the effect of influent alkalinity and reactor pH on aerobic granulation. In the first reactor R1 with high influent alkalinity the pH was adjusted in the neutral range, and in the second reactor R2 with low alkalinity the pH was held within the acidic range. The R1-dominating species were bacteria and the appearance time of granules was three weeks after reactor start-up. On the other hand, the acidic environment of R2 provided favorable conditions for fungal growth, and rapid granule formation occurred within the first week of operation. The varying microbial structure of granules resulted in different reactor performance in terms... 

In this article, a new method for solving multidimensional population balance (PB) equations for agglomeration is presented. First, discretized 2-dimensional PB (DPB) is derived and by applying probability approach, this method is extended to n-dimensional PB. The discretization of size intervals is in the form of v(j) = 2j-i v(i) and the volume based PB is used. Because of conservative nature of volume, all internal coordinates are converted to some independent volumes. A simple and clear procedure for solving multidimensional PB is proposed using probability concept. In addition, various types of birth and death mechanisms involved in PB are analyzed separately. Moreover, results of... 

Response surface methodology was used to investigate the effects of operating parameters such as impeller speed, binder mass and granulation time on the average size of granules produced in a lab scale conical high shear granulator. Two quadratic models were proposed to express granule mean size as a function of impeller speed and binder mass as well as impeller speed and granulation time. It was found out that in the studied domain, the influence of each parameter on granule size differs from one another. While increasing binder mass at constant quantity of powder increased the average size linearly, increasing impeller speed changed the mean size in accordance with quadratic trend. The... 

Experimental work was carried out to investigate the influence of impeller speed, granulation time, binder mass and their interactions on granule size distribution, mean size and binder content distribution in a conical high shear granulator. It was observed that the response of high shear granulation to changes in process parameters varies significantly from one operating condition to another. For all quantities of binder, the granule mean size increased with time at lower impeller speeds, while the opposite trend was observed at higher impeller velocities. For long mixing times, increasing impeller speed decreased the granule average size constantly; whereas for other durations, an... 

NaY zeolite nanoparticles were synthesized and shaped into the uniform spherical granules using a developed novel and simple two-step granulation technique. First, the alginate/nanozeolite or alginate/nanozeolite-bentonite spherical hybrid was successfully fabricated, and then the alginate was decomposed by calcinations resulting uniform spherical granules. To improve the mechanical stability of the prepared granules, bentonite was added as an inorganic binder at different ratios of 20wt.% to 40wt.%. Moreover, the effect of binder on the ion exchange properties of the prepared granules was studied. Increasing of binder content from 20wt.% to 40wt.% linearly enhanced the mechanical stability... 

Henry's law constant and crystal diffusivity of xenon in the granulated nano-NaY zeolite were measured by the pulse gas chromatography method. For this purpose the moments of response peaks of xenon were analyzed. The effect of extra column parts of the utilized chromatographic system was also considered by analyzing the moments of the response peak which was obtained by pulse injection of inert gas of helium into the carrier gas of nitrogen. In addition, the measurement of average velocity of the carrier gas regarding the pressure drop in the extra column parts of the system attributed to precise results. By carrying out the experiments at various temperatures in the range of 30-110 °C the... 

In this study, copper oxide nano particles were synthesized by batchwise supercritical hydrothermal method. After preparation of CuO nano particles, they were immobilized into the porous matrix of sodium alginate. The drying process formed a very porous structure that is useful for enhancing of adsorption activity. Produced CuO particles were characterized by X-ray diffractometery (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and BET for measuring the surface area. The prepared materials were then used as adsorbent in the removal of toxic metal ions in aqueous solution. To optimize the adsorption system, the effect of various parameters such as adsorbent... 

An integrated approach is presented for predicting granule particle size using Partial Correlation (PC) analysis and Artificial Neural Networks (ANNs). In this approach, the proposed model is an abstract form from the ANN model, which intends to reduce model complexity via reducing the dimension of the input set and consequently improving the generalization capability of the model. This study involves comparing the capability of the proposed model in predicting granule particle size with those obtained from ANN and Multi Linear Regression models, with respect to some indicators. The numerical results confirm the superiority of the proposed model over the others in the prediction of granule... 

This paper presents an experimental study on prediction of the early-age creep and shrinkage of concrete with and without silica fumes, trass, ground-granulated blast-furnace slag, combinations thereof, and influences of the proposed Iranian pozzolans. Experiments were carried out under a controlled ambient condition at a temperature of 40° C and a relative humidity (RH) of 50%, and a laboratory ambient condition at a temperature of 20° C and a relative humidity (RH) of 30% in order to collect the required data. Comparisons are made between ACI209-92, BS8110-1986 and CEB1970 prediction models, and an estimation model, based on 28-day results (short-term test method), using the same... 

In this research, an attempt was made to investigate the potential of nanophotocatalysts for treatment of hazardous wastewater streams. Titanium dioxide nanoparticles (as photocatalyst) were immobilized on a porous and low-density support called "perlite" using a very simple and inexpensive method. TiO2-coated perlite granules were used in a "Floating-bed photoreactor" to study the photocatalytic purification process of a typical wastewater polluted by furfural. The effects of initial concentration, catalyst mass/solution volume ratio, oxidant molar flow, residence time, and light intensity on process removal efficiency, and kinetics of the reactions were studied. SEM analyses showed a...