Sharif Digital Repository

In this research, results obtained on the growth kinetics of γ′ precipitates in superalloy IN-738LC are presented. It was found that when the coarsening of primary and secondary γ′ are considered together, the overall kinetic of coarsening followed a linear trend, as predicted by Lifshitz, Slyozov and Wagner (LSW) theory. However, when only the population of secondary γ′ was taken into account, growth rate for the secondary γ′ departed from the linear trend predicted by the theory. It is therefore suggested that the observed deviation of coarsening kinetics from linear behavior may be related to the short inter-particle distances in this system which caused elastic interaction energy to... 

ABSTRACT: Pyrolysis, so-called devolatilization, is one of the first steps of all thermochemical processes occurring in an inert atmosphere. The authors discuss the main kinetic features of heavy oil pyrolysis, on the basis of the data derived m from a TGA analysis and by using a kinetic model. The samples were heated over a range of temperature from 400 K to 430°C at various heating rates between 10 and 80°C/min. Experimental results showed that the effect of time is considerable in the case of tar conversion, compared to char and gases  

Branched hierarchical zinc oxide nanowires (BH-ZnO NWs) were fabricated successfully by a facile and rapid synthesis using two-step growth process. Initially, ZnO NWs have been prepared by anodizing zinc foil at room temperature and followed by annealing treatment. Then, the BH- ZnO NWs were grown on the ZnO NWs by a solution based method at very low temperature (31 oC). The BH- ZnO NWs with different aspect ratio were obtained by varying reaction time (0.5, 2, 5, 10 h). Photocatalytic activity of the samples was studied under both UV and visible light. The results indicated that the optimized BH-ZnO NWs (5 h) as a photocatalyst exhibited the highest photoactivity with about 3 times higher... 

Effect of NaF on crystallization kinetics, microstructure, and mechanical properties of mica glass ceramics were investigated by the differential thermal analysis (DTA), X-ray diffractometry (XRD), scanning electron microscopy (SEM), and microhardness tests. Non-isothermal DTA experiments showed that the crystallization activation energies of base glasses are changed in the range of 235-246 KJ/mol, while the crystallization activation energies of samples with addition of NaF are changed in the range of 263-367 KJ/mol. The increase of crystallization temperature is helpful for the increase of aspect ratio, and the microstructure of the glass ceramics becomes interconnected, which contributes... 

The influence of Zr 2 on the crystallization behavior, microstructure, and machinability of SiO 2-Al 2O 3-MgO-K 2O-B 2O 3-F glasses was investigated. The crystallization of the glass-ceramic was markedly affected by addition of ZrO 2. These glasses crystallize more rapidly. The number of mica crystals increases, whereas the size of the mica crystals decreases drastically. Machining of these glass-ceramics was found to be good, as confirmed by a drilling test using conventional steel tools. Such mechanical properties are attributable to the microstructure of these glass-ceramics. Very fine crystals are homogeneously distributed in glass matrix  

Non-isothermal differential thermal analysis (DTA), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used to study the nucleation and crystallization behavior of mica glass-ceramics with LiF as nucleating agent. The models enabled establishing the kinetic parameters for crystal growth of individual phases. The activation energies for crystal growth were found to be in the range of 161-301 KJ/mol, 416-424 KJ/mol, and 583-1011 KJ/mol for base glasses, samples with substitution of Li2O for K2O and samples with addition of LiF, respectively. Formation of transparent glass-ceramics from studied glass-samples has been investigated. Transparency is assumed to occur in the... 

Nowadays cobalt is mostly produced through the electrowinning process of sulfate solutions. Regarding to the competition between the precipitation of cobalt ions and evolution of hydrogen gas on the cathode surface during the reduction process in a sulfate bath, investigation on the mechanism of metal precipitation is of great importance. In the present work, study on the kinetics of cobalt electrowinning and the mechanism of the involved reactions have been carried out. The obtained results, confirm the mechanism of cobalt precipitation by depletion of hydroxides. The effects of temperature and scan rate parameters were studied on electrowinning of cobalt by cyclic voltammetry technique.... 

In this study chitosan hydrogel beads with porosity ∼ 0.86 and diameter ∼ 2 ± 0.07 mm were prepared from 85 % deacetylated chitosan for removal of Cd2+ ions from aqueous solutions. Chitosan powder was dissolved into dilute acetic acid as solvent and formed into spherical beads using a phase inversion technique. The effect of temperature, initial concentration of Cd2+ ions, and the period of agitation were perused to achieve the best isotherm model. Freundlich model was better fitted than Langmuir model (R2 > 0.99 and R2> 0.93 respectively, at pH of 6.3, and shaker speed of 200 rpm), the constants of Langmuir and Freundlich models were calculated, which RL value and qmax (mg/g wet weight) at... 

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing [Pd(NH3)4]2+ (0.02 M) and [Fe-Citrate]2+ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dis-persive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates – brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) – Fe content of the electrodeposited alloys increases by increasing the overpotential.... 

Microbial cells are producers of natural polymers present in plant cells. Production of pullulan (an extracellular microbial polysaccharide) by Aureobasidium pullularia pullulans (P. pullulans) was studied under fermentation conditions, and kinetic parameters were determined. Pullulan formation obeyed a growth and non-growth associated term. PHB (polyhydroxybutyrates) an intracellular biopolymer production by Rastonia eutropha (Alcaligen eutrophus), R. eutropha was studied under different culture media, including synthetic and natural carbon sources. Molasses as a natural carbon source in the culture media presented high efficiency in cell and biopolymer accumulation  

It is well known that the direct synthesis of Di-Methyl Ether (DME) from the Syngas is highly exothermic; therefore, the temperature control for its production and hence a suitable heat transfer pattern is of ought most significance to the success of such process. As such, slurry bubble column reactor is recognized to be a more suitable means for this purpose than other choices including fixed bed reactor which is the usual type of system in which direct DME synthesis takes place. In other words, slurry reactors are desirable due to having suitable heat and mass transfer properties. In this research a mathematical model for direct synthesis of DME from synthesis gas in a slurry reactor for a... 

In this research work, the pressure leaching of chalcopyrite concentrate with oxygen was studied. Experiments were carried out under conditions of the solid–liquid ratio of 0.1, agitation speed of 750 rpm, and sulfuric acid concentration of 2 M in a stainless-steel autoclave system under 0.6 to 1 MPa oxygen gas. Central composite design was used to design experiments, and three factors of temperature, time, and oxygen pressure were selected as the design variables. A linear model for %Cu and a quadratic model for %Fe were proposed by Minitab Software. The results showed that temperature is the most effective factor in chalcopyrite leaching. Under optimal conditions, 93.08% of copper with the... 

We have investigated different algorithms for the simulation of kinetics of small systems. We have simulated the first order reversible reaction with the Gillespie, Gibson and Brack time simulation as a function of Poisson distribution and compared the results of three algorithms. We have also simulated intracellular viral kinetics for a genome with Gillespie and Poisson distribution algorithms  

BACKGROUND: Medial thrust (MT) gait is a nonsurgical approach for reducing the knee adduction moment (KAM) in patients with knee osteoarthritis. However, its usefulness is indeterminate due to scarcity of research about changes in lower extremity kinetics and the ground reaction force (GRF) which have been investigated in this study. MATERIALS AND METHODS: Twenty patients (6 males, 14 females, age: 56.2±6.2 years) with medial knee osteo-arthritis participated in this cross-sectional study. A 12-camera motion analysis system and two force plates recorded kinematic and GRF data while participants walked barefoot along a 12m path with 1) their regular gait pattern and 2) MT gait pattern. The... 

In this investigation, we have studied the kinetics and mechanism of formation and desorption of H2S on the Pt(111) surface using a kinetic random walk model. The effect of temperature on the H2S formation was studied in the range of 85-150 K. It was observed that a maximum amount of H2S is formed at 90 K and the amount is reduced at higher temperatures. H2S production yield as a function of time at different initial sulfur coverage ranging from 0.02 to 0.33 ML (1 ML ≃ 1 x 1015 atoms/cm2) was also examined. It was obvious that as the initial S coverage increases, the rate of H2S formation rapidly increases and reaches a maximum value and then declines gradually. Furthermore, according to our... 

A simple optimization methodology is applied to estimate the intrinsic kinetic parameters for both reversible and irreversible unireactant immobilized enzyme systems that follow the Michaelis-Menten mechanism. The method utilizes a direct-search optimization algorithm along with the numerical solution of the governing differential equations. The usefulness and validity of the method is demonstrated by comparing the predicted values of the intrinsic kinetic constants using the proposed method with a series of experimental values reported in the literature for different immobilized enzyme systems with irreversible and reversible reactions  

Optimization based on appropriate parameters can be applied to improve a process. Mazut degradation as a critical issue in environment requires optimization to be efficiently done. To provide biodegradation conditions, experiments were designed on the least interactions among levels of parameters consisting of pH, Tween 80, glucose, phosphorous source, nitrogen source, and time. Kinetic constants and biomass were calculated based on 16 assays, designed using Taguchi method, which constructed various mazut biodegradation conditions. Kinetics of mazut degradation by newly isolated bacteria Enterobacter cloacae closely followed second order kinetic model. Results of the 16 experiments showed... 

A chemical kinetic model for i-butane and n-butane catalytic cracking over synthesized HZSM-5 zeolite, with SiO 2/Al 2O 3 = 484, and in a plug flow reactor under various operating conditions, has been developed. To estimate the kinetic parameters of catalytic cracking reactions of i-butane and n-butane, a lump kinetic model consisting of six reaction steps and five lumped components is proposed. This kinetic model is based on mechanistic aspects of catalytic cracking of paraffins into olefins. Furthermore, our model takes into account the effects of both protolytic and bimolecular mechanisms. The Levenberg-Marquardt algorithm was used to estimate kinetic parameters. Results from statistical... 

Many important problems in Computational Geometry needs to perform some kind of angle processing. The Polar Diagram [4] is a locus approach for problems processing angles. Using this structure as preprocessing, one can eliminate exhaustive searches to find objects with smallest angle. Handling data in change is a significant concept in Computer Science. One of the design and analysis tools used in the modeling of moving geometric objects is the kinetic data structure (or KDS) framework Kinetic Data Structure is a framework for maintaining a certain attribute of a set of objects while moving in a continuous manner. In this paper, we use the notion of kinetic data structure to model the...