Sharif Digital Repository

Since, presence of sulfur compounds in fuels leads to environmental pollution and deacrese of fuel quality, fuel desulfurization should be considered for enhancing the fuel charachteristics. Electrochemical desulfurization was recogonized as one of desulfurization techniques that uses anode and cathode in an electrolytic environment under mild temperature and pressure. In this research, electrochemical desulfurization of crude gas-oil has been studied over electrodes of copper and stainless steel in the presence of NaOH and sulfuric acid. In this research, the effects of operational prameters like stirring rate, temperature, applied potential, sodium hydroxide/sulfuric acid addition as... 

Surfactants are widely used in enhancing oil recovery. But application of worm-like micelles which seem to be a perfect candidate for enhancing heavy oil recovery have been less studied despite their significant ability in reducing interfacial tension and their high viscosity. This research consists of three parts. In the first part, the kinetic and equilibrium adsorption of surfactant on reservoir rock is experimentally investigated, and its appropriate kinetic and equilibrium adsorption model is specified. According to the adsorption models, the pseudo second order kintic coefficient of adsorption is proved to have a linear relationship with concentration, so its value at different... 

In this research, we have tried to predict the morphology of the membranes that were prepared by phase inversion method. In this research Polyvinylinedifluoride (PVDF) and dimethylacetamide (DMAc) was used as the polymer and solvent. The affect of titanium oxide (TiO2 ) and polyvinylpyrolidene (PVP) which are respectively an inorganic and an organic additive, on the morphology of the membranes was investigated. Ternary and Quadratic phase diagrams were drawn based on the Flory Huggins theory. The interaction between components was determined and the effect of interactions and molar volumes of polymer, solvent, non-solvent and additives on the binodal line was investigated. To predict... 

In this work, annealing procedure of cold-deformed AA5052-SiC composite has been simulated by using cellular automata approach and the effect of SiC second phase on softening kinetics has been studied. To do so, site saturated nucleation has been employed to establish initial microstructure. In addition, topological changing due to deformation has been implemented on the microstructure. During annealing, recovery and recrystallization phenomena occur simultaneously, and it has strong effect on the annealed microstructure. Therefore, during annealing, recrystallization and recovery has been considered simultaneously and decreasing in the stored energy, which has developed during deformation... 

Water flooding is known as a common method to maintain reservoir pressure/enhance oil recovery. The major problem in this process induced from inorganic deposits that caused formation damage around wellbore region. It is due to incompatible nature of injected and formation water which results in permeability reduction and well productivity decrease. Solving this problem is an important issue in the petroleum industry. BaSO4, CaSO4 and SrSO4 are inorganic sediments formed in this process. The physical model of water transport in reservoir and scaling damage due to sediments contains at least two dominant parameters; the kinetics coefficient that specifies the velocity of chemical reaction,... 

In 1989 DiPerna and Lions proved the stability of Boltzmann’s evolution equation using their theory of renormalized solutions. Their result , for the first time, proved the existence of solutions without extra assumptions on the initial condition and on arbitrary time intervals. While the wellknown Grad’s cut-off assumption is present in the original theory, there have been successful generalizations to account for the singular case. Also the renormalization theory has shed light on limiting regimes of the Boltzmann equation. Here we discuss the new techniques that are essential for such generalizations  

The kinetics of side reactions in dehydrogenation of propane over a supported platinum catalyst modified by tin was investigated. Catalytic dehydrogenation over a commercial Pt-Sn/γ-Al2O3 was carried out in a laboratory-scale plug-flow reactor at 580 to 620oC under atmospheric pressure. Several kinetic models derived from different reaction mechanisms were tested using experimental data obtained over a range of reaction conditions. It was found that the kinetics of the main dehydrogenation reaction was best described in terms of a Langmuir-Hinshelwood mechanism where adsorption of propane was the rate controlling step. Simple power low rate expressions were used to express the kinetics of... 

Modified zeolitic nanostructures were prepared by sol-gel, hydrothermal and coprecipitation methods. At first step, natural zeolite was used as a support for preparing the Ag/AgBr/TiO2 photocatalysts. Their photocatalytic properties were studied by degradation of pollutants and microorganism inactivation at the presence of different illumination source. These processes were mechanistically investigated and the results were explained. At second step, mordenite anocrystals, which synthesized by hydrothermal method, were used as an effective support to prepare the AgX/TiO2/MOR photocatalysts. Photocatalytic degradation of an azo dye performed over these nanocomposites and a mechanism suggested... 

Fighting contagious microbial diseases is considered a serious health issue, which has attracted much attention in worldwide. Thus, development of new materials based on nanostructures as a new generation of antibiotics to address this challenge has been of interest to researchers in recent years. Nanostructures based on metallic oxide semiconductors such as oxides with light absorption, production of electron-hole pairs in needle like structures cause tearing bacterial membrane and eventually destroy the bacterium. To this end, we designed experiments to study mechanism and physics governing the process of bacterial degradation to determine the best conditions for inhibiting bacteria... 

N, N′, N″-triethylenethiophosphoramide (Thiotepa) and its oxo analogue (Tepa) as the major metabolite are trifunctional alkylating agents with a broad spectrum of antitumor activity. In vivo and vitro studies show alkylation of DNA by Thiotepa and Tepa can follow two pathways, but it remains unclear which pathway represents the precise mechanism of action. In pathway 1, these agents are capable of forming cross-links with DNA molecules which can be carried out via two different mechanisms. In the first mechanism, the ring opening reaction is initiated by protonating the aziridine, which then becomes the primary target of nucleophilic attack by the N7-Guanine of DNA. The second one is the... 

In this study, static recrystallization (Rex) of a low carbon steel after cold rolling has bees simulated under non-isothermal condition by employing cellular automata (CA) method. Symmetric cold rolling and asymmetric cold rolling (ASR) which was arisen by inequality of friction coefficient have been applied as primary cold deformation. Residual stress and strain field after deformation, and temperature rate and distribution of specimens during annealing has been evaluated by employing two different models based on finite element method. Initial microstructure has been developed by haphazardly distribution of grains and topological adjustments were imposed on it. Results of FEM models were... 

Dimethyl Ether (DME) is a pure and economic fuel which can be used as a suitable alternative for diesel fuels. Two processes are traditionally used for DME synthesis: producing methanol from synthesis gas and then dehydrating it to DME (direct process), and converting methanol into DME in a catalytic dehydration reactor over a solid-acid catalyst (indirect process), in which the indirect process seems to have economical advantage. In this research, the γ-Al2O3 catalyst was synthesized through precipitation process and then characterized by powder X-ray diffraction (XRD) and porosimetry analysis. Afterwards this catalyst was utilized in methanol dehydration reaction in a slurry reactor. Next,... 

Nanocrystallization kinetics of amorphous Finemet-type alloys was studied using Isokinetic and Isoconversional methods (Kissinger model-fitting method, Vyazovkin advance method, Kissinger–Akahira–Sunose(KSA),Flynn–Wall–Ozawa(FWO),Tang and Starink) under isothermal and non-isothermal conditions. Effects of chemical composition on the nanocrystallization kinetics, microstructure and magnetic properties of Fe73.5Si13.5B9Nb3Cu1 and Fe77Si11B9Nb2.4Cu0.6 alloys were also investigated. Kinetic triplet (activation energy, frequency factor and reaction model) were determined by these methods and compared for the alloys. According to isoconversional methods, the activation energy is variable as a... 

In this work, the deformation behavior of an Aluminium-Magnesium alloy i.e. AA5052, in different temperature ranges was studied experimentally and theoretically. For this purpose, uniaxial tensile tests were carried out in the temperature range of 25°C to 450°C and under strain rates of 0.001 "s-1" to 0.05 "s-1" . Also, the occurrence of dynamic strain aging and dynamic softening mechanisms of the alloy were taken into account. It was observed that the dynamic strain aging occurred in the temperature range of 25°C to 125°C while the corresponding activation energy was defined as 46.2 kJ/mol which is close to migration of Mg atoms in aluminum. At hot deformation region, different softening... 

Bimetallic nanoparticles with unique structure, synergistic effect between two metals, and the tunable physical/chemical properties have been used for catalysis. Various methods exist for the staibility, and improvement of the catalytic performance of nanoparticles. In this thesis, different co-catalysts were applied to increase tha staibility, and activity of nanoparticles and metal oxides. In this way, Ni-based bimetallic nanoparticles including CuNi, CoNi, and AgNi, and AgPt with different concentrations were synthesized on the cerium oxide nanorods derived from cerium metal-organic frameworks and magnetic graphene oxide nanosheets, respectively and characterized. The catalytic... 

Nowadays, due to limitation of production from conventional oil reservoirs, enhanced recovery from heavy oil reservoirs is of great concern. However, production from these energy resources is not a simple task and production using common technologies is not easily exploitable. Heterogeneous structure and also high surface tension between injected fluid and reservoir oil are of the main challenges during water flooding processes in heavy oil reservoirs. The high surface tension force causes a large part of the oil remains in the reservoir after the water flooding operation. One method for overcoming this problem is the use of surfactants that reduces capillary forces and consequently... 

In this thesis, reactivity controlled compression ignition (RCCI) combustion fueled by diesel and natural gas is experimentally and numerically investigated. Natural gas as a fuel with low reactivity is injected into the intake manifold, and diesel as a fuel with high reactivity is injected directly into the combustion chamber. One of the main goals of this thesis is to experimentally examine the effect of important parameters on combustion phasing control, operational range extension, and pollutants. Natural gas is one of the important sources of energy in Iran and the world. Using natural gas in internal combustion engines can cause methane to slip into the atmosphere and intensify the... 

Moving data is becoming more and more important in different areas such as air traffic control, mobile communications, geographical information systems, GPS and other advanced technologies. In most cases, the path trajectory of such moving data is not known in advance. Moreover, they can change the direction and their speed of motion. Recently, a moving model, called black box model, has been proposed for such environments. In this model, there is a sequence of time stamps in which the position of each object is reported and the maximum displacement of each object in a time step is bounded by a known constant, dmax. In this thesis, we use this model to solve some computational... 

This thesis is devoted to the study of suitable functional frameworks for proving propagation of chaos and mean-field limit of nonlinear Vlasov-type equations for indistinguishable particles. The Kac model is a classic example and the motivation of this functional structure. On the one hand, Kac considered a spatially homogeneous gas, and on the other hand, he reduced the problem to one-dimensional collisions and dropped the conservation of momentum assumption. Therefore, he obtained a simplified version of the Boltzmann equation, which is named after him, the Kac equation. The main results which we study are quantitative estimates
on the decay of fluctuations around the deterministic... 

In order to obtain more insight into the enzymatic oxygen-atom-transfer (OAT) process and elucidate the relation between the structure and function of the synthetic model complexes, new molybdenum and tungsten complexes containing different chelating ligands were systematically prepared and investigated. Herein, the cis-dioxo-molybdenum(VI) complexes with new aromatic dithiolene ligands, formulated as [MoO2(2,3ppdt)2]NR4 and [MoO2(3,4ppdt)2]NR4, (2,3ppdt= pyrido-2,3-pyrazine-2,3-dithiolato, 3,4ppdt= pyrido-3,4-pyrazine-2,3-dithiol and R= Et or Bu) were prepared and investigated by elemental analysis, IR, 1H NMR and UV-Vis spectroscopic methods. An OAT reaction of [MoO2(2,3ppdt)2]2– with PPh3...