Sharif Digital Repository

Precipitation is an important stage of the Bayer process. For simulation of this section, growth-rate estimation of Al(OH)3 crystals, is vital for the solution of population balance. Various published equations for linear growth rate of Al(OH)3 are reviewed. In all of these equations, a square exponent was considered for supersaturation terms. In some of the previous works, it was believed that BCF model is the governing mechanism for surface growth of crystals. It is shown that polynuclear model is the most probable mechanism. Also, a modification of the best previous correlation is performed, which results in a considerable improvement of the growth-rate estimation over the available... 

CdS nanocrystals were prepared through a thermally activated (thermochemical) method. The synthesis was performed in two different oxygen-saturated and Ar purged atmospheres. Na2S2O3 was used as a heat-sensitive source of S in the experiments. Thioglycerol was also applied as the capping agent to restrain the growth. The growth was activated by heating and controlled by solution pH. The results demonstrated a considerably higher luminescence intensity for the synthesis in oxygen-saturated atmosphere. This could show the role of luminescent oxygen trap states created inside the CdS nanocrystals. The improved luminescence was observed for the synthesis at different solution pHs. Nevertheless,... 

Purpose: Does the long-term growth rate of a firm increase by exporting? If yes, how large is that increase in a developing economy? The paper aims to discuss this issue. Design/methodology/approach: The authors incorporate data from the manufacturing plants in Iran as a developing economy for 2003–2011 to address this question. Using fixed effect panel and propensity score matching method, the authors examine whether exportation can affect a firm’s growth rate to test for the learning to grow hypothesis. Findings: The findings document that: not only the exporters are larger and more productive than non-exporters, but they also grow faster in size and productivity measures as well.... 

We carry out an exact analysis of the average frequency ν+ αxi in the direction x i of positiveslope crossing of a given level α such that, h(x, t) h = α, of growing surfaces in spatial dimension d. Here, h(x, t) is the surface height at time t, and h is its mean value. We analyze the problem when the surface growth dynamics is governed by the Kardar-Parisi-Zhang (KPZ) equation without surface tension, in the time regime prior to appearance of cusp singularities (sharp valleys), as well as in the random deposition (RD) model. The total number N + of such level-crossings with positive slope in all the directions is then shown to scale with time as t d/2 for both the KPZ equation and the RD... 

This mini review article, intends to provide the essential information about microemulsion technique as a reliable approach toward the synthesis of zeolitic nano crystallites. The strategy discussed here provides a unique, effective, and potentially general methodology to the preparation of uniform and high purity nano crystallites of template-free zeolitic materials including LTA, faujasite type and other zeolitic-like materials (i.e. zeotype materials). Microemulsion is a reliable approach for controlled synthesis of uniform nano sized zeolitic particulates. On the other hand, the microwave assisted microemulsion technique has the advantages of short reaction time, producing smaller and... 

Economists and policy-makers believe that the Fiscal Decentralization is an effective strategy to promote economic growth. Thereby Economic Growth is seen as an objective of Fiscal Decentralization and efficiency in the allocation of resources in the public sector. This study analyzed the relationship between fiscal decentralization and economic growth in Iran for the period 2001-2007.We used data for 28 provinces of the country estimated the model using a panel data regression with Fixed Effect. We find that fiscal decentralization has a positive effect on Iran's economic growth  

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing [Pd(NH3)4]2+ (0.02 M) and [Fe-Citrate]2+ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dis-persive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates – brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) – Fe content of the electrodeposited alloys increases by increasing the overpotential.... 

Cu-2.7 vol.% Al2O3 (15 nm) composite was synthesized by an internal oxidation and hot extrusion process. The grain growth at elevated temperatures was studied and compared with extruded copper powder. Abnormal grain growth via a mechanism analogous to that of site-saturated phase transformation was observed. The critical grain size for the abnormal growth was determined to be 1.1 ± 0.2 μm. The growth rate decreased with time until the grain size approaching a final value ranging from 7.9 to 13.3 μm depending on the temperature. © 2008 Acta Materialia Inc  

Crystal-size distribution (CSD) is one of the most important parameters in sugar production. The objective is to grow crystals of uniform sizes or narrow CSD. CSD appears to be determined by the growth-rate history of the crystals and the relative supersaturation (SS) of the solution from which crystals growth takes place. Three methods for preparation of nucleation seeds were described and used for industrial crystallization of raw and white sugars; these are wet milling filtered sugar (ML), agitating saturated solution (AS) and powdered sugars (PD). Rosin-Rammler (RR) and mathematical models were adopted to investigate CSD and the uniformity of the produced crystals. Higher uniformity... 

In this study, the kinetics of nanocrystallization of amorphous Fe 73.5Si13.5B9Nb3Cu1 (F1) and Fe77Si11B9Nb2.4Cu0.6 (F2) alloys is investigated. The microstructure and magnetic properties of the nanocrystalline alloys are compared. The crystallization temperature of F2 alloy is shifted towards lower temperatures with respect to F1. Thus, the crystalline volume fraction and the crystalline grain size at specific annealing temperature for the F2 alloy are higher than for the F1 alloy, accounting for the higher coercive force of F2 alloy with respect to the one of F1 alloy. According to isoconversional methods, the activation energy for crystallization is variable as a function of transformed... 

This paper provides an empirical analysis of the principal determinants of post-conflict economic transitions during the period 1960-2010 using a dynamic panel estimation approach. In addition to demographic, economic, geographic, and institutional variables, we introduce a novel measure of conflict recurrence risk, estimated with a logistic regression approach controlling for unobserved fixed effects in a non-linear probability model. The empirical results show that the risk of conflict recurrence is a significant determinant of post-conflict economic performance, even after controlling for a broad set of demographic, economic, geographic, and institutional factors  

Up to now, attempts for developing coarse-grained SnO2-based varistors which exhibit high nonlinearity property at lower voltage have become a challenge without any prominent result because of its unknown grain growth mechanism. In this study, the effect of CuO addition to SnO2-based varistors as a grain growth enhancer additive on microstructural development, grain growth kinetics, and electrical properties was investigated. The characterization of grain growth kinetics showed that CuO addition encouraged grain growth and enhanced the grains size as it could be seen in the activation energy which decreased from 594 kJ/mol to 364 kJ/mol. In the samples with a low amount of CuO, the solute... 

The early stages of nucleation and growth of nanostructures can control the shape and final size of the fabricated nanostructure. Therefore, the study of the nucleation and growth mechanism of nanostructures is of great importance. The purpose of this study is to investigate the nucleation and growth mechanism of nickel nanocones from a chloride-based bath containing ethylene ammonium dichloride as a crystal modifier. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronoamperometry tests were employed to investigate the nucleation and growth mechanism and also the mechanism of crystal modifier performance on the growth of nanocones. Electrochemical studies revealed... 

A master equation for the Kardar-Parisi-Zhang (KPZ) equation in 2+1 dimensions is developed. In the fully nonlinear regime we determine the finite time scale of the singularity formation in terms of the characteristics of forcing. The exact probability density function of the one point height field is obtained correspondingly  

The aim of this article is to study the growth rate of intermetallic compounds at the interface of cold roll bonded Al/Cu bimetal at 250°C and compare the results with a similar study performed on friction welding of Al to Cu. Samples of tri-layered Cu-Al-Cu composite were produced by the cold roll welding process and heat treated at constant temperature of 250°C for 1 to 1000 h. The thickness, morphology and composition of the intermetallic compound at the interface of Cu and Al were studied by optical and scanning electron microscope and EDX analyzer. The presence of various intermetallic compounds (Cu3Al, Cu4Al3, CuAl and CuAl2) was detected and the priority of formation of each compound... 

Objective: This study aimed to present and evaluate a new deep learning model for determining cervical vertebral maturation (CVM) degree and growth spurts by analyzing lateral cephalometric radiographs. Methods: The study sample included 890 cephalograms. The images were classified into six cervical stages independently by two orthodontists. The images were also categorized into three degrees on the basis of the growth spurt: pre-pubertal, growth spurt, and post-pubertal. Subsequently, the samples were fed to a transfer learning model implemented using the Python programming language and PyTorch library. In the last step, the test set of cephalograms was randomly coded and provided to two... 

Growth mechanism of a single wall carbon nanotube on the surface of a nickel nanoparticle in the CVD method has been investigated by classical molecular dynamics method. Using first principles methods, we have first constructed a classical potential to describe the interaction between a carbon atom and the nickel surface. The important ingredient in this potential is its coordination number dependence, which also provides the key to the growth mechanism of the nanotube. From the simulations, it is proposed that the growth of an armchair nanotube takes place via attachment of dimers to its end which is in contact with the nickel surface. The effect of nickel nanoparticle's radius on the...