Sharif Digital Repository

Understanding of engine heat transfer is important because of its influence on engine efficiency, exhaust emissions and component thermal stresses. In this paper, the effect of various parameters such as compression ratio, equivalence ratio, spark timing, engine speed, inlet mixture temperature and swirl ratio as well as fuel type on the heat transfer through the chamber walls of a spark ignition (SI) engine is studied. For this purpose, a proper tool is developed which uses a KIVA multidimensional combustion modeling program and a finite-element heat conduction (FEHC) code iteratively. Also, an improved temperature wall function is used for the KIVA program. It was found that this iterative... 

Cubic plus association (CPA) equations of state (EoSs) have found great interest in describing thermodynamic properties of associating fluids. In CPA EoSs, the association contribution proposed by Wertheim is added to cubic EoSs such as Soave–Redlich–Kwong (SRK) and Peng–Robinson (PR). In different developments of CPA EoSs, adjusting the pure component properties such as critical temperature and critical pressure in addition to the association parameters is proposed in some works in the literature. In this work, the PR EoS has been extended to water, phenol, and a number of alcohols (methanol up to dodecanol) by addition of the Wertheim association contribution. In contrast to other CPA... 

Cubic plus association (CPA) equations of state (EoSs) have found great interest in describing thermodynamic properties of associating fluids. In CPA EoSs, the association contribution proposed by Wertheim is added to cubic EoSs such as Soave–Redlich–Kwong (SRK) and Peng–Robinson (PR). In different developments of CPA EoSs, adjusting the pure component properties such as critical temperature and critical pressure in addition to the association parameters is proposed in some works in the literature. In this work, the PR EoS has been extended to water, phenol, and a number of alcohols (methanol up to dodecanol) by addition of the Wertheim association contribution. In contrast to other CPA... 

Because of its unique properties, graphene has attracted the attentions of many academic research groups and recently, the industry. One of the promising applications of the graphene is in micro/nano-sensors, e.g. using it as a pressure sensor. To use it in mechanical-based nano-sensors, it is very important to investigate the mechanical behavior of the nano-sized graphene sheet and its sensitivity to the medium changes applied on its faces. In this work, we use the molecular dynamics MD method and simulate the behavior of graphene sheet under differential water pressure influences. In this regard, a square straight monolayer graphene sheet is placed as a separator diaphragm between two... 

This study presents a comprehensive investigation on hydrodynamic and thermal transport properties of mixed electroosmotically and pressure driven flow in microtubes. Particular emphasis is given to investigating the combined consequences of viscous dissipation, non-uniform Joule heating, and variable thermophysical properties. Analytical solutions are obtained using the Debye-Hückel linearization and constant fluid properties assumption, while a numerical solution is presented for variable fluid properties and non-uniform distribution of Joule heating. The results indicate that, viscous heating effect is pronounced significantly when a favorable pressure gradient exists and cannot be... 

A series of superabsorbent composites were synthesized through graft copolymerization of acrylic acid (AA) onto carboxymethyl cellulose (CMC) in the presence of celite powder using N,N'-methylenebisacrylamide (MBA) as a cross-linking agent and ammonium persulphate (APS) as an initiator. The chemical structure and thermal properties of the composite hydrogels were characterized by FTIR spectroscopy and TGA methods, respectively. Morphology of the samples was examined by scanning electron microscopy (SEM). In free-state, the swelling conditions and hence the related data are not real, because in all their applications the swelling particles of superabsorbent must absorb aqueous solutions while... 

The effects of incorporating the ester functional group (-C=OO-) into the side chain of the 1-alkyl-3-methylimidazolium cation ([C1COOCnC1im]+, n = 1, 2, 4) paired with [Br]-, [NO3]-, [BF4]-, [PF6]-, [TfO]-, and [Tf2N]- anions on the various thermodynamic properties and interaction energies of these biodegradable ionic liquids (ILs) were investigated by means of molecular dynamics (MD) simulations combined with ab initio calculations in the temperature range of 298-550 K. Excluding the simulated density, the highest values of the volumetric properties such as molar volume, isobaric expansion coefficient, and isothermal compressibility coefficient can be attributed to the largest cation... 

Following our recent study on the electronic properties of rough nanoribbons , in this paper the role of geometrical and roughness parameters on the thermal properties of armchair graphene nanoribbons is studied. Employing a fourth nearest-neighbor force constant model in conjuction with the nonequilibrium Green's function method the effect of line-edge-roughness on the lattice thermal conductivity of rough nanoribbons is investigated. The results show that a reduction of about three orders of magnitude of the thermal conductivity can occur for ribbons narrower than 10 nm. The results indicate that the diffusive thermal conductivity and the effective mean free path are directly proportional... 

Nitrogen has been appeared as a competitive gas injection alternative for gas-based enhanced oil recovery (EOR) processes. Minimum miscibility pressure (MMP) is the most important parameter to successfully design N2 flooding, which is traditionally measured through time consuming, expensive and cumbersome experiments. In this communication, genetic programming (GP) and constrained multivariable search methods have been combined to create a simple correlation for accurate determination of the MMP of N2-crude oil, based on the explicit functionality of reservoir temperature as well as thermodynamic properties of crude oil and injection gas. The parameters of the developed... 

In this work, an expression for the free volume Gibbs energy model based on the local composition concept (LCC) has been proposed in correlating the solubility, the partitioning and the surface tension of β-lactam, tetracycline, fluoroquinolone and chloramphenicol antibiotic groups in water, alcohol, ketone, trihalomethane, ether and ester solvent groups. Similar to the LCC models the proposed model has two combinatorial and residual terms. The extended Guggenheim model is used as combinatorial term and a new local composition-based model, which is the extended local area fraction NRTL-NRF model, is proposed for the residual term. The results obtained from the proposed model have been... 

Nanofluids viscosity is one of the most important thermophysical properties in nanofluids usage especially in chemical and petroleum engineering applications. So it is highly desirable to predict the viscosity of nanofluids accurately. Experimental measurements are impossible in most situations and present models are not comprehensive and efficient especially for high temperature, high volume concentration and high viscosity values. In this study, a new correlation has been developed based on the comprehensive database of water based Al2O3, TiO2, SiO2 and CuO nanofluids viscosity data found in literature. The proposed correlation uses temperature, nanoparticle size, nanoparticle volumetric... 

The compound, lead hydroxide Pb6O4(OH)4, was prepared by a method used for the first time in the authors laboratory. The compound was identified by XRD and it's purity was determined by analytical methods (100%). The thermal characteristics of this compound were investigated by using a thermogravimetry (TGA). This compound was found to be stable at room temperature and at 160°C will decompose completely to produce lead (II) oxide. © Sharif University of Technology, April 2007  

Deposition of asphaltenes upon precipitation is a main flow assurance concern, which propelled the development of various experimental and modeling techniques to accurately predict its occurrence. This work develops an integrated approach combining thermodynamic and deposition modules with a multiphase flow simulator to simultaneously model asphaltenes precipitation and deposition in wellbores. The Peng-Robinson equation of state and the modified Miller-Flory-Huggins theory are used to calculate the thermodynamic properties of the oil and asphaltenes precipitation, respectively. The deposition module is based on conservation laws for asphaltenes transport and is linked to the flow simulator... 

In this work, a new two-parameter cubic equation of state is presented based on perturbation theory for predicting phase behavior of pure compounds and of hydrocarbons and non-hydrocarbons. The parameters of the new cubic equation of state are obtained as functions of reduced temperature and acentric factor. The average deviations of the predicted vapor pressure, liquid density and vapor volume for 40 pure compounds are 1.116, 5.696 and 3.083%, respectively. Also the enthalpy and entropy of vaporization are calculated by using the new equation of state. The average deviations of the predicted enthalpy and entropy of vaporization are 2.393 and 2.358%, respectively. The capability of the... 

The objective of this paper is to derive the mathematical model of two-dimensional heat conduction at the inner and outer surfaces of a hollow cylinder which are subjected to a time-dependent periodic boundary condition. The substance is assumed to be homogenous and isotropic with time-independent thermal properties. Duhamel's theorem is used to solve the problem for the periodic boundary condition which is decomposed by Fourier series. In this paper, the effects of the temperature oscillation frequency on the boundaries, the variation of the hollow cylinder thickness, the length of the cylinder, the thermophysical properties at ambient conditions, and the cylinder involved in some... 

The present study deals with the structure-property relationship of organoclay (OC) filled nanocomposites based on rubber blend comprising of nitrile-butadiene rubber (NBR) and phenolic resin (PH). To obtain a better insight into the characteristics of the NBR/PH/OC hybrid system, a simple model system consisting of NBR/OC nanocomposites is also taken into consideration. A series of NBR/OC and NBR/PH/OC nanocomposites containing a wide range of OC concentrations (2.5-30 phr) are prepared by using traditional open two-roll mill. Structural analysis performed by X-ray diffraction (XRD), scanning electron microscope (SEM), and transmission electron microscope (TEM) exhibits mixed exfoliated and... 

Petroleum monoaromatics including benzene, toluene, ethylbenzene, and xylenes (BTEX) are among the notorious volatile organic compounds that contaminate water and soil. In this study, a surfactant- modified natural zeolite and its relevant granulated nanozeolites were evaluated as potential adsorbents for removal of petroleum monoaromatics from aqueous solutions. All experiments performed in batch mode at constant temperature of 20°C and pH of 6.8 for 48 h. The results revealed that the amount of BTEX uptake on granulated zeolites nanoparticles were remarkably higher than the parent micron size natural zeolite (in the order of four times). The isotherms data were analyzed using five models... 

Phase equilibrium data are required to estimate the capacity of a geological formation to sequester CO2. In this paper, a comprehensive study, including both thermodynamic and neural network modeling, is performed on CO2 solubility in brine. Brine is approximated by a NaCl solution. The Redlich-Kwong equation of state and Pitzer expansion are used to develop the thermodynamic model. The equation of state constants are adjusted by genetic algorithm optimization. A novel approach based on a neural network model is utilized as well. The temperature range in which the presented model is valid is 283-383K, and for pressure is 0-600bar, covering the temperature and pressure... 

In this study, an automotive air conditioning system is simulated by considering HFO-1234yf (2,3,3,3-tetrafluoropropene) as the drop-in replacement of HFC-134a. The simulated air conditioning system consists of a multi-louvered fin and flat-plate type evaporator, a wobble-plate type compressor, a mini-channel parallel-flow type condenser and a thermostatic expansion valve. The thermodynamic properties of the refrigerants are extracted from the REFPROP 8.0 software, and a computer program is simulated for the thermodynamic analysis. Two different conditions have been considered in this program for the cycle analysis: for the first state, the cooling capacity is taken as constant, and for the...