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    A Polypropylene-Based Microextraction Method Coupled with HPLC-FD for Determination of Fluoxetine in Human

    , M.Sc. Thesis Sharif University of Technology Gharibi Marzankola, Mahsa (Author) ; Bagheri, Habib (Supervisor)
    Abstract
    Considering principles of both micro-solid phase extraction (µ-SPE) and stir-bar sorptive extraction (SBSE) techniques, in this study a microextraction technique was developed using a polypropylene sheet as extracting device for isolation of fluoxetine from biological samples. Being rather inexpensive and simple to prepare extracting device, elimination of time consuming sorbent synthesis step and memory effect are some of the advantages of the proposed method. The extraction process was performed using a polypropylene sheet as extracting device. Solvent desorption was performed in a microvial and then extractant was injected into HPLC system. The effect of various parameters including pH,... 

    Manufacturing and Investigating of Polypropylene/Silica Nanocomposites via in-situ Polymerization and Using Bi-supported Ziegler-Natta Catalyst

    , M.Sc. Thesis Sharif University of Technology Azinfar, Bahareh (Author) ; Ramezani Saadat, Ahmad (Supervisor)
    Abstract
    The main object of this thesis is production and investigation of polypropylene-fumed silica nanocomposites by using bi-supported Ziegler-natta catalytic system and in-situ polymerization. Magnesium ethoxide and fumed silica were used as supports of catalyst. TiCl4 was accompanied by triisobutyl aluminum(TiBA) and diisobutyl phthalate(DIBP) as electron doner constituting Ziegler-Natta catalytic system. Preparation of catalyst and polymerization were taken place in slurry phase under the argon atmosphere. At the beginning of the polymerization experiment, several type of nanocomposites were made under various conditions(such as different Al/Ti molar ratio) to find optimum condition to... 

    Push-out tests on polypropylene concrete

    , Article 11th East Asia-Pacific Conference on Structural Engineering and Construction, EASEC-11, Taipei, 19 November 2008 through 21 November 2008 ; 2008 Maleki, S ; Mahoutian, M ; Sharif University of Technology
    2008
    Abstract
    The results of several monotonioc push-out tests on polypropylene concrete with channel shear connectors are presented in this research. The results are compared with ordinary concrete specimens with the same test setup. The effect of confining reinforcement on the shear capacity and ductility of polypropylene concrete composite system is investigated  

    Composites of rice husk/wheat straw with pMDI resin and polypropylene

    , Article Polymers and Polymer Composites ; Volume 15, Issue 8 , 2007 , Pages 619-626 ; 09673911 (ISSN) Frounchi, M ; Dadbin, S ; Jahanbakhsh, J ; Janat Alipour, M ; Sharif University of Technology
    Rapra Technology Ltd  2007
    Abstract
    The application of agricultural fibers for making particleboards has been studied in two types of composites: (i) type I particleboards were composites of wheat straw and rice husk fibers with polymeric methylene di-phenyl diisocyanate resin (pMDI) as a binder made by compression moulding; (ii) type II particleboards were composites of rice husk and polypropylene made by extrusion and injection moulding. In type I particleboards, the effects of varying the resin content and various combinations of wheat straw/rice husk fibers were investigated and characterised in terms of physical and mechanical properties of particle boards such as modulus of rupture, modulus of elasticity, compression... 

    Effect of polypropylene fibers and cement on the strength improvement of subgrade lying on expansive soil

    , Article Iranian Journal of Science and Technology - Transactions of Civil Engineering ; 2021 ; 22286160 (ISSN) Khan, S. Z ; Rehman, Z ; Khan, A. H ; Qamar, S ; Haider, F ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2021
    Abstract
    The current study revealed the effectiveness of polypropylene (PP) fibers and cement to enhance the strength of black cotton soil. PP fibers and cement with different concentrations were mixed with black cotton soil. The strength of PP fiber and cement-based soil samples was measured in terms of unconfined compressive strength (UCS) and California Bearing ratio (CBR). Specimens for UCS and CBR tests were prepared at 2%, 4%, 6% and 8% of cement (by dry weight of soil) and seven percentages of polypropylene fibers i.e. 0.0%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5% and 0.6% (by dry weight of soil). Fourier transform infrared (FTIR) analysis confirmed the presence of polypropylene and cement contents in... 

    Effect of polypropylene fibers and cement on the strength improvement of subgrade lying on expansive soil

    , Article Iranian Journal of Science and Technology - Transactions of Civil Engineering ; Volume 46, Issue 1 , 2022 , Pages 343-352 ; 22286160 (ISSN) Khan, S. Z ; Rehman, Z ; Khan, A. H ; Qamar, S ; Haider, F ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2022
    Abstract
    The current study revealed the effectiveness of polypropylene (PP) fibers and cement to enhance the strength of black cotton soil. PP fibers and cement with different concentrations were mixed with black cotton soil. The strength of PP fiber and cement-based soil samples was measured in terms of unconfined compressive strength (UCS) and California Bearing ratio (CBR). Specimens for UCS and CBR tests were prepared at 2%, 4%, 6% and 8% of cement (by dry weight of soil) and seven percentages of polypropylene fibers i.e. 0.0%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5% and 0.6% (by dry weight of soil). Fourier transform infrared (FTIR) analysis confirmed the presence of polypropylene and cement contents in... 

    Synthesis of polypropylene/clay nanocomposites using bisupported Ziegler-Natta catalyst

    , Article Journal of Applied Polymer Science ; Volume 115, Issue 1 , 2010 , Pages 308-314 ; 00218995 (ISSN) Ramazani, S. A. A ; Tavakolzadeh, F ; Baniasadi, H ; Sharif University of Technology
    Abstract
    In this article, preparation of polypropylene/clay nanocomposites (PPCNC) via in situ polymerization is investigated. MgCl2/montmorillonite bisupported Ziegler-Natta catalyst was used to prepare PPCNC samples. Montmorillonite (MMT) was used as an inert support and reinforcement agent. The nanostructure of the composites was characterized by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy techniques. Obtained results showed that silica layers of the MMT in these PPCNC were intercalated, partially exfoliated, and uniformly dispersed in the polypropylene matrix. Thermogravimetric analysis showed good thermal stability for the prepared PPCNC. Differential... 

    Determination of the extended Drucker-Prager parameters using the surrogate-based optimization method for polypropylene nanocomposites

    , Article Journal of Strain Analysis for Engineering Design ; Volume 51, Issue 3 , 2016 , Pages 220-232 ; 03093247 (ISSN) Payandehpeyman, J ; Majzoobi, G. H ; Bagheri, R ; Sharif University of Technology
    SAGE Publications Ltd  2016
    Abstract
    In this article, a new method is proposed to identify the constants of the extended Drucker-Prager yield surface for polypropylene nanocomposites. The method is based on optimizing the difference between the numerical and the experimental results of a three-point bending test. The test specimens are made of polypropylene/nanoclay and polypropylene/nano-calcium carbonate nanocomposites with different nanoparticles content. Moreover, the effect of composite filler content on the extended Drucker-Prager constants of polypropylene, as the composite matrix, is investigated. Inasmuch as numerical simulation is usually very time-consuming and highly nonlinear, a surrogate-based model with radial... 

    An alternative additive manufacturing-based joining method to make Metal/Polymer hybrid structures

    , Article Journal of Manufacturing Processes ; Volume 45 , 2019 , Pages 217-226 ; 15266125 (ISSN) Ozlati, A ; Movahedi, M ; Tamizi, M ; Tartifzadeh, Z ; Alipour, S ; https://www.sciencedirect.com/science/article/abs/pii/S1526612519302087
    Elsevier Ltd  2019
    Abstract
    Fused Deposition Modeling with Polypropylene filament was employed to make a lap joint between Polypropylene and pre-punched Al-Mg alloy sheets, in the form of bonds between the polymeric substrate and the additive part and mechanical lock between the additive part and aluminum base sheet. Effects of the joint interface area (hole diameter of 5–13 mm) and preheating of the substrates (room temperature, 50 and 90℃) were investigated on the mechanical properties of the joints. Peak load in the tensile-shear and cross-tension tests increased with enhancement of the joint interface area (up to ˜280 N and ˜160 N, respectively). Higher joint strength in the tensile-shear test compared to the... 

    Strength of SCLC recycle springs and fibers concrete subject to high temperatures

    , Article Structural Concrete ; 2021 ; 14644177 (ISSN) Pachideh, G ; Toufigh, V ; Sharif University of Technology
    John Wiley and Sons Inc  2021
    Abstract
    In this article, the self-compacting lightweight concretes (SCLC) with different fibers were prepared and exposed to elevated temperatures, and their mechanical properties were investigated. Three types of fibers were steel fibers (SF), polypropylene fibers (PPF), and metal springs with a volume fraction of 0.4%. One hundred and fifty cylindrical specimens were prepared, and the compression, tensile and flexural tests were carried out on them after exposure to high temperatures ranging from 25 to 700°C. The findings indicate that incorporation of steel fibers and springs enhanced the compressive strength of concrete by 20% compared to the control specimen. Meanwhile, the polypropylene fibers... 

    Effect of hybridization on crystallization behavior, mechanical properties, and toughening mechanisms in rubber-modified polypropylene flax fiber composites

    , Article Journal of Composite Materials ; Volume 56, Issue 17 , 2022 , Pages 2677-2693 ; 00219983 (ISSN) Bahrami, R ; Bagheri, R ; Sharif University of Technology
    SAGE Publications Ltd  2022
    Abstract
    Nowadays, the significance of sustainability has urged composite manufacturers to replace traditional synthetic fibers with eco-friendly natural alternatives due to their environmental and economic benefits. This work aims to fabricate hybrid polypropylene (PP) composites with short flax fibers, octene-ethylene copolymer (POE) rubber particles, and maleic anhydride-grafted polypropylene (MAPP) compatibilizer. The main goal is to gain an insight into the combined effect of toughening mechanisms induced by the short fibers and rubber particles at the crack tip and wake of composites, which is a crucial step in reaching a balance between toughness and rigidity. In this regard, a novel... 

    Strength of SCLC recycled springs and fibers concrete subject to high temperatures

    , Article Structural Concrete ; Volume 23, Issue 1 , 2022 , Pages 285-299 ; 14644177 (ISSN) Pachideh, G ; Toufigh, V ; Sharif University of Technology
    John Wiley and Sons Inc  2022
    Abstract
    In this article, the self-compacting lightweight concretes (SCLC) with different fibers were prepared and exposed to elevated temperatures, and their mechanical properties were investigated. Three types of fibers were steel fibers (SF), polypropylene fibers (PPF), and metal springs with a volume fraction of 0.4%. One hundred and fifty cylindrical specimens were prepared, and the compression, tensile and flexural tests were carried out on them after exposure to high temperatures ranging from 25 to 700°C. The findings indicate that incorporation of steel fibers and springs enhanced the compressive strength of concrete by 20% compared to the control specimen. Meanwhile, the polypropylene fibers... 

    Investigation of the gas barrier properties of PP/ciay nanocomposite films with EVA as a compatibiliser prepared by the melt intercalation method

    , Article Polymer - Plastics Technology and Engineering ; Volume 49, Issue 10 , 2010 , Pages 991-995 ; 03602559 (ISSN) Shafiee, M ; Ahmad Ramazani, S. A ; Danaei, M ; Sharif University of Technology
    2010
    Abstract
    In this research, polypropylene (PP) nanocomposite films were prepared by melt intercalation method and their properties have been evaluated. To facilitate the formation of either intercalated or exfoliated nanocomposites, ethylene vinyl acetate copolymer (EVA) was used as a compatibiliser. Morphology of composites was determined by X-ray Diffraction (XRD) and transmission electron microscopy (TEM). XRD and TEM analyses confirmed that increasing of EVA content leads to achievement of intercalated nanocomposites. Furthermore, differential scanning calorimetry (DSC) measurement indicated a decrease in crystallinity, melting point and crystallization temperature. Also, permeability tests showed... 

    Rubberized alkali-activated slag mortar reinforced with polypropylene fibres for application in lightweight thermal insulating materials

    , Article Construction and Building Materials ; 2020 Rajaei, S ; Shoaei, P ; Shariati, M ; Ameri, F ; Musaeei, H. R ; Behforouz, B ; de Brito, J ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Every year, about a thousand million tires reach the end of their service life, more than half of which are disposed of in landfills. The waste tire rubber has a great potential for application as aggregate phase in production of lightweight concrete/mortar. This study is aimed at evaluating the effects of using crumb rubber (CR) as fine aggregate at replacement ratios of 0–60% (by volume) in alkali-activated slag mortars. Furthermore, polypropylene fibre (PPF) was used at 0.5% and 1% of volume of the mix to enhance the properties of mortar mixes such as flexural strength and shrinkage behaviour. The compressive strength, flexural strength, water absorption, thermal conductivity, drying... 

    Studying the Effect of Dynamic Vulcanization of EPDM on Scratch Resistance of Rubber-Modified Polypropylene

    , M.Sc. Thesis Sharif University of Technology Zarrinbakhsh, Nima (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    Polypropylene is a commodity thermoplastic with good physical and mechanical properties along with fair recyclability and cost. However, the application of polypropylene is limited in some cases, especially in automotive industry, as a result of inappropriate toughness of this material. Although rubber toughening of polypropylene is a method used to increase the toughness, it reduces scratch resistance. Studies performed in the polymer group of this department reveal that the cavitation resistance of elastomeric phase and its bonding to the matrix are two effective parameters in scratch resistance of this material. In this study, it is tried to alter the cavitation resistance of elastomeric... 

    Study on Effect of Chemical Parameters on Mechanical and Morphological Properties of Biodegradable wo Phase Propylene/Starch Blends

    , M.Sc. Thesis Sharif University of Technology Dorri Moghadam, Afsaneh (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    In recent years the rapid rise of polymer consumption especially in the form of packaging materials became a real menace for the environment. Polyolefin are some of the most dominant packaging materials and responsible by part of the problems in the disposal of one-trip packaging. One of the possible ways of solving this problem is the introduction of additives increasing their susceptibility to environmental degradation into non-biodegradable polymers. One such additive is starch- the natural, cheap, and easily biodegradable polymer. Starch was already used as a filler or as a blend with polyolefin. Addition of dry starch granules to polyolefin follows the general trend of filler effects on... 

    Investigation Properties of Polypropylene/Carbon Nanotube Nanocomposites Prepared via in Situ Polymerization Using Bi-Supported Ziegler Natta Catalyst

    , M.Sc. Thesis Sharif University of Technology Jafari Esfad, Narjes (Author) ; Ramezani Saadatabadi, Ahmad (Supervisor)
    Abstract
    In this research polypropylene/carbon nanotube nano composites were prepared via in situ polymerization using Bi-supported Ziegler-Natta catalytic systems. Magnesium etoxide and Multi wall carbon nanotubes(MWCNT) functionalized by hydroxyl groups were used as supports of catalyst. TiCl4 and TiBA were used as catalyst and co catalyst respectively. After defining the polymerization optimum conditions and considering its parameters constant, nano composites with different carbon nanotube contents were produced by changing the polymerization time. Scanning Electron Microscopy (SEM) images certified very good dispersion of MWCNTs throughout polypropylene matrix. The thermal properties behavior of... 

    Study Effects of Nucleating Agent and Nano Reinforecment on Crystalline Structure and Mechanical Properties of Polypropylene Block Copolymer

    , M.Sc. Thesis Sharif University of Technology Shahsavan, Shakiba (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    Polypropylene block copolymer is used in different industries like pipe productions. This copolymer has proper mechanical properties, specially it has good impact strength, but in some applications it’s elastic modulus (stiffness) is not enough and that leads to some problemes in servise. Nucleating agents influence crystalline structure and properties and also the mechanical properties by controlling the crystallization process. Nanoparticles also have a beneficial effects on physical and mechanical properties. In this study, the effect of adding two types of α-phase nucleating agents (commercial names NA11 and DMDBS) in the form of masterbatch wt 5% with a carrier of polypropylene block... 

    An Investigation on Mechanical Behavior of Polypropylene/Polyethylene Blend - Calcium Carbonate Nano Composite

    , M.Sc. Thesis Sharif University of Technology Shayesteh Zeraati, Ali (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    Polymer blending has an important role in preparation of materials with suitable properties without synthesizing new polymers. One of these blends is polypropylene (PP)/ polyethylene (PE). PE is added for improving the impact strength and toughness of PP. For improvementof the properties, a compatibilizer is used due to incompatibility of the PP/PE blend. Improving the impact properties is usually related to the reduction in stiffness. Considering the importance of stiffness in many industrial applications, mineral fillers are employed for increasing the stiffness. In this research, the goal has been to manufacture polypropylene-based ternary composite(Polypropylene/ Polyethylene/Nanometric... 

    Oxygen Barrier Improvement of the BOPP Films in Food Industry

    , Ph.D. Dissertation Sharif University of Technology Shayanipour, Hamid Reza (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    One of the most popular methods in order to protect foods is to package using various materials. By this act, the shelf life of the packaged foods may range from a few days to more than a year. Multiple types of plastics are being used as materials for packaging food, including polyolefin, polyester, polyvinyl chloride, polyvinylidene chloride, polystyrene, polyamide, and ethylene vinyl alcohol. Although more than 30 types of plastics have been used as packaging materials, polyolefin and polyesters are the most common. Biaxially Oriented Polypropylene (BOPP) is a polypropylene film that has been stretched in both the machine and cross directions. BOPP film has become one of the most popular...