Sharif Digital Repository

The electrochemical behavior of Furazolidone (Fu) was investigated on the surface of the glassy carbon electrode modified with different carbon nanomaterials, including carbon nanotubes (CNTs), carbon nanoparticles (CNPs), nanodiamond-graphite (NDG), graphene oxide (GO), reduced graphene oxide (RGO) and RGO-CNT hybrids (various ratios) using linear sweep voltammetry (LSV). The results of voltammetric studies exhibited a considerable increase in the cathodic peak current of Fu at the RGO modified GCE, compared to other modified electrodes and also bare GCE. The surface morphology and nature of the RGO film was thoroughly characterized by scanning electron microscopy (SEM), atomic force... 

Novel polyampholytic superabsorbing nanocomposites based on the zwitterionic sulfobetaine monomer [3-(methacrylamido)propyl)]dimethyl(3- sulfopropyl)ammonium hydroxide were synthesized through in situ polymerization in aqueous solution with different contents of an organo-modified clay (OMMT, Cloisite 30B). Structural and thermomechanical properties of hydrogels were characterized by FT-IR, XRD, and DMTA, respectively. Swollen gel strength of hydrogels was determined by a rheological method. Storage modulus of the hydrogels was considerably improved in comparison with its the clay-free counterpart. The nanocomposite hydrogel containing 15% OMMT possessed the highest gel strength. The glass... 

This study examined the bond at the interface of masonry bricks and fiber-reinforced polymer when exposed to five environments. Three fabrics (aramid, carbon, and glass) and one type of epoxy resin were used. A total of 375 brick-fiber-reinforced polymer specimens were made using wet lay-up technic and exposed to chemical solutions at four pH values (2.5, 7, 10, and 12.5) and substitute seawater. The effect of dry heat on the bond at the interface was also investigated. Single-lap shear tests were then carried out on the samples after 2, 4, 6, 8, 10, and 13 weeks of exposure. The experimental results indicated that freshwater and seawater had a considerable effect on the bond strength of... 

Molecular level understanding of the properties of ionic liquids inside nanopores is needed in order to use ionic liquids for many applications such as electrolytes for energy storage in electric double-layer capacitors and dye-sensitized solar cells for conversion of solar energy. In this study, classical molecular dynamics (MD) simulations have been performed to investigate the radial distribution, glass transition, ionic transfer number, and electrical conductivity of the ionic liquid 1-ethyl-3-methylimidazolium hexafluorophosphate [EMIM][PF6] ionic liquid encapsulated in carbon nanotube (CNT). The effect of nitrogen as a doping element in CNT on these properties of [EMIM][PF6] was also... 

Previous studies have shown that a small variation in the chemical composition of metallic glasses (MGs) can drastically alter their strength and ductility. However, the underlying structural origin and atomistic mechanisms remain unclear. Using large-scale molecular dynamics simulations, we studied the effect of chemical composition and affinity on the microstructure and deformation behaviour of Zr50Ni50 − xAlx MG by varying the value of x in the range of 5 ≤ x ≤ 25 (at.%). We show that an increase in x is able to strengthen and embrittle the material. In particular, a ductile (homogeneous deformation) to brittle (shear banding) transition occurs at x ~ 15. To reveal the structural origin,... 

The present paper describes a voltammetric sensor based on glassy carbon electrode (GCE) modified with a thin film of multi-walled carbon nanotubes (MWCNTs) coated with an electro-polymerized layer of titan yellow-doped over–oxidized polypyrrole (OPPY) for the determination of tizanidine (TIZ). A significant enhancement was observed in the anodic peak current of TIZ on the surface of OPPY/CNT/GCE, relative to the bare, CNT- and OPPY-coated GCEs. The microscopic structure and surface morphology of the composite film was thoroughly characterized by means of atomic force microscopy (AFM), scanning electron microscopy (SEM) and cyclic voltammetry (CV) techniques. The effect of various... 

Execution speed seriously bothers application developers and users for wearable devices such as Google Glass. Intensive applications like 3D games suffer from significant delays when CPU is busy. Energy is another concern when the devices are in low battery level but users need them for urgency use. To ease such pains, one approach is to expand the computational power by cloud offloading. This paradigm works well when the available Internet access has enough bandwidth. Another way is to leverage nearby devices for computation-offloading, which is known as device-to-device (D2D) offloading. In this paper, we present Dandelion, a unified code offloading system for wearable computing. Dandelion... 

A new method for fabrication of silver nano-islands on glass fibers using a top-down process is introduced. A thin layer of silver chemically coated on the surface of the glass fibers evolves into silver islands by heat treatment. The effect of the concentration of the initial solution and the temperature were investigated. Segregation was more clearly observed for lower solution concentrations and higher temperatures. The temperature of 500 °C was found optimum where separated islands form. At higher temperatures, the coagulation and burial of silver islands occur. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and diffused reflectance spectroscopy (DRS) were... 

Toughness improvement of an epoxy resin and respective hoop wound composite were investigated systematically using amine-terminated butadiene acrylonitrile (ATBN) liquid rubber. Rubber modification improves fracture toughness of epoxy resin with slight reduction in the glass transition temperature (Tg), flexural and compressive properties of resin. Impact resistance of composite is improved by rubber modification similar to modified resin. Interlaminar shear strength (ILSS), compressive modulus and strength, and flexural strength of composite decreased slightly with rubber modification. To interpret the data, the void content of composite samples was determined and the damaged surfaces of... 

By displacing oil in porous media with other fluid, different mechanisms of fluid displacing occur. The importance of understanding the trapping mechanisms like pore body filling is irrefutable. Pore body filling mechanism with a coordination number of four has different events like I0, I1, I2 and I3. Previous studies showed that the event of I0 occurs when the pore is only filled by a compressible non-wetting phase, but this study showed that this event could also occur by an incompressible non-wetting phase. Trapping mechanisms can be examined in a glass micro-model. In this research, a glass micro-model with three different patterns was used. Results showed that at two spots of the... 

A new non-enzymatic sensor for glucose is prepared by using of Ni(II)-one dimensional coordination polymer (Ni(II)-Cp) and C 60 . The Ni(II)-Cp prepared by slow diffusion and evaporation of two solution layers of NiCl 2 and diaza-macrocycle bearing two pyridine side arms (as the reported tecton) in DMF. The Ni(II)-Cp was characterized by powder x-ray diffraction (PXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) as well as Fourier transform infrared spectroscopy (FT-IR). C 60 as modified was added to Ni(II)-Cp for improving the electrical and chemical stability of the composite. The newly assembled Ni(II)-Cp/C 60 also coated on glassy carbon electrode (GC) to... 

Recently, graphitic carbon nitride (g-C3N4) has attracted great interest for photo(electro)chemical applications such as sensing, solar energy exploitation, photocatalysis, and hydrogen generation. This paper presents the potential application and benefits of g-C3N4 nanolayers as a green and highly efficient electrode modifier for the detection of trace lead ions in drinking water and urban dust samples. Carbon nitride nanosheets with a thickness of ∼6 A° and lateral of 100–150 nm were prepared through high-temperature polymerization of melamine followed by sonication-assisted liquid exfoliation. A glassy carbon electrode (GCE) was modified by a thin layer of g-C3N4 through drop casting and... 

The structural integrity of the sealant is critical for the reliability of solid oxide cells (SOCs) stacks. In this study, elastic modulus (E), hardness (H) and fracture toughness (KIC) of a rapid crystallizing glass of BaO–CaO–SiO2 system termed “sealant G” are reported as determined using an indentation test method at room temperature. A wide range of indentation loads (1 mN–10 N) was used to investigate the load-dependency of these mechanical properties. Values of 95 ± 12 GPa, 5.8 ± 0.2 GPa and 1.15 ± 0.07 MPa m0.5 were derived for E, H and KIC using the most suitable indentation loads. An application relevant annealing treatment of 500 h at 800 °C does not lead to a significant change of... 

Interactions between the metal interconnect and glass sealant in the solid oxide cells stack are critical to retaining the system integrity. To address this issue, in the current study, 8YSZ coating is applied on the Crofer22 APU steel via sol-gel and dip-coating method. Dense and continuous 8YSZ coatings are obtained on Crofer22 APU substrates. X-ray diffraction and Raman spectroscopy results show that both cubic and tetragonal structures of 8YSZ are formed. A glass-based sealing paste is applied on bare and 8YSZ coated Crofer22 APU steel. The interfacial compatibility and chemical stability of steel/glass and steel/8YSZ/glass joint couples are investigated using SEM and EDS line scan... 

Development of simple yet precise sensing platforms for rapid determination of biological species and drugs is of paramount importance, not only for analysis of pharmaceutical formulations during the production stage, but also in clinical practices and medical diagnosis. In the present research, we report on the electrochemical determination of atorvastatin (ATOR) by using silver nanowires/gold-modified glassy carbon electrode (Ag NWs/Au/GCE). The modified electrode was constructed through a two-step procedure in which narrow silver nanowires synthesized via a polyol method are drop casted on a pre-modified GCE with electrodeposited gold particles. The results of XRD analysis indicated the... 

Gel-fiber structure with the potential of extracellular matrix (ECM) mimics can be introduced as a suitable candidate for bioengineering applications. In this study, piezoelectric gellan gel-fiber was prepared with incorporating poly(vinylidenefluoride) (PVDF)/glass-flake in the gellan matrix. Glass-flake nanoparticles were modified with silane group, PVDF/glass-flake nanofibers were synthesized and short-strand nanofibers were fabricated using the mechanical homogenizer method. Brunauer–Emmett–Teller (BET), Fourier-transform infrared spectroscopy (FTIR), and Thermogravimetric analysis (TGA) analyses were used for surface modification study, and scanning electron microscopy (SEM),... 

Anti-reflection and self-cleaning coatings on the glass substrate are used to improve the performance of solar systems. TiO2 are one of the most used semiconductors for this application. In this research meso-porous TiO2 coatings (that synthesized by the sol-gel process) with the various extent of porosity (using different concentrations of Pluronic F127, as pore-forming agent) have been investigated. The coating's thickness and porosity and anti-reflective properties were studied by FE-SEM and UV/VIS spectrometer (transmission spectra test), respectively. It was found that the use of F127 leads to the formation of pores smaller than 30 nm and increases the surface roughness from 1.5 (for... 

Following our previous work on morphology, corrosion resistance and thermal properties of unsaturated polyester (UP)/nanoclay composites, the effect of electron beam (EB) irradiation on mechanical properties of UP/nanoclay composites with various nanoclay contents is investigated in this work. Moreover, influence of EB irradiation with doses of 100, 500 and 1000 kGy on tensile properties and hardness of nanocomposite was examined. FTIR spectroscopy was employed to examine the effect of irradiation on chemical structure of polymer. EB irradiation up to 500 kGy led to the improvement of tensile strength and hardness of the samples. The best mechanical properties were observed for the... 

In the present study, the effects of Sr and Mg were investigated on mechanical and biological properties of 58S bioactive glass (BG). SiO2-P2O5-CaO BG with different contents of Sr and Mg were synthesized via the sol-gel method and immersed in simulated body fluid (SBF) for several days to explore their biocompatibility. Precise analyses of the BG using X-ray powder diffraction, scanning electron microscopy, and transmission electron microscopy showed that the Mg-doped BG containing 8 wt % MgO possessed better biocompatibility. It was also found that mechanical properties of the BG could be improved by increasing the amounts of MgO and SrO. Both 5Sr-BG and 8Mg-BG samples did not exhibit any... 

Ammonium polyphosphate (APP) is one of the most widely used halogen-free flame retardant, added in various resins to improve the fire properties, such as flame and smoke spread ratings and LOI, of fiber-reinforced polymer (FRP) composites. This paper experimentally investigates the effects of using APP, as a fire-retardant filler, on mechanical properties (i.e. ultimate tensile, flexural, and bond strength) of glass fiber-reinforced polymer (GFRP) and carbon fiber-reinforced polymer (CFRP) composites. Based on two fiber types (i.e. carbon and glass) and three different APP mass fractions in resin (i.e. 0, 20, and 40% of total weight of matrix), six sets of specimens were prepared for each...