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    Control of High Purity Distillation Columns

    , M.Sc. Thesis Sharif University of Technology Roodpeyma, Maedeh (Author) ; Shahrokhi, Mohammad (Supervisor)
    Abstract
    Selection of the most appropriate control configuration for two point control strategy in a distillation column is a challenging problem. In the present work, three control configurations namely , and , have been employed to control a high purity distillation column separating the binary mixture of Benzene-Toluene. A simple linear model for the process has been derived via a system identification technique. The uncertainty and performance weights have been defined and have been utilized to design a robust controller based on the μ-synthesis approach. The genetic algorithm is employed and the peak value of μ is minimized in order to obtain appropriate PI controller parameters for each... 

    Experimental Study of Solar Still with Heat Pipes Using Phase Change Material

    , M.Sc. Thesis Sharif University of Technology Ravan, Ayoub (Author) ; Sadrhosseini, Hani (Supervisor) ; Shafii, Mohammad Behshad (Supervisor)
    Abstract
    Solar distillation is a comparatively easy treatment of brackish (i.e. contain dissolved salts) water supplies. Distillation is a well-known process, which may be used for water filtration utilizing heating sources. In this research, the solar distillation set with heat-pipes was made and tested in 18 months.At the first step, during four days, the pipes were filled with some water to certain height every day while temperature and produced water were estimated. At the second step, the vacuum pipes were filled with some oil and tested for 4 different heights within 4 days; and in final steps, aluminum chips, washing wire and metal foam were shaded into the tank then tested by an optimum water... 

    Class Attention Map Distillation In Semantic Segmentation

    , M.Sc. Thesis Sharif University of Technology Karimi Bavandpour, Nader (Author) ; Kasaei, Shohreh (Supervisor)
    Abstract
    Semantic segmentation is the tash of labeling each pixel of an input image. It is one of the main problems in computer vision and plays an important role in scene understanding. State of the art methods of solving it are based on Convolutional Neural Networhs (CNNs). While many real world tasks like autodriving cars and robot navigation require fast and lightweight models, CNNs inherently tend to give beter accuracy when they are deeper and bigger, and this has raised interest in designing compact networks. Knowledge distillation is one of the popular methods of training compact networhs and helps to transfer a big and powerful network’s knowledge to a small and compact one. In this research... 

    Distillation of free entanglement from bound entangled states using weak measurements

    , Article Physical Review A - Atomic, Molecular, and Optical Physics ; Volume 88, Issue 6 , 2013 ; ISSN: 10502947 Baghbanzadeh, S ; Rezakhani, A. T ; Sharif University of Technology
    2013
    Abstract
    We propose a scheme for distillation of free bipartite entanglement from bipartite bound entangled states. The crucial element of our scheme is an ancillary system that is coupled to the initial bound entangled state via appropriate weak measurements. We show that in this protocol free entanglement can be always generated with nonzero probability by using a single copy of the bound entangled state. We also derive a lower bound on the entanglement cost of the protocol and conclude that, on average, applying weaker measurements results in relatively higher values of free entanglement as well as lower costs  

    Development of a continuous kinetic model for catalytic hydrodenitrogenation of bitumen

    , Article Scientia Iranica ; Volume 14, Issue 2 , 2007 , Pages 152-160 ; 10263098 (ISSN) Ashuri, E ; Khorasheh, F ; Gray, M. R ; Sharif University of Technology
    Sharif University of Technology  2007
    Abstract
    Catalytic hydrocracking of topped Athabasca bitumen was investigated in a continuous stirred-basket 0reactor, using a fresh and spent commercial catalyst, as well as in the presence of no catalyst. A continuous lumping model was developed for kinetic analysis of hydrodenitrogenation and hydrocracking reactions. The normalized boiling point was used to describe the reactant mixture as a continuous mixture. The continuous model, with five adjustable parameters, was used to describe hydrocracking reactions. Reactions of nitrogen compounds were described by series reactions, involving cracking to lower molecular weight products, as well as direct denitrogenation. The model was able to accurately... 

    Mixed qualitative/quantitative dynamic simulation of processing systems

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 24, Issue 1 , 2005 , Pages 53-67 ; 10219986 (ISSN) Yadegar, S ; Pishvaie, M. R ; Sharif University of Technology
    2005
    Abstract
    In this article the methodology proposed by Li and Wang for mixed qualitative and quantitative modeling and simulation of temporal behavior of processing unit is reexamined and extended to more complex case. The main issue of their approach considers the multivariate statistics of principal component analysis (PCA), along with clustered fuzzy digraphs and reasoning. The PCA and fuzzy clustering provide tools to categorize the quantitative dynamic trends, describing the temporal behavior of joint human-process interactions qualitatively, and through the proposed neuro-fuzzy reasoning the system responses can be obtained when the system is exposed to uncertain disturbances. First, the method... 

    Comparison among various configurations of hybrid distillation–membrane setups for the energy efficiency improvement of bioethanol distillery: a simulation study

    , Article Journal of Chemical Technology and Biotechnology ; October , 2021 ; 02682575 (ISSN) Iftikhar, S ; Aslam, Z ; Ali, U ; Akhtar, A ; Sharif University of Technology
    John Wiley and Sons Ltd  2021
    Abstract
    BACKGROUND: Hybrid distillation–membrane setups have attracted attention in recent years due to their lower energy usage for ethanol purification. Membrane separation processes operate without heating that reduces energy demand. However, it is somewhat challenging to select the optimal material and process for a membrane purifying ethanol, especially to get an ethanol purity of 99.99% with maximum recovery. RESULTS: In this study, three different configurations of hybrid distillation–membrane setups are proposed consisting of distillation–pervaporation/vapor permeation processes by considering ceramic, polymeric and composite membranes. The design of hybrid processes is performed by coupling... 

    Superhydrophobic dual layer functionalized titanium dioxide/polyvinylidene fluoride-co-hexafluoropropylene (TiO2/PH) nanofibrous membrane for high flux membrane distillation

    , Article Journal of Membrane Science ; Volume 537 , 2017 , Pages 140-150 ; 03767388 (ISSN) Seyed Shahabadi, S. M ; Rabiee, H ; Seyedi, S. M ; Mokhtare, A ; Brant, J. A ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    In this study, superhydrophobic dual layer membranes with highly porous structure were fabricated using electrospinning and electrospraying techniques. Electrospinning method was used to produce the support nanofibrous layer using polyvinylidene fluoride-co-hexafluoropropylene (PH) as the polymer and a mixed solvent system of N,N-Dimetylformamide (DMF) and acetone. Afterwards, hydrophobic, functionalized TiO2 nanoparticles were deposited on the surface of the support layer using the electrospraying technique. TiO2 chemical functionalization and their deposition on the support layer were investigated by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy. The... 

    Boron Isotope Separation by Distillation of BF3-(C2H5)2O Complex

    , M.Sc. Thesis Sharif University of Technology montazeri, Meysam (Author) ; Otukesh, Mohammad (Supervisor) ; Ahmadi, Javad (Supervisor)
    Abstract
    Natural boron consists of two stable isotopes, mass 10 (19.3%) and mass 11 (80.7%). 10B isotope has a large thermal neutron capture cross-section and it therefore, used widely in such aspects as modern industry, military equipment, medical science and so on. specially the demand of atomic energy industry for the boron isotope is increased severely. So the separation of 10B from natural boron has received very wide attention at present. There are many kinds of methods on the boron isotopes separation, such as chemical exchange reaction and distillation in boron trifluoride method, ion exchange in boric acid solution method, counter current recycle membrane cascades in boron trifluoride... 

    Simulation and Control of an Aromatic Extractive Distillation Column

    , M.Sc. Thesis Sharif University of Technology Karima, Mohammad Mahdi (Author) ; Shahrokhi, Mohammad (Supervisor)
    Abstract
    In this study steady state and dynamic simulation of an NFM extractive distillation unit for seperation of aromatics and non-aromatic components has been carried out. Column output composition obtained with experimental binary coefficients is compared with those obtainded by UNIFAC equation. The results indicate that using UNIFAC for all binrary coefficients results in an unacceptable error in concentration of benzene. If the experimental binary coefficents of benzene with NFM are used and the rest are calculated by UNIFAC equation, the simulation results will be very close to those obtained via experimental binary coefficients. Also it is shown that considering a constant efficiency for all... 

    Development of Optimal Integrated and Intensive Model of Energy Processing and Conversion

    , Ph.D. Dissertation Sharif University of Technology Avami, Akram (Author) ; Saboohi, Yadollah (Supervisor)
    Abstract
    In a single chemical plant, the operation of each unit operation is not independent of each other. In the other hand, the main operations are performed in reactors following by several separation steps including distillation and purification units. The total energy requirements are sullied by the heat exchanger networks. The performance of these systems is improved by integration and intensification of the reactor and distillation column in a single unit. The main objective of the present work is to provide an effective design approach to intensify the reactor and distillation column. In a reactive distillation column, the reaction and separation is done in a single unit. Increasing... 

    Technical and Economical Feasibility Study of Applying Heat Pump Systems to Provide Utilities for Oil & Gas Industries

    , M.Sc. Thesis Sharif University of Technology Hamidzadeh, Zeinab (Author) ; Sattari, Sorena (Supervisor) ; Amidpour, Majid (Supervisor)
    Abstract
    Distillation is the most applied unit in the separation processess of the oil and gas industries. Because the distillation process requires energy in the form of the utilities, integration of heat pump systems in the distillation process as an application of these systems is considered in this research. A new and effective methodology of proper integrating of heat pump and distillation columns has been proposed by collecting thermodynamic and thermoeconomic tools. Then, this procedure has been applied on the ethane recovery and NGL fractionation units of 4 & 5 phases of the south pars field. The exergy analysis of the distillation columns is the first step of this methodology as the... 

    Investigation of Equilibrium and Thermodynamic Behavior Using an Entrainer for Azeotropic Mixture Separation

    , M.Sc. Thesis Sharif University of Technology Alemrajabi, Mahmood (Author) ; Farhadi, Fatollah (Supervisor)
    Abstract
    Azeotropic separation has multiple difficulties. In order to remove the azeotropes, different solutions are recommended such as the use of entrainers, extractive distillation, and pervaporation. Based on initial condition of the mixture, a decision tree is proposed. As a sample, the Ethanol – Ethyl Acetate system is selected and a new solvent – entrainer is proposed with addition of different salts. The suitable concentrations of salt, entrainers or solvent are tested experimentally to draw the relevant RCM.
    A suitable set up is designed and assembled, and then samples are taken to analyze in order to provide T-XY diagram. The pressure also is taken into account to correct its effect.... 

    Rigorous Synthesis of Optimal Heat Integrated Complex Column Sequences Using Genetic Algorithm

    , M.Sc. Thesis Sharif University of Technology Baroughi, Amir Hossein (Author) ; Bozorgmehri, Ramin (Supervisor) ; Farhadi, Fathollah (Supervisor)
    Abstract
    Finding the optimal heat integrated distillation column sequence is an utmost important optimization problem in process engineering. The frequently used approach in this area is to obtain a suitable sequencing candidate and then accomplish the heat integration based on the application of Pinch technology to finalize the design. This approach reduces the problem complexity at the expense of not necessarily reaching the best possible result. This work follows a genetic super structure approach to systematic and rigorous synthesis of optimal multi-component distillation sequences (including simple and thermally coupled complex columns) and simultaneously heat exchanger networks by using a... 

    PlantWide Optimization of Vacuum & Visbreaker Units

    , M.Sc. Thesis Sharif University of Technology Moradi, Sona (Author) ; Farhadi, Fatolah (Supervisor) ; Bozorgmehry Boozarjomehry, Ramin (Supervisor)
    Abstract
    Process optimization is a technique by which the plant operating condition is obtained such that a specific objective is achieved while the other process requirements are still met. These requirements can include product quality specifications, physical equipment limitations, and the constraints corresponding to the environmental, health, and safety issues. Frequently, this objective is an economic one. In the process optimization, the use of improper optimization techniques may lead to impractical results. One of these strategies is the plant wide optimization. In order to show the effect of plant wide optimization, one should use a complicated enough process as a bench mark of the... 

    Application of Membrane Distillation Technology for Treating Saline Water of Sarcheshme Copper Refinery

    , M.Sc. Thesis Sharif University of Technology Mahmoodi Meymand, Negar (Author) ; Shaygan, Jalaleddin (Supervisor)
    Abstract
    Sarcheshme Copper refinery is using ion exchange columns to supply deionized water to the refinery. Every day, 240 cubic meters of waste water from ion exchange columns process are released in nature. The main purpose of this research is to use membrane distillation to purify this wastewater, which reduces the fresh water requirement and at the same time prevents environmental pollution. Membrane distillation technology is capable to purify the high salinity wastewater that other conventional membrane technologies are not able to purify. In this study, the PTFE membrane was used due to its high permeability and low surface energy with pore size of 0.22 μm and membrane thickness of 0.2 to... 

    , M.Sc. Thesis Sharif University of Technology Bagheri Mehrabadi, Niloofar (Author) ; Simchi, Abdol Reza (Supervisor) ; Madaah Hosseini, Hamid Reza (Supervisor)
    Abstract
    The use of magnetic compounds for drug delivery and magnetic imaging has been studied in many studies. The easy use of magnetic particles makes them widespread. By applying a magnetic field, the particles reach the desired position and return to the original state by cutting off the field. The use of these magnetic materials in the nanoscale also adds other benefits, including: convenient and rapid transfer of nanoparticles, rapid repulsion of the kidneys, reducing the risk of overdose, etc. In recent years, the use of quantum dots for the diagnosis and treatment of tumors has attracted much attention. The use of hybrid quantum dots and magnetic nanoparticles can incorporate the desired... 

    High Saline Water Treatment by the Process of Membrane Distillation Combined with Solar Energy

    , M.Sc. Thesis Sharif University of Technology Shokrollahi, Milad (Author) ; Rajabi, Abbas (Supervisor) ; Musavi, Abbas (Supervisor)
    Abstract
    In this study, membrane distillation process was used for treatment of high salinity waters. The focus of this study is to simulate and build a setup of membrane distillation process. Since the membrane distillation process is based on the driving force of the temperature difference, the required temperature is provided by both the use of heaters and the use of solar energy. To increase the feed temperature by solar energy, a black polymer coating on the main membrane is used. The main membrane used in this process is PVDF polymer and the polymer coated on the surface is the PAN polymer. After simulating and constructing the laboratory setup, the influence of a variety of parameters on the... 

    Supervised Semantic Segmentation of RGB-Depth Images

    , Ph.D. Dissertation Sharif University of Technology Fooladgar, Fahimeh (Author) ; Kasaei, Shohreh (Supervisor)
    Abstract
    The labeling process is one of the most important tasks in the field of computer vision. The dense labeling problem is the main step towards 2D and 3D scene understanding. The main goal of dense labeling is to label all pixels of images that are known as a semantic segmentation of images in the related literature. Although the state-of-the-art results are mainly achieved by deep learning methods, traditional methods had also been at the center of attention for some years. In the last decades, convolutional neural networks have changed the landscape of visual recognition tasks such as labeling and semantic segmentation. The most important issues in deep learning models are the hardware and... 

    Reduction of Communication Cost and Effect of Heterogeneity in Federated Learning Via Efficient Clustering of Users

    , M.Sc. Thesis Sharif University of Technology Babaei Vavdareh, Mehdi (Author) ; Behroozi, Hamid (Supervisor) ; Hossein Khalaj, Babak (Supervisor)
    Abstract
    Nowadays sharing data between users and organizations can be difficult due to privacy and legal reasons. Therefore, real-world data is not fully exploited by machine learning methods. A novel model training method called Federated Learning was proposed to alleviate the aforementioned problem by enabling users to jointly train learning models without sharing data. Federated learning utilization faces many challenges among which high communication cost, statistical heterogeneity and system heterogeneity are most important. This research deals with these challenges by proposing two methods of Reduced Clustering Federated Learning (RCFL) and Weighted Federated Distillation (WFD). Moreover, we...