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Production of Gold with High Purity by Electrorefining Process
, M.Sc. Thesis Sharif University of Technology ; Yoozbashizadeh, Hossein (Supervisor)
Abstract
Gold is a noble and precious metal used in various industries, including jewelry, electrical and electronic, catalyst, and medical industries. Multiple processes are used to extract and refine gold; each one has its advantages and disadvantages. In this research Work, comprehensive information on the electrochemical purification process of gold from anode electrode with 75% crude gold and titanium cathode electrode in the chloride electrolyte solution is presented. To perform the purification process, first using the parameters and their levels, including temperature (30, 45, and 60 degrees Celsius), voltage (2, 2.2, and 2.4 volts), and acid concentration (1, 2, and 3 M), Design of...
Thermodynamics and Kinetics Study of Gas Hydrates in Presence of Ionic Liquids
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Cyrus (Supervisor) ; Taghikhani, Vahid (Supervisor) ; Nazari, Khodadad (Supervisor)
Abstract
Gas hydrates are ice-like clathrate compounds. Methane, carbon dioxie and natural gas compounds can form gas hydrate and plug pipelines, in order to preventing of gas hydrate formation, inhibitors like electrolytes are added to the natural gas pipelines. In this work a model proposed to predict the hydrate formation conditions in presence of some inhibitors such as NaCl, KCl, NaBr, KBr, [BMIM][BF4] and [BMIM][Br]. So a new equation of state that can be applied to both electrolyte and associating solutions called GV-SAFT-MSA is developed. Two dialkylimidazolium ionic liquids [BMIM][BF4] and [BMIM][MS] have been investigated for their potential application as novel gas hydrate inhibitors. The...
Experimental Study and Modeling of Saturation Molality of Inorganic Salts in formation water
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Ghotbi, Sirous (Supervisor) ; Yousefi, Leyla (Co-Advisor)
Abstract
Saturation molality for a number of single and mixed aqueous electrolyte solutions containing NaCl, Na2CO3, and K2SO4, was measured at atmospheric pressure over a wide range of temperature. In order to check the repeatability of the experimental data, the experiments were replicated three times and average of the results was considered as final saturation molality. Experimental data of saturation molality for single electrolyte solutions were correlated using the modified UNIFAC–Dortmund model to account for the shortrange interaction. Binary interaction parameters, between water molecules and ionic species were also reported. For the long-range interactions between the ionic species in...
Prediction of Thermodynamic Parameters in Solutions with Similar Composition to Plasma or Blood
, Ph.D. Dissertation Sharif University of Technology ; Abdekhodaie, Mohammad Jafar (Supervisor) ; Ghotbi, Cyrus (Co-Advisor)
Abstract
Serum osmolality is an important physiological quantity that is directly related to health condition of human body. Glucose, urea, and NaCl are the main components which determine the value of serum osmolality. Besides, calcium and potassium are vital inorganic cations for the body. Thus, it is of high importance to investigate the interactions between these physiological solutes in aqueous solution. Thermodynamic quantities like osmotic and activity coefficients contain enthalpic and entropic information and thus are a direct measure of interactions in these complex systems. Thus, theoretical and experimental methods were applied to investigate these thermodynamic parameters in multi-solute...
Thermodynamic Properties of Aqueous Electrolyte Solutions Containing Urea
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Siroos (Supervisor) ; Taghikhani, Vahid (Supervisor)
Abstract
The behavior of biomolecules in mixtures is affected by the presence of electrolytes. For instance, in the presence of an electrolyte, solubility of most biomolecules like proteins,peptids and amino acids can be increased or decreased. As a biomolecule, urea is a protein denaturant and influences protein folding and protein-DNA binding. The presence of ions can affect the interactions between urea and water In this thesis, experimental data of density and electrical conductance of aqueous solutions of urea-NaCl were obtained at different physical conditions. Density measurement experiments were carried out at different temperatures from 20-40 oC. Apparent and infinite dilution molar volumes...
Experimental study and modelling of saturation molality of NaCl in quaternary aqueous electrolyte solutions at various temperatures
, Article Desalination ; Volume 267, Issue 2-3 , February , 2011 , Pages 228-232 ; 00119164 (ISSN) ; Roayaei, E ; Taghikhani, V ; Safekordi, A ; Zahedzadeh, M ; Sharif University of Technology
2011
Abstract
Saturation molality of sodium chloride in mixed aqueous electrolyte solutions containing NaCl, CaSO4 and Na2SO4 was measured at atmospheric pressure over the wide range of temperatures using an equilibrium cell equipped with an accurate temperature control system. The measurements were carried out at different CaSO4 and Na2SO4 concentrations. In order to check the repeatability of the experimental data for the saturation molality of NaCl, the experiments were replicated three times and the values reported were the average of the replicas. To model the data generated in this work, the PDH+UNIFAC-Dortmund activity coefficient model was used. The model used to predict the mean ionic activity...
Mapping geographical inequalities in oral rehydration therapy coverage in low-income and middle-income countries, 2000-17
, Article The Lancet Global Health ; Volume 8, Issue 8 , 2020 , Pages e1038-e1060 ; Lindstedt, P. A ; Blacker, B. F ; Johnson, K. B ; Baumann, M. M ; Schaeffer, L. E ; Abbastabar, H ; Abd Allah, F ; Abdelalim, A ; Abdollahpour, I ; Abegaz, K. H ; Abejie, A. N ; Abreu, L. G ; Abrigo, M. R. M ; Abualhasan, A ; Accrombessi, M. M. K ; Acharya, D ; Adabi, M ; Adamu, A. A ; Adebayo, O. M ; Adedoyin, R. A ; Adekanmbi, V ; Adetokunboh, O. O ; Adhena, B. M ; Afarideh, M ; Ahmad, S ; Ahmadi, K ; Ahmed, A. E ; Ahmed, M. B ; Ahmed, R ; Akalu, T. Y ; Alahdab, F ; A Aly, Z ; Alam, N ; Alam, S ; Alamene, G. M ; Alanzi, T. M ; Alcalde Rabanal, J. E ; Ali, B. A ; Alijanzadeh, M ; Alipour, V ; Aljunid, S. M ; Almasi, A ; Almasi Hashiani, A ; Al Mekhlafi, H. M ; Altirkawi, K. A ; Alvis Guzman, N ; Alvis Zakzuk, N. J ; Amini, S ; Amit, A. M. L ; Andrei, C. L ; Anjomshoa, M ; Anoushiravani, A ; Ansari, F ; Antonio, C. A. T ; Antony, B ; Antriyandarti, E ; Arabloo, J ; Aref, H. M. A ; Aremu, O ; Armoon, B ; Arora, A ; Aryal, K. K ; Arzani, A ; Asadi Aliabadi, M ; Atalay, H. T ; Athari, S. S ; Athari, S. M ; Atre, S. R ; Ausloos, M ; Awoke, N ; Ayala Quintanilla, B. P ; Ayano, G ; Ayanore, M. A ; Aynalem, Y. A ; Azari, S ; Azzopardi, P. S ; Babaee, E ; Babalola, T. K ; Badawi, A ; Bairwa, M ; Bakkannavar, S. M ; Balakrishnan, S ; Bali, A. G ; Banach, M ; Banoub, J. A. M ; Barac, A ; Bärnighausen, T. W ; Basaleem, H ; Basu, S ; Bay, V. D ; Bayati, M ; Baye, E ; Bedi, N ; Beheshti, M ; Behzadifar, M ; Behzadifar, M ; Bekele, B. B ; Belayneh, Y. M ; Bell, M. L ; Bennett, D. A ; Berbada, D. A ; Bernstein, R. S ; Bhat, A. G ; Bhattacharyya, K ; Bhattarai, S ; Bhaumik, S ; Bhutta, Z. A ; Bijani, A ; Bikbov, B ; Birihane, B. M ; Biswas, R. K ; Bohlouli, S ; Bojia, H. A ; Boufous, S ; Brady, O. J ; Bragazzi, N. L ; Briko, A. N ; Briko, N. I ; Britton, G. B ; Burugina Nagaraja, S ; Busse, R ; Butt, Z. A ; Cámera, L. A ; Campos Nonato, I. R ; Cano, J ; Car, J ; Cárdenas, R ; Carvalho, F ; Castañeda Orjuela, C. A ; Castro, F ; Chanie, W. F ; Chatterjee, P ; Chattu, V. K ; Chichiabellu, T. Y ; Chin, K. L ; Christopher, D. J ; Chu, D. T ; Cormier, N. M ; Costa, V. M ; Culquichicon, C ; Daba, M. S ; Damiani, G ; Dandona, L ; Dandona, R ; Dang, A. K ; Darwesh, A. M ; Darwish, A. H ; Daryani, A ; Das, J. K ; Das Gupta, R. D ; Dash, A. P ; Davey, G ; Dávila Cervantes, C. A ; Davis, A. C ; Davitoiu, D. V ; De la Hoz, F. P ; Demis, A. B ; Demissie, D. B ; Demissie, G. D ; Demoz, G. T ; Denova Gutiérrez, E ; Deribe, K ; Desalew, A ; Deshpande, A ; Dharmaratne, S. D ; Dhillon, P ; Dhimal, M ; Dhungana, G. P ; Diaz, D ; Dipeolu, I. O ; Djalalinia, S ; Doyle, K. E ; Dubljanin, E ; Duko, B ; Duraes, A. R ; Ebrahimi Kalan, M ; Edinur, H. A ; Effiong, A ; Eftekhari, A ; El Nahas, N ; El Sayed, I ; El Sayed Zaki, M ; El Tantawi, M ; Elema, T. B ; Elhabashy, H. R ; El-Jaafary, S. I ; Elkout, H ; Elsharkawy, A ; Elyazar, I. R. F ; Endalamaw, A ; Endalew, D. A ; Eskandarieh, S ; Esteghamati, A ; Esteghamati, S ; Etemadi, A ; Ezekannagha, O ; Fareed, M ; Faridnia, R ; Farzadfar, F ; Fazlzadeh, M ; Feigin, V. L ; Fereshtehnejad, S. M ; Fernandes, E ; Filip, I ; Fischer, F ; Foigt, N. A ; Folayan, M. O ; Foroutan, M ; Franklin, R. C ; Fukumoto, T ; Gad, M. M ; Gayesa, R. T ; Gebre, T ; Gebremedhin, K. B ; Gebremeskel, G. G ; Gesesew, H. A ; Gezae, K. E ; Ghadiri, K ; Ghashghaee, A ; Ghimire, P. R ; Gill, P. S ; Gill, T. K ; Ginindza, T. G ; Gomes, N. G ; Gopalani, S. V ; Goulart, A. C ; Goulart, B. N. G ; Grada, A ; Gubari, M. I. M ; Gugnani, H. C ; Guido, D ; Guimarães, R. A ; Guo, Y ; Gupta, R ; Hafezi Nejad, N ; Haile, D. H ; Hailu, G. B ; Haj Mirzaian, A ; Haj Mirzaian, A ; Hamadeh, R. R ; Hamidi, S ; Handiso, D. W ; Haririan, H ; Hariyani, N ; Hasaballah, A. I ; Hasan, M. M ; Hasanpoor, E ; Hasanzadeh, A ; Hassankhani, H ; Hassen, H. Y ; Hegazy, M. I ; Heibati, B ; Heidari, B ; Hendrie, D ; Henry, N. J ; Herteliu, C ; Heydarpour, F ; Hidru, H. D. D ; Hird, T. R ; Hoang, C. L ; Homaie Rad, E. H ; Hoogar, P ; Hoseini, M ; Hossain, N ; Hosseini, M ; Hosseinzadeh, M ; Househ, M ; Hsairi, M ; Hu, G ; Hussen, M. M ; Ibitoye, S. E ; Igumbor, E. U ; Ilesanmi, O. S ; Ilic, M. D ; Imani Nasab, M. H ; Iqbal, U ; Irvani, S. S. N ; Islam, S. M. S ; Iwu, C. J ; Izadi, N ; Jaca, A ; Jahanmehr, N ; Jakovljevic, M ; Jalali, A ; Jayatilleke, A. U ; Jha, R. P ; Jha, V ; Ji, J. S ; Jonas, J. B ; Jozwiak, J. J ; Kabir, A ; Kabir, Z ; Kahsay, A ; Kalani, H ; Kanchan, T ; Karami Matin, B ; Karch, A ; Karim, M. A ; Karimi Sari Surendra Karki, H ; Kasaeian, A ; Kasahun, G. G ; Kasahun, Y. C ; Kasaye, H. K ; Kassa, G. G ; Kassa, G. M ; Kayode, G. A ; Kazemi Karyani, A ; Kebede, M. M ; Keiyoro, P. N ; Kelbore, A. G ; Kengne, A. P ; Ketema, D. B ; Khader, Y. S ; Khafaie, M. A ; Khalid, N ; Khalilov, R ; Khan, E. A ; Khan, J ; Khan, M. N ; Khan, M. S ; Khatab, K ; Khater, A. M ; Khater, M. M ; Khayamzadeh, M ; Khazaei, M ; Khazaei, S ; Khosravi, M. H ; Khubchandani, J ; Kiadaliri, A ; Kim, Y. J ; Kimokoti, R. W ; Kisa, A ; Kisa, S ; Kissoon, N ; Shivakumar, K. M ; Kochhar, S ; Kolola, T ; Komaki, H ; Kosen, S ; Koul, P. A ; Koyanagi, A ; Kraemer, M. U. G ; Krishan, K ; Kugbey, N ; Kumar, G. A ; Kumar, M ; Kumar, P ; Kumar, V ; Kusuma, D ; La Vecchia, C ; Lacey, B ; Lad, S. D ; Lal, D. K ; Lam, F ; Lami, F. H ; Lamichhane, P ; Lansingh, V. C ; Lasrado, S ; Laxmaiah, A ; Lee, P. H ; LeGrand, K. E ; Leili, M ; Lenjebo, T. L ; Leshargie, C. T ; Levine, A. J ; Li, S ; Linn, S ; Liu, S ; Liu, S ; Lodha, R ; Longbottom, J ; Lopez, J. C. F ; Magdy Abd El Razek, H ; Magdy Abd El Razek, M ; Mahadeshwara Prasad, DR ; Mahasha, P. W ; Mahotra, N. B ; Majeed, A ; Malekzadeh, R ; Malta, D. C ; Mamun, A. A ; Manafi, N ; Manda, A. L ; Manohar, N. D. D ; Mansournia, M. A ; Mapoma, C. C ; Maravilla, J. C ; Martinez, G ; Martini, S ; Martins-Melo, F. R ; Masaka, A ; Massenburg, B. B ; Mathur, M. R ; Mayala, B. K ; Mazidi, M ; McAlinden, C ; Meharie, B. G ; Mehndiratta, M. M ; Mehta, K. M ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
Background: Oral rehydration solution (ORS) is a form of oral rehydration therapy (ORT) for diarrhoea that has the potential to drastically reduce child mortality; yet, according to UNICEF estimates, less than half of children younger than 5 years with diarrhoea in low-income and middle-income countries (LMICs) received ORS in 2016. A variety of recommended home fluids (RHF) exist as alternative forms of ORT; however, it is unclear whether RHF prevent child mortality. Previous studies have shown considerable variation between countries in ORS and RHF use, but subnational variation is unknown. This study aims to produce high-resolution geospatial estimates of relative and absolute coverage of...
The MSA and the individual ionic activity coefficients
, Article Iranian Journal of Science and Technology, Transaction B: Technology ; Volume 27, Issue 2 , 2003 , Pages 247-252 ; 03601307 (ISSN) ; Modarress, H ; Khoshkbarchi, M. K ; Vera, J. H ; Sharif University of Technology
2003
Abstract
The mean spherical approximation (MSA) has been applied to accurately correlate the activity coefficients of individual ions in aqueòus solutions of single 1:1 electrolytes. In order to account for changes in the hydration of the ions, the size parameters of the ions are considered to be composition dependent. The values of the size parameters show that the hydration of the ions decreases as the electrolyte concentration increases. Results obtained from the full MSA and from a simplified version of MSA (SMSA), were compared. The use of the simplified version had a small effect on the final results and dramatically reduced the computation of the effort
Prediction of hydrate formation for the systems containing single and mixed electrolyte solutions
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 26, Issue 1 , 2007 , Pages 35-45 ; 10219986 (ISSN) ; Rashtchian, D ; Ghotbi, C ; Taghikhani, V ; Khayat, G ; Sharif University of Technology
Iranian Journal of Chemistry and Chemical Engineering
2007
Abstract
In this work the effect of electrolytes on hydrate formation was investigated. To do so, a new model was used in predicting the hydrate formation conditions in presence of both single and mixed electrolyte solutions. The new model is based on the van der Waals - Platteeuw hydrate equation of state. In order to evaluate the values for the activity of water in electrolyte solutions the simplified version of the Ghotbi-Vera Mean Spherical Approximation (SGV-MSA) model was used. According to the SGV-MSA model the ions in the solutions are considered as charged hard spheres with different sizes. The values of the parameters for the SGV-MSA model are independent of temperature and depend only on...
Application of the non-primitive MSA-based models in predicting the activity and the osmotic coefficients of aqueous electrolyte solutions
, Article Fluid Phase Equilibria ; Volume 221, Issue 1-2 , 2004 , Pages 189-196 ; 03783812 (ISSN) ; Ghotbi, C ; Taghikhani, V ; Azimi, G ; Sharif University of Technology
2004
Abstract
The non-primitive mean spherical approximation (NP-MSA) based models were used to correlate the individual and the mean ionic activity coefficients of the symmetric and asymmetric aqueous electrolyte solutions. The results of the models for the mean ionic activity coefficients were directly used to calculate the osmotic coefficient for the electrolyte solutions studied in this work. In the NP-MSA models, the Ghotbi-Vera and the Boublik-Mansoori-Carnahan-Starling- Leland hard sphere equation of state as the reference system coupled with the non-primitive mean spherical approximation model (NP-GV-MSA and NP-BMCSL-MSA models, respectively). In correlating the mean ionic activity coefficients of...
Application of the GV-MSA model to the electrolyte solutions containing mixed salts and mixed solvents
, Article Fluid Phase Equilibria ; Volume 231, Issue 1 , 2005 , Pages 67-76 ; 03783812 (ISSN) ; Taghikhani, V ; Ghotbi, C ; Sharif University of Technology
2005
Abstract
In this work the Ghotbi-Vera mean spherical approximation (GV-MSA) model, coupled with two different expressions for the cation-hydrated diameters, was used in predicting the mean ionic activity coefficients (MIAC) of electrolytes for a number of the mixed-solvent and mixed-salt electrolyte solutions at 25 °C. In all cases the cation diameters in solutions changed with concentration of electrolyte while the anion diameters were considered to be constant and equal to the corresponding Pauling diameters. In application of the GV-MSA model to the electrolyte systems, two different expressions were used for concentration dependency of cation-hydrated diameters, i.e., the GV-MSA1 and GV-MSA2...
Prediction of the aqueous solubility of BaSO4 using pitzer ion interaction model and LSSVM algorithm
, Article Fluid Phase Equilibria ; Vol. 374, issue , July , 2014 , p. 48-62 ; ISSN: 03783812 ; Shokrollahi, A ; Jamialahmadi, M ; Ghazanfari, M. H ; Bahadori, A ; Zendehboudi, S ; Sharif University of Technology
Abstract
Deposition of barium sulfate (or BaSO4) has already been recognized as a devastating problem facing process industries and oilfield operations, mainly owing to its low solubility in aqueous solutions. Predicting and also preventing the overall damage caused by BaSO4 precipitation requires a profound knowledge of its solubility under different thermodynamic conditions. The main aim of this study is to develop a solubility prediction model based on a hybrid of least squares support vector nachines (LSSVM) and coupled simulated annealing (CSA) aiming to predict the solubility of barium sulfate over wide ranges of temperature, pressure and ionic compositions. Results indicate that predictions of...
Activity coefficient prediction for binary and ternary aqueous electrolyte solutions at different temperatures and concentrations
, Article Journal of Solution Chemistry ; Volume 41, Issue 1 , 2012 , Pages 75-88 ; 00959782 (ISSN) ; Ghotbi, C ; Abdekhodaie, M. J ; Sharif University of Technology
Abstract
The mean spherical approximation (MSA) model, coupled with two hard sphere models, was used to predict the activity coefficients of mixtures of electrolyte solutions at different temperatures and concentrations. The models, namely the Ghotbi-Vera-MSA (GV-MSA) and Mansoori et al.-MSA (BMCSL-MSA), were directly used without introducing any new adjustable parameters for mixing of electrolyte solutions. In the correlation step, the anion diameters were considered to be constant, whereas the cation diameters were considered to be concentration dependent. The adjustable parameters were determined by fitting the models to the experimental mean ionic activity coefficients for single aqueous...
Measurement and correlation of surface tension for single aqueous electrolyte solutions
, Article International Journal of Thermophysics ; Volume 31, Issue 4-5 , May , 2010 , Pages 852-859 ; 0195928X (ISSN) ; Taghikhani, V ; Ghotbi, C ; Sharif University of Technology
2010
Abstract
In this study, the values of the surface tension for a number of single aqueous electrolyte solutions were measured at various temperatures and electrolyte concentrations using the well-known and computer-aided pendant-drop method. In order to conduct the experimental measurements, a high-pressure IFT-700 apparatus, equipped with a view cell and a data acquisition system, was used. The systems studied in this study were aqueous solutions of KCl, NaCl, CaCl 2, and Na 2SO 4. The pooled standard deviation and the confidence limit of the surface-tension data for a 95 % confidence level were determined to be 0.17mN · m -1 and σ̄ ± 0.19, respectively. It should be noted that while the surface...
Application of the MSA-based models in correlating the surface tension for single and mixed electrolyte solutions
, Article Journal of Chemical Thermodynamics ; Volume 41, Issue 11 , 2009 , Pages 1264-1271 ; 00219614 (ISSN) ; Taghikhani, V ; Ghotbi, C ; Sharif University of Technology
2009
Abstract
Experimental values for surface tension of single and mixed electrolyte solutions were correlated using the models based on the perturbation theory. The Mean Spherical Approximation (MSA) model, coupled with the Ghotbi-Vera (GV) and the Mansoori et al. (BMCSL) equations of state, were used to correlate the experimental values of the surface tension. The results showed that the models can favourably correlate the experimental values for single electrolyte solutions. However, it was observed that the GV-MSA model can more accurately predict the surface tension for single electrolytes, especially at higher concentrations. Two different expressions for concentration dependency of cation hydrated...
The role of ion partitioning in electrohydrodynamic characteristics of soft nanofluidics: Inclusion of EDL overlap and steric effects
, Article Chemical Engineering Science ; Volume 190 , 2018 , Pages 443-458 ; 00092509 (ISSN) ; Saidi, M. H ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
In this paper, we aim to account for the partitioning of finite sized ions and electric double layer (EDL) overlapping effects on the electrostatics and hydrodynamics of soft nanofluidics by stablishing a modified Poisson-Boltzmann (MPB) equation enjoying mean field approach. The application of the present MPB equation enables us to describe the interaction between the steric effect and electrostatic repulsion of EDL ions due to permittivity difference of polyelectrolyte layer (PEL) and electrolyte solution. Utilizing the Debye-Hückel approximation pertinent to low surface potentials, we analytically derive the solutions of electric potential and velocity profiles of mixed electroosmotic and...
A new hydration model in correlating the mean ionic activity coefficient and density of aqueous electrolyte solutions
, Article Journal of Dispersion Science and Technology ; Volume 31, Issue 5 , 2010 , Pages 641-649 ; 01932691 (ISSN) ; Taghikhani, V ; Vossoughi, M ; Sharif University of Technology
Abstract
In this article, a new hydration model has been proposed to study the phase behavior of aqueous electrolyte solutions. The proposed model distinguishes between an anion and cation in the electrolyte solution. The model has three adjustable parameters which can be obtained using the experimental data of the mean ionic activity coefficients for 113 electrolyte solutions. The results of the proposed model were compared with those of obtained from the Pitzer, the E-NRTL and the E-Wilson models. The results showed that the proposed model can accurately correlate the mean ionic activity coefficients of the aqueous electrolyte solutions than the other models. Also, the proposed model was used in...
Correlation and prediction the activity coefficients and solubility of amino acids and simple peptide in aqueous solution using the modified local composition model
, Article Fluid Phase Equilibria ; Volume 255, Issue 2 , 2007 , Pages 160-166 ; 03783812 (ISSN) ; Taghikhani, V ; Vossoughi, M ; Sharif University of Technology
2007
Abstract
In this work, the modified Wilson model was used to obtain the activity coefficients of amino acids and simple peptides in non-electrolyte aqueous solutions. The Wilson model was modified using the new local mole fraction proposed by Zhao et al. and non-random case for the reference state. The binary interaction parameters (BIP) of the modified Wilson model for amino acid-water pairs were obtained using the experimental data of the activity coefficients for amino acids available in the literature. The modified Wilson model was also used to correlate the solubility of amino acids in water and the values of Δh/R, Δs/R, and Δg/R of the solutions studied were reported. The results obtained...
Extension of the dense system equation of state to electrolyte solutions
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 26, Issue 1 , 2007 , Pages 17-33 ; 10219986 (ISSN) ; Panahi, A ; Sharif University of Technology
2007
Abstract
In this work we have applied the Dense System Equation of State (DSEOS) to electrolyte solutions. We have found that this equation of state can predict the density of electrolyte solutions very accurately. It has been tested for different electrolytes solutions at different temperatures and compositions. A hypothetical binary model has been applied to find the dependencies of parameters of this equation of state on solution temperature and composition. Using such a simple model the heat capacity of NaCl solution was calculated for which the absolute percent deviation is less than 2 %. The DSEOS is tested for the following electrolytes: Na2SO4, MgCl2, MgSO4, KCl, NaCl, and NaBr. We found that...
A transient model of vanadium redox flow battery
, Article Mechanics and Industry ; Volume 17, Issue 4 , 2016 ; 22577777 (ISSN) ; Elyasi, S ; Sharif University of Technology
EDP Sciences
2016
Abstract
It has been attempted to gain a new viewpoint in transient cell modeling of vanadium redox flow battery. This has been achieved by considering electrochemical relations along with conceptual electrical circuit of this kind of battery. The redox flow battery is one of the best rechargeable batteries because of its capability to average loads and output power sources. A model of transient behavior is presented in this paper. The transient features are considered as the most remarkable characteristics of the battery. The chemical reactions, fluid flow, and electrical circuit of the structure govern the dynamics. The transient behavior of the redox flow battery based on chemical reactions is...