Sharif Digital Repository

Octahedral crystals of Fe-Metal-organic frameworks like Fe-MIL-101, which is the most stable and active metal-organic frameworks; in combination with graphitic carbon nitride nanosheets could significantly enhance the photocatalytic activity of g-C3N4 for inorganic dye degradation under the irradiation of visible light application. This appropriate cocatalyst modifies the performance of semiconductor via suppressing the recombination of photo-induced carriers and since the synthesized composite prepared by in-situ procedure possesses close contact between each other, the migration of electrons in the photocatalytic reaction will be continued, so the degradation process via the active species... 

The main aim of present thesis is to synthesis and characterize of ferrite nanocomposites as a new generation phtocalyst and their application in degradation of various types of environmental pollutants in different irradiation time and dark conditions. Ferrites have been used anchored to carbon allotropes such as graphene oxide and carbon nanotubes, in order to improve their photocalytic activity as well as phase structure, textural and optical properties. Firstly, a new SnS2-BiFeO3/rGO nanocomposite has been prepared to increase the visible-light-responsive photodegradation of organic dyes such as cationic methylene blue (MB) and anionic methyl orange (MO). The obtained results showed... 

The short life of Polymer Electrolyte Membrane (PEM) fuel cells is one of the critical criteria to their commercialization. A longer operation life time should be achieved to reach high reliability, low $/kWh cost and to use fuel cells as economical alternative energy systems.Therefore,diagnosing degradation mechanisms and the causes of power loss in fuel cell life time is of great importance. Operating conditions affect output power density and performance degradation. To achieve maximum power generation through fuel cell life time, a model is needed which is able to estimate power density and performance degradation simultaneously regarding to operating conditions. In present work, a... 

The energy systems efficiency is a great issue confront power plants professionals. Besides using high-tech components in power plants, plant operation optimization can significantly improve energy efficiency and economic performance, as efficiency of plant components generally depends on operating conditions. In addition, system preventive maintenance can reduce plant operation and failure costs, however it is also costly when done frequently. Therefore, optimizing operating conditions and preventive maintenance intervals can minimize the expected total cost of plant due to operation, failures and preventive maintenances. In recent years, the use of optimization models to determine plant... 

Up till now, various contributions of research to soil-structure-interaction context have been primarily focused on structural systems exhibiting elastic-perfectly plastic material behavior. In this paper, combined effects of material degradation, p-delta, and soil-structure-interaction considering foundation uplift have been deemed to determine seismic response of a single degree of freedom system. The system is composed of a column with a lumped mass on top that is placed on a rigid foundation. The foundation is mounted on Winkler springs and dashpots to account for soil-foundation compliance and material/radiational damping. The springs are tensionless to guarantee that uplift phenomenon... 

Tehran Refinery, as an industrial center that has significant water consumption in Tehran, intends to use the flow of water from the treatment plant south of Tehran after final preparation, with the aim of managing water resources and meeting its needs. And it uses a biological activated carbon (BACF) filter to reduce the DOC concentration. In these filters, the removal of organic matter is performed by the adsorption process as well as the biodegradation process by microorganisms grown on activated carbon. The presence of biofilm leads to continuous bio-regeneration of activated carbon during the water treatment process. Therefore, in this study, by examining the performance of these... 

In this project, metal oxides loaded on different supports were used in the heterogeneous electro-Fenton (EF) process for organic pollutants removal. At first, Fe3O4/AC was synthesized for catechol degradation as a phenolic compound. 98.2% removal of catechol was achieved by operational conditions optimization. The catalytic activity of Fe3O4/AC was remained constant after 6 cycles. In the other study, reduced graphene oxide was used as a support for the magnetite nanoparticle catalyst. The catalytic activity of Fe3O4/rGO in EF degradation of reactive red 195 (RR195) dye was studied and 93.34% removal was obtained. Response surface methodology (RSM) was used and a quadratic model with... 

The aim of conducting this research is to study, fabrication and photocatalytic application of electrospun ZnO-based composite nanofibers. One of the most important challenges is to apply photocatalyst under solar irradiation and improve its activity for pollutant degradation. ZnO is a wide band gap semiconductor, hence, it is not active under the visible light. In Iran, we have at least 300 sunny days in a year. Therefore, fabrication and application of photocatalytic material with activity under the sunlight which contains 47% of visible light is so vital in our country. Since CuO is a visible light active photocatalyst and its interface with ZnO forms a type I heterojunction, this... 

Nanoporous metal-organic frameworks are among the new and advanced compounds that have attracted attention of researchers due to their unique properties such as high surface area, high porosity and regular structure. These compounds can catalyze and degrade pollutants. Due to the high consumption of organic compounds, especially textile dyes, the pollution caused by wastewater is increasing in various industries. Disposal of wastewater containing organic pollutants into aquatic environments can alter the natural color, change the taste of water and disturb the life of living organisms. If the dyes are left untreated in aquatic ecosystems, they can remain in the environment for a very long... 

consumption of which (especially azo dyes) have been increasing nowadays, causing the increase of textile wastewaters. Usually, these wastewaters contain an immense number of dyes, and if these dyes release in the environment especially in waters, they cause some problems, such as the change of watercolor as well as taste, and affect creatures' lives severely. Moreover, If the dyes are left untreated in aquatic ecosystems, they can remain in the environment for a very long time, resulting in harmful and irreversible effects. Azo dyes are classified as mono, di-, three, azo dyes due to their bonds. Because dyes are increasingly used, nowadays, different methods are developed for the treatment... 

Nanocomposite FeVO4/CeO2 was synthesized by hydrothermal method and was applied for removal of methyl orange. This nanocomposite was characterized by SEM, FT-IR, XRD, BET methods. SEM images showed that FeVO4 nanorode decorated on CeO2 spherical particles. The results of XRD patterns confirmed the triclinic structure for Fe(III)vanadate and the cubic fluorite structure for cerium oxide. The surface area of FeVO4, CeO2 and FeVO4/CeO2 was determined by BET analysis which the results represented an increase in surface area in nanocomposite using cerium oxide as support. The electro-Fenton reaction was performed in undivided electrochemical reactor using stainless steel electrodes and the... 

In this research, BiFeO3/Bi2WO6 nanocomposite was synthesized by hydrothermal method and utilized for piezocatalytic degradation of methyl orange dye. This nanocomposite was characterized by XRD, FE-SEM, FT-IR, DRS, PL and Raman spectroscopy. The results of XRD patterns confirmed the rhombohedral crystal structure of BiFeO3 nanoparticles and orthorhombic crystal structure of Bi2WO6 nanosheets. FT-IR and Raman spectroscopy approved the existence of chemical bonds and non-centrosymmetric structure of catalysts. The FE-SEM images displayed the formation of BiFeO3 nanodisks and the Bi2WO6 nanosheets and the decoration of BiFeO3 nanodisks on the Bi2WO6 nanosheets. By using the data of DRS... 

In this research, piezocatalysts ceramics Bi4Ti3-xMnxO12 (x=0,0.1,0.2,0.3) were synthesized by hydrothermal method and utilized in the process of rhodamine B piezocatalytic degradation.These piezocatalysts were characterized using XRD, FE-SEM, FT-IR, DRS and PL methods. The results of XRD patterns confirmed the formation of orthorhombic crystal structure of Bi4Ti2.9Mn0.1O12 and Bi4Ti3O12 piezocatalysts. FT-IR spectroscopy confirmed the existence of chemical bonds of piezocatalysts. FE-SEM images showed the formation of Bi4Ti2.9Mn0.1O12 and Bi4Ti3O12 nanoplates. Using DRS analysis data, the absorption edge wavelength and energy gap of the synthesized piezocatalysts were obtained. Also, the... 

Due to the continuing progress in CMOS technology and increased number of cores within a chip, multiple components with different levels of criticality have been integrated into a common hardware platform. These systems with these characteristics are known as Mixed-Criticality Systems (MCS). Also, due to the migration towards multi-core systems, power consumption and specifically instantaneous power consumption is the main concern. To avoid the use of cooling technology, we need to reduce the instantaneous power consumption of the system. However, most existing approaches in MCS have paid attention to reliability guaranteed and energy minimization. Therefore, we consider a dynamic scheduling... 

A triple photocatalytic composite of biochar, metal-organic framework and phosphomolybdic acid was prepared through solvothermal treatment of iron (III) chloride hexahydrate, terephthalic acid, lavandulifolia-derived biochar and phosphomolybdic acid. The composite was thoroughly characterized and utilized for photodegradation of organic dyes under visible light irradiation. Investigations of reaction variables confirmed that, the highest yield of 96.2% for a cationic Rhodamine-B (RhB) dye was achieved at ambient temperature when using 0.07 g of catalyst at pH of 7 and a dye concentration of 10 ppm. The activity of the composite was superior compared to its individual components implying... 

Development of novel photosensitizers and photocatalysts with near-infrared (NIR) light activity and efficient sunlight harvesting is of great importance in photodynamic therapy and environmental remediation. In this work, very small (20 nm) upconverter SrF2:Yb,Tm@CaF2:Yb@Fluorine-doped TiO2 heteronanoparticles (denoted as UCNPs@TiO2) with strong UV-blue emission and wide-spectrum photocatalytic activity were synthesized via a facile three-step hydrothermal method, for the first time. The SrF2: Yb,Tm upconverter nanoparticles were produced as the light-emitting core, epitaxially-grown CaF2 : Yb as the middle shell to enhance the Upconversion luminescence efficiency and TiO2 as the... 

Photocatalytic degradation is one of the developing modern and effective methods for decontamination of hazardous pollutants of chemical industrial wastewater. This method has several advantages including the possibility of using free and sustainable energy of sun. However, it is still needed to active photocatalysts under solar light and also the enhancement and optimization of operating parameters, and consequently, these topics are selected as goals of the present thesis. Accordingly in this research, first, to obtain a photocatalyst that is highly efficient (especially under visible and solar light), multi-doping and polyethylene glycol (PEG) were used and for the first time,... 

Triclosan is widely used as an antibacterial agent in personal health care products, especially in recent years with the spread of the Coronavirus. This substance is one of the emerging contaminants, and due to its stable and toxic nature, this material cannot be destroyed in the process of biological wastewater treatment. In this research, a new bacterial strain was isolated and purified from industrial wastewater for the biological removal of triclosan. Based on 16S rRNA sequencing, it was found that the isolated strain belongs to the Enterobacter cloacae family and can grow in high concentrations of triclosan. It was observed that naphthalene dioxygenase and laccase enzymes are active... 

The N-doped rGO/NiFe2O4@Ti-doped ZnO as a novel ternary nanocomposite with magnetic recyclable was obtained by a facile and low-cost hydrothermal method. The structure, morphology, and optical as well as magnetic properties of synthesized nanocomposite were analyzed using the X-ray diffraction (XRD), Fourier-transform infrared spectra (FTIR), Raman spectroscopy, Emission scanning electron microscopy (FESEM) with Energy dispersive spectra, Transmission electron microscopy (TEM), UV-vis diffusive reflectance spectra, and Vibrating sample magnetometer (VSM). The photocatalytic activity was determined by the degradation of Methylene blue (MB) and Methylene orange (MO) dyes under visible light... 

In this research, the synthesis of the electrospum nano fiber doped zinc oxide and its photocatalyst usage was investigated. The band gap of the zinc oxide in the area of UV leads to deactivation of this material at the visible light. With due the attention to sunny weather in Iran and the fact that about 50 percentage of sunlight is visible light, producing and usage of catalyst materials actived at visible light is economical. Doping is one of the ways of activating ZnO at visible light, so in this research thiourea is used as the source of ZnO doping. The results of the expriments done at visible light and also spectrums of DRS, XPS and XRD prove that the doping is happened. Also, in this...