Sharif Digital Repository

Nitrates of lithium, cobalt and nickel were used to synthesize LiNi0.8Co0.2O2 cathode material through sol-gel technique. Various synthesis parameters such as calcination time, temperature, chelating agent and the solvent were studied to determine the optimized condition for processing the cathode nono materials. TG/DTA tests were used to identify the optimized calcination temperature. Different techniques such as ICP, XRD and TEM were employed to characterize the chemical composition, crystal structure, size and morphology of the powders. Micron and nano-sized powders were produced using citric / oxalic and TEA as chelating agent, respectively. Results show that the best condition for... 

Inappropriate effects of fossil fuels and conventional power generation systems on the environment have necessitated a sustainable energy system for the next decade by growing interests in renewable energy systems. The world’s most fast-growing renewable energy resource is the wind energy. The main problem of wind power is the power fluctuations at the load side caused by the variable nature of wind speed, and the main issue in case of remote locations is the long-term storage of power generated by wind turbines. Batteries can be used to store a limited amount of energy for a short time. Although new advances in this field have been achieved, most common type of batteries is hardly able to... 

Constantly rising fuel prices and environmental consciousness have caused alternative transport solutions to be considered.Recently, batteries and electric vehicle industries have developed to become a reasonable alternative for gasoline powered cars. Plug-In hybrid electric vehicles could be connected to the electrical grid to be recharged. To ease the charging process, one solution could use an on-board charger to charge the electric vehicle. This charger should be able to be connected to a conventional outlet for convenience reasons and moreover, it should be a grid friendly charger in order not to pollute the electrical network. After studying the introduced structures for electric... 

Focusing on fossil fuel to secure energy demand lead to big challenges. Hydrogen as alternative for fossil fuel has attracted a lot of attentions. Fuel cell with an electrochemical reaction which it’s byproducts are water and heat convert Hydrogen into electricity. High efficiency and low environmental pollution, persuade many researchers toward fuel cell commercialization. But problems such as high cost, high power oscillation and inertia, avoid fuel cell from significant development. One way to deal with these problems is using the fuel cell and battery hybrid system. In recent decade too many research has been made in utilizing this hybrid system in transportation. This project... 

Nowadays, high reliability requirements for commercial and industrial loads, make it necessary to install microgrids for supplying the loads during power outages. Due to the fact that solar energy is clean, free of noise pullotion and also it benefits from the governmental obligations, it is a wealthy choice for supplying the load in microgrid. Designing and operation of the photovoltaic microgrid are the two important steps that should be considered. In this thesis, these two steps have been investigated by integrating a battery system into a solar PV plant and control of PV mictrorid in islanded mode. In the designing step, the optimum battery bank is calculated. For calculating the... 

In Li batteries, lithium ions are exchanged between two electrodes, along with the accompaning electron transfer to maintain riability good ionic conductivities and electrolytes stability are achived through additives to the electrolyte. Such matrial should possess good anions acceptability. This work investigates the potential of aza-ethers in this regard. The softness criteris is basically employed. DFT calculation for selected molecules of different size, substituents and interacting atoms are used to correlate softness, electrophilicity, Fukui no, etc to the usefulness of the corresponding matrials  

In recent years lithium-air batteries captured worldwide attention because of their high energy density. Solid state electrolytes is one of the main components of lithium-air batteries. Lithium almunium titanium phosphate(LATP) is a nasicon type ion conduction which may be of great potential as solid electrolyte. The object of this thesis was the preparation of LATP solid electrolyte which can be used in a lithium-air battery. To reach this goal LATP powder was synthesized using a solution-based method and an appropriate crystallization temperature was selected based on obtained results of X-ray diffraction analysis. In the next step solid electrolytes was prepared under different pressing... 

In this project, a model which had been suggested for a lithium battery is used with the assumption of using C.N.T instead of activated carbon for the cathode. This battery include lithium foil, C.N.T and solution as anode, cathode and electrolyte. The electrolyte solution consist of lithium salt and a separator. The mathematical solving of the model consisted of using two CPM and DFM methods. In DFM method, a concentration gradient was considered as the driving force for diffusion and in the CPM method chemical potential as the driving force. Furthermore CPM method considered energy interaction between ions. Changing physical parameters of cathode and modification of model parameters... 

Occurrence of natural disasters such as flood, windstorms, tsunamis and earthquakes has caused striking effects on critical infrastructures like power systems in recent decades. There are some examples of high-impact low-possibility (HILP) events which causes catastrophic effects on power systems. Traditionally, planning and operational studies of power system have been run taking into account some reliability metrics. Although, the reliability indices can represent the ability of a system in confronting with possible failures of components, they are unable to efficiently consider the effects of severe events such as earthquake and other HILP events. Moreover, traditional power systems were... 

Today, considering the global demand for reducing greenhouse gas emissions, rechargeable batteries are considered as a source of energy in electric vehicles, hybrid electric vehicles and smart grids. In all these applications for secondary batteries, the battery management system requires an accurate estimate state of charge of each cell. However, this estimate is difficult particularly for battery aging. In this study, a lithium-ion battery is modeled by using multidimensional multiphysics modeling and simulated in a comsol. In this simulation, the effect of the thermal conductivity coefficient on the battery temperature, initial salt concentration in electrolyte and the rate of discharge... 

As one of the main features of Li-Ion batteries, internal resistance severely affects performance and characteristics of these batteries e.g. output power and working voltage. In this study, we tried to understand role of internal resistance on microstructure development and provide a correlative relation between microstructural features and performance of lithium-ion batteries. To catch this target, four types of Li-Ion battery chose, varying cathode type. These batteries were exposed to both normal and severe cycling conditions. Regarding to the key role of current rate on the performance of Li-ion batteries, an extensive research on different types of batteries at various current rates... 

In Lithium ion batteries, the separator is membrane that placed between the cathode and the anode is one of critical components. Its primary function is to effectively transport ionic charge carriers between two electrodes as an efficient ionic conductor as well as to prevent the electric contact between them as a good electric insulator. The separator does not involve directly in any cell reactions, but its structure and properties play an important role in determining the battery performance. Commercially available polyolefin separators low cost, good electric resistance, high electrochemical stability, and effectively prevent thermal runaway caused by the electrical short-circuits or... 

The vanadium redox flow battery (VRB) is a promising solution for storing renewable energy, such as wind and solar energy and promising for replacing these energies with fossil energies. Since a great proportion of a current battery cost is due to the presence of a nafione membrane in the middle of the battery cell, the membrane removal reduces the cost of these batteries. In this project, a single cell membrane-less flow battery in discharge mode has been simulated by COMSOL software. In order to remove the membrane from this battery, a Y-shaped microchannel, lateral faces containing thin porous film which act as anode and cathode, has been used. The small size of the channel and low... 

In this dissertation, two parts of research has been conducted. First, with the aim of minizing the fluctuations of power output of wind farms and the need for energy storage system, optimization of wind farm (WF) layout has been studied. Deployment of battery energy storage system (BESS) is a viable option to alleviate the inherent power fluctuation of wind farms. In this thesis and based on the power spectrum density (PSD) theorem, it is hown that the WF layout affects not only the total harvested energy but also the level of power fluctuation, which in turn influences required capacity of battery energy storage system (BESS) needed to mitigate the inherent power fluctuation of the wind... 

Study the potential and internal resistance of the electrochemical cells in different states of charge are important for practical and usage. Measurement of these parameters in an electrochemical cell is inseparably bound to the electrochemical resistance, temperature and also geometric states of different parts of the cell. In This project we focus on power and resistance of one kind of batteries called thermally activated batteries. These batteries are active after receiving heat and they are inactive at room temperature. Two of the most important models of these batteries that are discussed in this project are LiSi/ LiCl- KCl / FeS2 battery ( with liquid - molten salt electrolyte ) and... 

The main objective of this research is to experimentally evaluate thermal behavior of commercially available rechargeable Li-ion batteries based on minimum measurements on main battery parameters and then develop experimental based models to investigate their thermal behavior. Li-ion batteries with Graphit anodes and Li(Ni0.8¬Co0.15Al0.05)O2 cathodes will be used for this purpose. Voltage and temperature developments during cycling under various currents at controlled ambient temperatures are measured by battery tester. Measurements show that temperature evolutions demonstrate falls and rises at specific State-of-Charge (SoC) of the battery during cycling and therefore some heat consumers... 

Nowadays, with the development of the generation and storage technologies of electrical energy, increasing attention to environmental issues, and interest in improving the reliability of electrical energy distribution networks, the motivation to develop the distribution networks from pssive to active mode. Although, the utilizing of electrical energy storage systems (EESs) made technical and economic analysis of power system more complicated, but some of these challenges have faciliated by microgrids. Indeed, microgrids, as low voltage and medium voltage networks, can provide a set of significant benefits at the level of distribution networks by improving energy efficiency, power quality,... 

Due to environmental concerns and continuous decrease in the price, photovoltaic (PV) generations have been increasing in the recent years. PV units can operate in grid-connected or islanded modes. In grid-connected mode, the PV unit delivers its generated power to the grid; on the other hand, in islanded mode, it supplies the local loads. In this research, a new decentralized power management and load sharing method for a photovoltaic based islanded microgrid consisting of various PV units, battery units and hybrid PV/battery units is proposed. Unlike the previous methods in the literature, there is no need to communication among the units and the proposed method is not limited to the... 

Recently lithium iron silicate (Li2FeSiO4) has been used as a new cathode material for lithium ion battery. Li2FeSiO4 has such benefits like low raw material price so lower production cost, lower environmental pollution, higher safety, electro chemical and cyclic stability and high theoretical capacity of 166 mAh/g against other cathode materials like LiMn2O4, LiBNiO2, LiCoO2 and LiFePO4. In this research Li2FeSiO4 was synthesized through sol gel synthesis method and effect of chelating agent concentration, calcination temperature and time has been investigated. To determine the appropriate calcination temperature range, TG/DTA was performed. Then the dried gel powder was calcined at each... 

Interest in lithium sources has been increasing because of wide applications of the metal in high-energystorage lithium batteries and its compounds in otherfields.Lithium appears in lake, brines and several minerals such as spodumene, petallite, and lepidolite. Several methods such as ion exchange (adsorption), solvent extraction, and coprecipitation have been investigated for the extraction of lithium from seawater, brine, and geothermal water. The adsorption method is suitable for recovery of lithium from seawater because certain inorganicion-exchange materials show extremely high selectivity for lithium ions only.The objective of this study is to evaluate the applicability of nano...