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    Wettability Alteration of Reservoir Rocks to Super Gas-Wet Condition Using Nanocomposite by Applying Contact Angle Measurement for Gas-Crude Oil System

    , M.Sc. Thesis Sharif University of Technology Zandi, Ahmad (Author) ; Ghazanfari, Mohammad Hossien (Supervisor) ; Fatemi, Mobeen (Supervisor) ; Esmaeilzadeh, Pouriya (Co-Supervisor)
    Abstract
    Today, increasing the productivity of reservoirs is more important than in the past, while the use of nanoparticles to change the wettability of rock and increase the recovery factor from the reservoir has been considered by many researchers. Despite previous studies on the use of nanoparticles to change the wettability of rock to gas-wet, the use of nanocomposites with super gas-wet at high temperature and pressure in the crude oil-gas system has rarely been considered. In this research, several nanocomposites with different structures have been synthesized in the laboratory and nanofluids with different formulations have been used to coat the rock thin sections and measure droplet contact... 

    Core-scale Mechanistic Simulation of Engineered Salinity Waterflooding Using Bond-Product-Sum Method

    , M.Sc. Thesis Sharif University of Technology Almasian, Pourya (Author) ; Mahani, Hassan (Supervisor)
    Abstract
    Considering the world's diminishing oil reserves, as well as the growing demand for oil and energy consumption, Enhanced Oil Recovery (EOR) techniques are becoming increasingly important in the attempt to improve oil production. Engineering salinity waterflooding has gained widespread attention and popularity in the last two decades due to its environmental friendliness, lack of expensive additives, low operating costs, and ease of use as an oil extraction process. The goal of this study is to use an innovative method to develop a mechanistic approach model that simulates and forecasts the mechanism and performance of the engineered water flooding process. Wettability alteration, the most... 

    Mechanistic Investigation of Enhanced Oil Recovery by Engineered Water Using Computational Fluid Dynamics at Pore Scale

    , Ph.D. Dissertation Sharif University of Technology Namaee Ghasemi, Arman (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Despite the proven advantage of the engineered water flooding technique, a coherent and mechanistic understanding of the fundamental phenomena occurring at pore scale is lacking. Most of the available simulation models have a phenomenological approach and have limited predictive capability. One of the key questions is how to justify and relate large (Darcy) scale observations to effects and phenomena that essentially occur at much smaller scales (i.e. pore and molecular level). Furthermore, two-phase flow dynamics and the effect of complex interplay between wettability, capillary number, and ions dispersion in a heterogeneous porous medium on the trapping and mobilization of oil at pore... 

    Pore-scale Simulation of Trapping Phenomena and Hysteresis Effect in Porous Media

    , M.Sc. Thesis Sharif University of Technology Tabibnejad Azizi, Mehdi (Author) ; Fatemi, Mobeen (Supervisor)
    Abstract
    So far, many studies have been carried out on the core-scale regarding the effects of hysteresis on the macro-scale properties of systems including fluids and porous rock, however, many issues related to the physics of the problem (especially regarding the way fluids are distributed and the trapping of the non-wetting phase) at the pore-scale need further investigation. In the process of multiphase fluid flow in porous media, hysteresis refers to the dependence of the results of the fluids’ displacements on the history of fluid saturation and the direction of saturation changes (increasing or decreasing). The first step to investigate the hysteresis effect is to determine the amount of fluid... 

    Wettability Alteration and its Effect on Oil Recovery by using Colloidal Nano-Silica in Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Sadatshojaie, Ali (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Goodarznia, Iraj (Supervisor) ; Badakhshan, Amir (Co-Supervisor)
    Abstract
    As many oil fields are reaching their final stage of production, new technologies are required in order to maintain production and increase recovery of hydrocarbons. Among these techniques of enhanced oil recovery (EOR), chemical injection method focuses on increasing the effectiveness of waterflooding. Due to the relatively high costs and considerable adsorption on the rock formations, this method is no longer used. In Recent years nanofluids (nanoparticles dispersed in brine) have been used as a cheap, efficient and environmentally friendly alternative more than any other chemicals. It has been stated that the Smart Water method and enhanced oil recovery by SiO2 nanoparticles are effective... 

    Study of Industrial Wastewater as Low-Salinity Water for Enhanced Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Hossein (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Considering the water tensions, especially in the Middle East, water resources for the implementation of water-based EOR methods are shown to be critically limited. Water sources such as industrial wastewater hold great potential to be used for this purpose due to their significant available volume and the need for their disposal because of environmental regulations. In this research, the potential of injecting industrial wastewater, as low-salinity water, in an Iranian carbonated oil reservoir has been thoroughly investigated by conducting core-scale experiments. In this regard, we also developed a guideline for designing various types of experiments to use this "unconventional" injection... 

    Monitoring the influence of dispersed nano-particles on oil-water relative permeability hysteresis

    , Article Journal of Petroleum Science and Engineering ; Vol. 124, issue , December , 2014 , p. 222-231 ; ISSN: 09204105 Parvazdavani, M ; Masihi, M ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    In recent years, polysilicon nanoparticles are used to enhance the oil recovery through the water injection process in oilfields. The contributing mechanisms are the reduction of interfacial tension and wettability alteration which lead to improving or decreasing the oil phase relative permeability and can be traced by change of relative permeability curves. However, profound understanding of the effect of dispersed nano-silica particles on the hysteretic behavior of relative permeability curves remains a controversy topic in the literature.The current study illustrates the influence of dispersed silica particles on hysteretic trend of two-phase curves of oil-water relative permeability.... 

    Effect of time and temperature on crude oil aging to do a right surfactant flooding with a new approach

    , Article Proceedings of the Annual Offshore Technology Conference ; Vol. 2, issue , 2014 , p. 1136-1142 ; ISSN: 01603663 ; ISBN: 9781632663870 Heidari, M. A ; Habibi, A ; Ayatollahi, S ; Masihi, M ; Ashoorian, S ; Sharif University of Technology
    Abstract
    Dilute Surfactant flooding has been recognized as one of the significant processes in chemical flooding. Many oil reservoirs became appropriate candidates for surfactant/water flooding when screening criteria was developed. Injected surfactant tried to mobilize the residual oil that was trapped in interstice. The main contributing mechanism to enhance oil recovery by surfactant flooding was defined as rock wettability alteration. Wettability is one of the substantial parameters to choose the best approach for a successful surfactant flooding in which tiny change in wettability will lead to improve oil recovery fundamentally. In this experimental study the effect of different aging time and... 

    Monitoring wettability alteration by silica nanoparticles during water flooding to heavy oils in five-spot systems: A pore-level investigation

    , Article Experimental Thermal and Fluid Science ; Vol. 40, issue , July , 2012 , p. 168-176 ; ISSN: 08941777 Maghzi, A ; Mohammadi, S ; Ghazanfari, M. H ; Kharrat, R ; Masihi, M ; Sharif University of Technology
    Abstract
    It is well known that the displacement efficiency of EOR processes is mainly affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of pores surfaces remains a topic of debate in the literature. Furthermore, a little is known about how the dispersed silica nanoparticles affect the microscopic/macroscopic recovery efficiency of heavy oils during common immiscible EOR processes such as water flooding. In this study, a series of injection experiments was performed on five-spot glass micromodel which is initially saturated with the heavy oil. Distilled water and dispersed silica nanoparticles in water (DSNW) at different values of weight percent... 

    Numerical simulation of surfactant flooding in darcy scale flow

    , Article Petroleum Science and Technology ; Vol. 32, Issue. 11 , 2014 , Pages 1365-1374 ; ISSN: 10916466 Morshedi, S ; Foroughi, S ; Beiranvand, M. S ; Sharif University of Technology
    Abstract
    One of the methods that is used nowadays in enhanced oil recovery is surfactant flooding. The main mechanisms of surfactant flooding in reservoir consist of reduction of interfacial tension between water and oil and modification of rock wettability. In this study, the authors simulate the surfactant injection process in Darcy scale and in one-dimensional, multicomponent, multiphase state, and effects of physical phenomena such as adsorption, dispersion, convection, and exchange between fluids and solids are considered. Wettability alteration of reservoir rock due to presence of surfactant in injected fluid is detected in relative permeability and capillary pressure curves. First, the authors... 

    Modification of rock/fluid and fluid/fluid interfaces during MEOR processes, using two biosurfactant producing strains of Bacillus stearothermophilus SUCPM#14 and Enterobacter cloacae: A mechanistic study

    , Article Colloids and Surfaces B: Biointerfaces ; Vol. 117 , May , 2014 , pp. 457-465 ; ISSN: 09277765 Sarafzadeh, P ; Zeinolabedini Hezave, A ; Mohammadi, S ; Niazi, A ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    During any microbial enhanced oil recovery process, both cells and the metabolic products of bacteria govern the tertiary oil recovery efficiency. However, very accurate examination is needed to find the functionality of these tiny creatures at different reservoir conditions. In this regard, the effect of cell structure on ultimate microbial recovery efficiency which is the most dominant mechanism based on the microorganism types (gram-negative or gram-positive) was systematically investigated. At the first stage, possible different active mechanisms using Bacillus stearothermophilus SUCPM#14 strain were tested using specially designed injection protocol, in situ and ex situ core flooding... 

    Investigation of wettability alteration through relative permeability measurement during MEOR process: A micromodel study

    , Article Journal of Petroleum Science and Engineering ; Vol. 120, issue , 2014 , p. 10-17 Khajepour, H ; Mahmoodi, M ; Biria, D ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    Microbial Enhanced Oil Recovery (MEOR) as a tertiary process employs microorganisms and their metabolites to reduce the residual oil saturation of the reservoir mainly through interfacial tension (IFT) reduction and wettability alteration. In spite of its great potential and the mentioned advantages, application of MEOR has been limited because of the lack of practical convincing experimental results. In this study, the effects of MEOR process on wettability changes and the reduction of residual oil saturation have been examined by providing microscopic visualization of two phase flow in transparent glass micromodels. Biosurfactant producing bacterial strain (Enterobacter cloacae) was... 

    The impact of surfactants on wettability change and level of water imbibition in relation to EOR in carbonate reservoirs

    , Article Petroleum Science and Technology ; Volume 31, Issue 20 , 2013 , Pages 2098-2109 ; 10916466 (ISSN) Zangeneh Var, A ; Bastani, D ; Badakhshan, A ; Sharif University of Technology
    2013

    Asphaltene precipitation due to natural depletion of reservoir: Determination using a SARA fraction based intelligent model

    , Article Fluid Phase Equilibria ; Volume 354 , September , 2013 , Pages 177-184 ; 03783812 (ISSN) Hemmati Sarapardeh, A ; Alipour Yeganeh Marand, R ; Naseri, A ; Safiabadi, A ; Gharagheizi, F ; Ilani Kashkouli, P ; Mohammadi, A. H ; Sharif University of Technology
    2013
    Abstract
    Precipitation of asphaltene leads to rigorous problems in petroleum industry such as: wettability alterations, relative permeability reduction, blockage of the flow with additional pressure drop in wellbore tubing, upstream process facilities and surface pipelines. Experimentally determination of the asphaltene precipitation is costly and time consuming. Therefore, searching for some other quick and accurate methods for determination of the asphaltene precipitation is inevitable. The objective of this communication is to present a reliable and predictive model namely, the least - squares support vector machine (LSSVM) to predict the asphaltene precipitation. This model has been developed and... 

    Application of biosurfactants to wettability alteration and IFT reduction in enhanced oil recovery from oil-wet carbonates

    , Article Petroleum Science and Technology ; Volume 31, Issue 12 , Jul , 2013 , Pages 1259-1267 ; 10916466 (ISSN) Biria, D ; Maghsoudi, E ; Roostaazad, R ; Sharif University of Technology
    2013
    Abstract
    To obtain potentially applicable microorganisms to an effective in situ microbial enhanced oil recovery operation, bacteria that were compatible with the harsh conditions of a petroleum reservoir were isolated from a crude oil sample. The application of an oil spreading technique showed that all of the isolates were capable of producing biosurfactants from both the glucose and crude oil as carbon sources. The secreted biosurfactants could at least reduce the surface tension 20 mN/m and for one of the isolates; the surface tension value dropped below 40 mN/m. In addition, the contact angle measurements revealed that the produced biosurfactants could effectively alter the wettability of the... 

    Nanotechnology-assisted EOR techniques: New solutions to old challenges

    , Article Society of Petroleum Engineers - SPE International Oilfield Nanotechnology Conference 2012 ; 2012 , Pages 382-396 ; 9781622761104 (ISBN) Ayatollahi, S ; Zerafat, M. M ; Sharif University of Technology
    SPE  2012
    Abstract
    Enhanced Oil Recovery techniques are gaining more attention worldwide as the proved oil reserves are declining and the oil price is hiking. Although many giant oil reservoirs in the world were already screened for EOR processes, the main challenges such as low sweep efficiency, costly techniques, possible formation damages, transportation of huge amounts of EOR agents to the fields especially for offshore cases, analyzing micro-scale multi-phase flow in the rock to the large scale tests and the lack of analyzing tools in traditional experimental works, hinder the proposed EOR processes. Our past experiences on using nanotechnology to the upstream cases, especially EOR processes, revealed... 

    Monitoring wettability alteration by silica nanoparticles during water flooding to heavy oils in five-spot systems: A pore-level investigation

    , Article Experimental Thermal and Fluid Science ; Volume 40 , July , 2012 , Pages 168-176 ; 08941777 (ISSN) Maghzi, A ; Mohammadi, S ; Ghazanfari, M. H ; Kharrat, R ; Masihi, M ; Sharif University of Technology
    2012
    Abstract
    It is well known that the displacement efficiency of EOR processes is mainly affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of pores surfaces remains a topic of debate in the literature. Furthermore, a little is known about how the dispersed silica nanoparticles affect the microscopic/macroscopic recovery efficiency of heavy oils during common immiscible EOR processes such as water flooding. In this study, a series of injection experiments was performed on five-spot glass micromodel which is initially saturated with the heavy oil. Distilled water and dispersed silica nanoparticles in water (DSNW) at different values of weight percent... 

    Optimization assisted asphaltene deposition modeling in porous media during a natural depletion scheme

    , Article Petroleum Science and Technology ; Volume 30, Issue 9 , Mar , 2012 , Pages 958-965 ; 10916466 (ISSN) Hematfar, V ; Bagheri, M ; Kharrat, R ; Ghazanfari, M ; Ghotbi, C ; Sharif University of Technology
    2012
    Abstract
    Changes in thermodynamic properties such as pressure, temperature, and composition may result in asphaltene precipitation and deposition in porous media. In addition, asphaltene deposition can cause wettability alteration, permeability reduction, and ultimately a decrease in the productivity of a reservoir. Natural depletion is one of the most common processes of asphaltene deposition in which pressure changes destabilize the dissolved asphaltene in the oil and settle them onto the rock surface. In this work, natural depletion experiments in consolidated core samples were performed under simulated reservoir conditions to obtain reliable data and analyze the asphaltene deposition mechanisms.... 

    Asphaltene deposition during CO 2 injection and pressure depletion: A visual study

    , Article Energy and Fuels ; Volume 26, Issue 2 , December , 2012 , Pages 1412-1419 ; 08870624 (ISSN) Zanganeh, P ; Ayatollahi, S ; Alamdari, A ; Zolghadr, A ; Dashti, H ; Kord, S ; Sharif University of Technology
    Abstract
    Carbon dioxide miscible flooding has become a popular method for Enhanced Oil Recovery (EOR) because it not only efficiently enhances oil recovery but also considerably reduces green house gas emissions. However, it can significantly cause asphaltene deposition, which leads to serious production problems such as wettability alteration, plugging of the reservoir formation, blocking the transportation pipelines, etc. It is crucial to investigate the effects of different factors on asphaltene deposition. A novel experimental setup was prepared to employ a high-pressure visual cell for investigation of asphaltene deposition on a model rock under typical reservoir conditions. The evolution of... 

    Pore-Scale Monitoring of Wettability Alteration by Silica Nanoparticles During Polymer Flooding to Heavy Oil in a Five-Spot Glass Micromodel

    , Article Transport in Porous Media ; Volume 87, Issue 3 , 2011 , Pages 653-664 ; 01693913 (ISSN) Maghzi, A ; Mohebbi, A ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    It is well known that the oil recovery is affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of medium surfaces has remained a topic of debate in the literature. Furthermore, there is a little information of the way dispersed silica nanoparticles affect the oil recovery efficiency during polymer flooding, especially, when heavy oil is used. In this study, a series of injection experiments were performed in a five-spot glass micromodel after saturation with the heavy oil. Polyacrylamide solution and dispersed silica nanoparticles in polyacrylamide (DSNP) solution were used as injected fluids. The oil recovery as well as fluid distribution in...