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    Mechanistic Investigation of Enhanced Oil Recovery by Engineered Water Using Computational Fluid Dynamics at Pore Scale

    , Ph.D. Dissertation Sharif University of Technology Namaee Ghasemi, Arman (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Despite the proven advantage of the engineered water flooding technique, a coherent and mechanistic understanding of the fundamental phenomena occurring at pore scale is lacking. Most of the available simulation models have a phenomenological approach and have limited predictive capability. One of the key questions is how to justify and relate large (Darcy) scale observations to effects and phenomena that essentially occur at much smaller scales (i.e. pore and molecular level). Furthermore, two-phase flow dynamics and the effect of complex interplay between wettability, capillary number, and ions dispersion in a heterogeneous porous medium on the trapping and mobilization of oil at pore... 

    Pore-scale Simulation of Trapping Phenomena and Hysteresis Effect in Porous Media

    , M.Sc. Thesis Sharif University of Technology Tabibnejad Azizi, Mehdi (Author) ; Fatemi, Mobeen (Supervisor)
    Abstract
    So far, many studies have been carried out on the core-scale regarding the effects of hysteresis on the macro-scale properties of systems including fluids and porous rock, however, many issues related to the physics of the problem (especially regarding the way fluids are distributed and the trapping of the non-wetting phase) at the pore-scale need further investigation. In the process of multiphase fluid flow in porous media, hysteresis refers to the dependence of the results of the fluids’ displacements on the history of fluid saturation and the direction of saturation changes (increasing or decreasing). The first step to investigate the hysteresis effect is to determine the amount of fluid... 

    Wettability Alteration and its Effect on Oil Recovery by using Colloidal Nano-Silica in Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Sadatshojaie, Ali (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Goodarznia, Iraj (Supervisor) ; Badakhshan, Amir (Co-Supervisor)
    Abstract
    As many oil fields are reaching their final stage of production, new technologies are required in order to maintain production and increase recovery of hydrocarbons. Among these techniques of enhanced oil recovery (EOR), chemical injection method focuses on increasing the effectiveness of waterflooding. Due to the relatively high costs and considerable adsorption on the rock formations, this method is no longer used. In Recent years nanofluids (nanoparticles dispersed in brine) have been used as a cheap, efficient and environmentally friendly alternative more than any other chemicals. It has been stated that the Smart Water method and enhanced oil recovery by SiO2 nanoparticles are effective... 

    Study of Industrial Wastewater as Low-Salinity Water for Enhanced Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Hossein (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Considering the water tensions, especially in the Middle East, water resources for the implementation of water-based EOR methods are shown to be critically limited. Water sources such as industrial wastewater hold great potential to be used for this purpose due to their significant available volume and the need for their disposal because of environmental regulations. In this research, the potential of injecting industrial wastewater, as low-salinity water, in an Iranian carbonated oil reservoir has been thoroughly investigated by conducting core-scale experiments. In this regard, we also developed a guideline for designing various types of experiments to use this "unconventional" injection... 

    Experimental Investigation of Heavy Oil Recovery by Natural Surfactant Injection in Heterogeneous Systems Using Micromodel Apparatus

    , M.Sc. Thesis Sharif University of Technology Aabloo, Milad (Author) ; Rashtchian, Davood (Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Advisor)
    Abstract
    Nowadays, due to limitation of production from conventional oil reservoirs, enhanced recovery from heavy oil reservoirs is of great concern. However, production from these energy resources is not a simple task and production using common technologies is not easily exploitable. Heterogeneous structure and also high surface tension between injected fluid and reservoir oil are of the main challenges during water flooding processes in heavy oil reservoirs. The high surface tension force causes a large part of the oil remains in the reservoir after the water flooding operation. One method for overcoming this problem is the use of surfactants that reduces capillary forces and consequently... 

    Experimental and Modeling Study of Controlled Salinity Water Injection for Enhanced Oil Recovery from one of Iranial Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Shojaei, Mohammad Javad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Masihi, Mohsen (Co-Advisor)
    Abstract
    From previous years, water injection was considered as one of the most common methods for enhanced oil recovery. But recently much attention has been paid on the use of low salinity water (LSW) as an enhanced oil recovery fluid. The main mechanism that causes improve oil recovery is wettability alteration to a more water wet state. The change observed in recovery factor during LSW flooding induced from changes in relative permeability and capillary pressure when different levels of salinity are used. However, a few researchers tried to evaluate how macroscopic flow functions depend on the salinity of injected water. To this end, a series oil displacements by water performed on sandstone rock... 

    Wettability alteration of reservoir rocks to gas wetting condition: a comparative study

    , Article Canadian Journal of Chemical Engineering ; Volume 96, Issue 4 , April , 2018 , Pages 997-1004 ; 00084034 (ISSN) Erfani Gahrooei, H. R ; Ghazanfari, M. H ; Karimi Malekabadi, F ; Sharif University of Technology
    Wiley-Liss Inc  2018
    Abstract
    Productivity of gas condensate reservoirs reduces significantly due to the near wellbore condensate/water blockage phenomenon. A novel, permanent solution to alleviate this problem is near wellbore wettability alteration of reservoir rocks to preferentially gas wetting conditions; industrial chemical materials are good candidates for this purpose, because of their eco-friendly characteristics, economical price, and mass production. In this paper, a comparative study is conducted on two industrial fluorinated chemicals, MariSeal 800 and SurfaPore M. Static and dynamic contact angle measurements, spontaneous imbibition, and core flooding tests were conducted to investigate the effect of... 

    Performance of sea water dilution on the surface free energies of the crude oils in water-flooded carbonate rock

    , Article Journal of Adhesion Science and Technology ; Volume 32, Issue 12 , 2018 , Pages 1359-1368 ; 01694243 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Taylor and Francis Ltd  2018
    Abstract
    Although several investigations have studied the low-salinity water injection (LSWI) performance during the past decades, the effect of crude oil type on the interfacial tension (IFT) and wettability alteration is still in dark. In this regard, this study is aimed to obtain the thermodynamic energies including adhesion, cohesion and spreading coefficient during LSWI. To achieve this goal, IFT and static contact angle values of three different crude oils (i.e. light, medium and heavy) are measured as a function of sea water salinity. The obtained results revealed that the dilution of sea water can change the wettability of reservoir rock from oil wet state towards water wet state, while crude... 

    The effect of nanoparticles on spontaneous imbibition of brine into initially oil-wet sandstones

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Volume 41, Issue 22 , 2019 , Pages 2746-2756 ; 15567036 (ISSN) Sobhani, A ; Ghasemi Dehkordi, M ; Sharif University of Technology
    Taylor and Francis Inc  2019
    Abstract
    In this paper, the effect of silica nanoparticles on oil production due to the spontaneous imbibition of brine into oil-wet sandstones has been studied. The imbibed fluids were NaCl 3 wt. % solutions containing various concentrations of nanoparticles and the recovered oil for each solution was compared. The results revealed that nanoparticles yielded more oil recovery. Nanofluid was used after brine imbibition, and the oil recovery increased from 17.8% to 40% while in the case of using the same nanofluid as the first imbibed fluid the oil recovery was 53%. Also, the results indicated that the oil recovery depends on nanoparticle concentrations. © 2019, © 2019 Taylor & Francis Group, LLC  

    The stability and surface activity of environmentally responsive surface-modified silica nanoparticles: the importance of hydrophobicity

    , Article Journal of Dispersion Science and Technology ; Volume 41, Issue 9 , 2020 , Pages 1299-1310 Ghaleh, V.R ; Mohammadi, A ; Sharif University of Technology
    Taylor and Francis Inc  2020
    Abstract
    In this study, the effect of hydrophobicity of environmentally responsive surface-modified silica nanoparticles on the stability and surface activity of the nanoparticles is examined. To this end, n-propyl, n-hexyl, or n-octyl chains and methoxy poly(ethylene glycol) chains at various quantities were coated covalently on the surface of silica nanoparticles to regulate the hydrophobicity of the responsive nanoparticles. Various experimental tools such as stability analysis, interfacial-tension and contact-angle measurements, and emulsion formation were performed to investigate the effect of hydrophobicity. It became evident that the presence of the hydrophobic agents influences considerably... 

    Effect of SO4 −2 ion exchanges and initial water saturation on low salinity water flooding (LSWF) in the dolomite reservoir rocks

    , Article Journal of Dispersion Science and Technology ; Volume 41, Issue 6 , 2020 , Pages 841-855 Safavi, M. S ; Masihi, M ; Safekordi, A. A ; Ayatollahi, S ; Sadeghnejad, S ; Sharif University of Technology
    Taylor and Francis Inc  2020
    Abstract
    The low salinity water injection has become one of the most important studies in the oil industry for improving oil recovery compared to conventional seawater injection. Thus, extensive studies have been conducted in carbonate and sandstone reservoirs to investigate how the physical properties of rocks and the chemical composition of fluids influence low salinity effect, while, the carbonate reservoir rocks requires more investigation of the effect of molecular and/or ionic interactions. In this experimental work, the effectiveness of various water flooding schemes in carbonate reservoir rock samples is investigated. In this regard, the oil recovery potential of seawater (SW), reservoir... 

    Investigation of rock and fluid interactions during engineered water flooding in dolomite reservoir rocks

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; 2020 Safavi, M. S ; Masihi, M ; Safekordi, A. A ; Ayatollahi, S ; Sadeghnejad, S ; Sharif University of Technology
    Taylor and Francis Inc  2020
    Abstract
    Engineered water (EW) flooding is one of the enhanced oil recovery (EOR) techniques in carbonate reservoirs. In this method, the wettability of reservoir rock is altered by controlling the amount of various ions in the injected brine. The thermodynamics of wettability is related to the surface interactions and stability of water film on a rock surface. It can be identified by calculating disjoining pressure isotherms. In this study, core flooding tests, contact angle and zeta potential measurements along with the disjoining pressure isotherm calculation by the DLVO theory were used to investigate the wettability alteration of dolomite rock. Four brines include reservoir formation water... 

    The impacts of silica nanoparticles coupled with low-salinity water on wettability and interfacial tension: Experiments on a carbonate core

    , Article Journal of Dispersion Science and Technology ; Volume 41, Issue 8 , 2020 , Pages 1159-1173 Sadatshojaei, E ; Jamialahmadi, M ; Esmaeilzadeh, F ; Wood, D. A ; Ghazanfari, M. H ; Sharif University of Technology
    Taylor and Francis Inc  2020
    Abstract
    Two main reservoir mechanisms that impact oil recovery factors are wettability alteration and interfacial tension (IFT) change. In this study, these two key mechanisms are evaluated experimentally for samples from the Asmari (carbonate) oil reservoir utilizing silica nanoparticles in the presence of low-salinity water. The nanofluid, rock formation and crude oil samples were prepared meticulously to ensure meaningful experimental could be conducted over a range of low-salinity conditions. The results show that across the range of salinities studied, the absolute value of zeta potential of nanofluids decreases with increasing total dissolved solids (TDS) in the water treated with silica... 

    Effects of low-salinity water coupled with silica nanoparticles on wettability alteration of dolomite at reservoir temperature

    , Article Petroleum Science and Technology ; Volume 34, Issue 15 , 2016 , Pages 1345-1351 ; 10916466 (ISSN) Sadatshojaei, E ; Jamialahmadi, M ; Esmaeilzadeh, F ; Ghazanfari, M. H ; Sharif University of Technology
    Taylor and Francis Inc 
    Abstract
    Wettability alteration in porous media is one of the mechanisms for enhancing oil recovery through injecting low-salinity water into carbonate reservoirs, in which active ions can remove the carboxylic oil component from the rock surface, altering the rock's wettability toward a water-wet condition. This study investigated the concomitant effects of low-salinity water and hydrophilic SiO2 nanoparticles on oil-wet dolomite rock. Results revealed that low-salinity water coupled with hydrophilic nano-SiO2 in oil-wet dolomite rock remarkably affected the wettability alteration of the rock, showing that the simultaneous presence of ions in water and hydrophilic nano-SiO2 led to considerable... 

    Effect of nanoclay on improved rheology properties of polyacrylamide solutions used in enhanced oil recovery

    , Article Journal of Petroleum Exploration and Production Technology ; Volume 5, Issue 2 , June , 2015 , Pages 189-196 ; 21900558 (ISSN) Cheraghian, G ; Khalili Nezhad, S. S ; Kamari, M ; Hemmati, M ; Masihi, M ; Bazgir, S ; Sharif University of Technology
    Springer Verlag  2015
    Abstract
    Recently, a renewed interest arises in the application of nanotechnology for the upstream petroleum industry. In particular, adding nanoparticles to fluids may drastically benefit enhanced oil recovery (EOR) and improve well drilling, by changing the properties of the fluid, rocks wettability alteration, advanced drag reduction, strengthening the sand consolidation, reducing the interfacial tension and increasing the mobility of the capillary trapped oil. In this study, we focus on roles of clay nano-particles on polymer viscosity. Polymer-flooding schemes for recovering residual oil have been in general less than satisfactory due to loss of chemical components by adsorption on reservoir... 

    Isolation and screening of Bacillus subtilis MJ01 for MEOR application: biosurfactant characterization, production optimization and wetting effect on carbonate surfaces

    , Article Journal of Petroleum Exploration and Production Technology ; Volume 9, Issue 1 , 2019 , Pages 233-245 ; 21900558 (ISSN) Jahanbani Veshareh, M ; Ganji Azad, E ; Deihimi, T ; Niazi, A ; Ayatollahi, S ; Sharif University of Technology
    Springer Verlag  2019
    Abstract
    The bacterial strain MJ01 was isolated from stock tank water of one of the Iranian south oil field production facilities. The 16S rRNA gene of isolate, MJ01, showed 99% similarity to Bacillus subtilis. The results revealed that biosurfactant produced by this strain was lipopeptide-like surfactin based on FTIR analysis. Critical micelle concentration of produced surfactin in distilled water was 0.06 g/l. Wettability study showed that at zero salinity surfactin can change original oil-wet state to water-wet state, but in seawater salinity it cannot modify the wettability significantly. To utilize this biosurfactant in ex situ MEOR process, economical and reservoir engineering technical... 

    Simulation of two-phase flow by injecting water and surfactant into porous media containing oil and investigation of trapped oil areas

    , Article Journal of Petroleum Exploration and Production ; Volume 11, Issue 3 , 2021 , Pages 1353-1362 ; 21900558 (ISSN) Sajadi, S. M ; Jamshidi, S ; Kamalipoor, M ; Sharif University of Technology
    Springer Science and Business Media B.V  2021
    Abstract
    Nowadays, as the oil reservoirs reaching their half-life, using enhanced oil recovery methods is more necessary and more common. Simulations are the synthetic process of real systems. In this study, simulation of water and surfactant injection into a porous media containing oil (two-phase) was performed using the computational fluid dynamics method on the image of a real micro-model. Also, the selected anionic surfactant is sodium dodecyl sulfate, which is more effective in sand reservoirs. The effect of using surfactant depends on its concentration. This dependence on concentration in using injection compounds is referred to as critical micelle concentration (CMC). In this study, an... 

    Environmentally responsive surface-modified silica nanoparticles for enhanced oil recovery

    , Article Journal of Nanoparticle Research ; Volume 18, Issue 9 , 2016 ; 13880764 (ISSN) Behzadi, A ; Mohammadi, A ; Sharif University of Technology
    Springer Netherlands 
    Abstract
    Environmentally responsive surface-modified nanoparticles are colloidal nanoparticles coated with, at least, two physicochemically distinct surface groups. Recent advances in the synthesis and production of nanoparticles have enabled the production of environmentally responsive surface-modified nanoparticles with both hydrophilic and hydrophobic surface groups. These nanoparticles act like colloidal surfactants. In this paper, environmentally responsive surface-modified silica nanoparticles are synthesized and used for enhancement of oil recovery. For this purpose, silica nanoparticles are coated with polyethylene glycol chains as hydrophilic agent and propyl chains as hydrophobic agent at... 

    Microorganisms’ effect on the wettability of carbonate oil-wet surfaces: implications for MEOR, smart water injection and reservoir souring mitigation strategies

    , Article Journal of Petroleum Exploration and Production Technology ; Volume 10, Issue 4 , 2020 , Pages 1539-1550 Jahanbani Veshareh, M ; Ayatollahi, S ; Sharif University of Technology
    Springer  2020
    Abstract
    In upstream oil industry, microorganisms arise some opportunities and challenges. They can increase oil recovery through microbial enhanced oil recovery (MEOR) mechanisms, or they can increase production costs and risks through reservoir souring process due to H2S gas production. MEOR is mostly known by bioproducts such as biosurfactant or processes such as bioclogging or biodegradation. On the other hand, when it comes to treatment of reservoir souring, the only objective is to inhibit reservoir souring. These perceptions are mainly because decision makers are not aware of the effect microorganisms’ cell can individually have on the wettability. In this work, we study the individual effect... 

    Nanotechnology-assisted EOR techniques: New solutions to old challenges

    , Article Society of Petroleum Engineers - SPE International Oilfield Nanotechnology Conference 2012 ; 2012 , Pages 382-396 ; 9781622761104 (ISBN) Ayatollahi, S ; Zerafat, M. M ; Sharif University of Technology
    SPE  2012
    Abstract
    Enhanced Oil Recovery techniques are gaining more attention worldwide as the proved oil reserves are declining and the oil price is hiking. Although many giant oil reservoirs in the world were already screened for EOR processes, the main challenges such as low sweep efficiency, costly techniques, possible formation damages, transportation of huge amounts of EOR agents to the fields especially for offshore cases, analyzing micro-scale multi-phase flow in the rock to the large scale tests and the lack of analyzing tools in traditional experimental works, hinder the proposed EOR processes. Our past experiences on using nanotechnology to the upstream cases, especially EOR processes, revealed...