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    Experimental and Modeling Investigation of Wettability Alteration to Gas Wetting Condition in Gas Condensate Reservoirs

    , M.Sc. Thesis Sharif University of Technology Erfani Gahrooei, Hamid Reza (Author) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    During production from gas condensate reservoirs, reservoir pressure decreses to lower than dew point pressure of the reservoir fluid. Consequently, condensates will form in near wellbore regions, which significantly decrease well productivity. One of the remediations that is recently proposed for solving this problem is wettability alteration of near wellbore region to gas wetting condition. In comparison to other methods, it provides a better permanency, which is its key advantage. The main purpose of this thesis is, quantitative, qualitative and modeling study of wettability alteration of rock to gas wetting condition and verification of modeling rsults for a reservoir rock sample. Also,... 

    Simulation of GAGD Process to Study the Impact of Effective Parameters on Operability Range and Recovery Factor

    , M.Sc. Thesis Sharif University of Technology Nasiri, Javad (Author) ; Pishvaie, Mahmoud Reza (Supervisor) ; Bozorgmehry, Ramin (Supervisor)
    Abstract
    Gravity drainage is the self-propulsion of oil downward in the reservoir rock. Under favorable natural and operational conditions, it has been found to effect recoveries comparable to water displacement. With modern technical knowledge, the operator can often make a choice between dissolved gas drive, water drive and gravity drainage as the principal recovery agent in a reservoir. So far, gravity drainage has received less consideration than the other two. Gravity drainage is one of the most important processes taking place in fractured reservoirs and it plays a major role in oil recovery from low permeability matrix blocks during gas injection process. Gravity drainage is responsible for... 

    Experimental Investigation of Mechanism of Wettability Alteration Induced By Hot Water and Steam Injection

    , M.Sc. Thesis Sharif University of Technology Salehi, Afshin (Author) ; Masihi, Mohsen (Supervisor)
    Abstract
    One of the most important production mechanisms of fractured reservoirs is wettability alteration. Since most fractured reservoirs are carbonate, and thus are often oil-wet; production of these reservoirs is facing their special challenges. Since most of our country reservoirs are fractured carbonate type, determination of the exact mechanisms of their production is necessary. Thermal EOR methods traditionally have been welcomed by big oil companies. Also, these methods of enhanced oil recovery techniques, have a much greater share in the production history of all EOR methods, rather than other EOR methods. Exponentially decreasing of oil viscosity on heating, is the main reason for using... 

    Coupling Flow and Geochemistry for Numerical Simulation of Low Salinity/Smart Waterflooding in Carbonates

    , M.Sc. Thesis Sharif University of Technology Alipour, Sina (Author) ; Ayatollahi, Shahab (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Due to the decrease in oil reserves in the world, increasing population and the growing demands for oil consumption in the world, increasing the oil recovery from oil reservoirs has become more important. Increasing the amount of oil production efficiency by using low salinity water/modified salinity water has been highly appreciated during the last two decades. Low-salt water is a new method, due to its advantages such as low cost, simplicity of operation and low environmental hazards. It is believed that low salinity water can alter the rock wettability from a more oil-wetting state to a more water-wetting state. In order to be able to predict the performance of low salinity water... 

    Pore-scale Modeling and Simulation of Low Salinity Waterflooding (LSWF) with OpenPNM

    , M.Sc. Thesis Sharif University of Technology Abdollahi, Saeed (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahabodin (Supervisor) ; Sadegh Nejad, Saeid (Co-Supervisor)
    Abstract
    The Low salinity water flooding is one of the important methods of secondary and tertiary oil production in which many expert petroleum-production engineering working on it in recent two decades. There are some basis mechanisms for low salinity method presented in the literatures including fine migrations, alkaline flooding, multicomponent ionic exchange, electrical double-layer expansion and pH-driven wettability alteration. The main approach is generating low salinity mechanism especially wettability alteration in OpenPNM framework. OpenPNM is a python base framework developed by Jeff Gostick for porous media modeling. OpenPNM has paved the way for extracting pore network models (PNM) from... 

    Investigation of Low Salinity Waterflooding Predictive Capability and the Development of a Tool for Screening Candidates

    , M.Sc. Thesis Sharif University of Technology Golmohammadi, Meysam (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahab (Supervisor)
    Abstract
    Among different enhanced oil recovery (EOR) methods, low salinity waterflooding (LSWF) has been attractive to researchers because of its relative simplicity and lower environmental problems compared to other conventional EOR methods. Numerous researchers have attempted to find the main cause of the low salinity effect (LSE). According to previous studies, several experimental techniques have been proposed for predicting LSE and screening potential field candidates. However, there is a lack of a systematic investigation of all (or even some of) the methods to compare and determine their LSE predictive capability. Predictive capability development is essential because it saves costs and time... 

    Low Salinity Water Assisted by Surfactants for Enhanced Oil Recovery: Mechanistic Study and Spontaneous Imbibition Tests

    , M.Sc. Thesis Sharif University of Technology Heidari, Mehdi (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Enhanced Oil Recovery (EOR) techniques have become of the main priorities of the oil industry during the high oil price era. It is interesting to note that the common method to increase production from reservoirs is the water injection method, which recovers a very low amount of oil from the oil-wet matrices due to the lack of water imbibition. Previous studies have shown that changing the wettability of rock would critically increase the oil recovery efficiency. This could be achieved by the low-salinity water injection method. In recent years, extensive studies have been conducted on this technique to evaluate its effectiveness for various types of oil reservoirs. Simultaneous injection... 

    Micromodel Investigation of the Non-Monotonic Effect of Injection Water Salinity on Wettability and Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Karimpour Khamaneh, Mehran (Author) ; Mahani, Hassan (Supervisor)
    Abstract
    Based on numerous laboratory and field evidence, low-salinity waterflooding or engineered salinity waterflooding can lead to enhanced oil production. According to the literature, the mechanisms involved in this process can be divided into two general categories: fluid-fluid interactions and solid-liquid interactions. These mechanisms are caused by intermolecular and electrostatic forces at the rock and fluid interfaces. The most important controlling factor of the electrostatic forces is the concentration of ions at/near fluids-rock interface. Therefore, improving the concentration of ions causes a shift in wettability toward a more water-wetting state, eventually leading to increased oil... 

    Numerical simulation of surfactant flooding in darcy scale flow

    , Article Petroleum Science and Technology ; Vol. 32, Issue. 11 , 2014 , Pages 1365-1374 ; ISSN: 10916466 Morshedi, S ; Foroughi, S ; Beiranvand, M. S ; Sharif University of Technology
    Abstract
    One of the methods that is used nowadays in enhanced oil recovery is surfactant flooding. The main mechanisms of surfactant flooding in reservoir consist of reduction of interfacial tension between water and oil and modification of rock wettability. In this study, the authors simulate the surfactant injection process in Darcy scale and in one-dimensional, multicomponent, multiphase state, and effects of physical phenomena such as adsorption, dispersion, convection, and exchange between fluids and solids are considered. Wettability alteration of reservoir rock due to presence of surfactant in injected fluid is detected in relative permeability and capillary pressure curves. First, the authors... 

    Asphaltene precipitation due to natural depletion of reservoir: Determination using a SARA fraction based intelligent model

    , Article Fluid Phase Equilibria ; Volume 354 , September , 2013 , Pages 177-184 ; 03783812 (ISSN) Hemmati Sarapardeh, A ; Alipour Yeganeh Marand, R ; Naseri, A ; Safiabadi, A ; Gharagheizi, F ; Ilani Kashkouli, P ; Mohammadi, A. H ; Sharif University of Technology
    2013
    Abstract
    Precipitation of asphaltene leads to rigorous problems in petroleum industry such as: wettability alterations, relative permeability reduction, blockage of the flow with additional pressure drop in wellbore tubing, upstream process facilities and surface pipelines. Experimentally determination of the asphaltene precipitation is costly and time consuming. Therefore, searching for some other quick and accurate methods for determination of the asphaltene precipitation is inevitable. The objective of this communication is to present a reliable and predictive model namely, the least - squares support vector machine (LSSVM) to predict the asphaltene precipitation. This model has been developed and... 

    Low salinity water injectionat different reservoir rocks: Similarities and differences

    , Article Special Topics and Reviews in Porous Media ; Volume 7, Issue 1 , 2016 , Pages 87-97 ; 21514798 (ISSN) Hassani, K ; Rostami, B ; Ayatollahi, S ; Yassin, M. R ; Sharif University of Technology
    Begell House Inc  2016
    Abstract
    A literature review of laboratory and field scale studies on low salinity water (LSW) injection showed that the salinity and composition of injected water can have a significant impact on oil recovery. Historically, extensive research has been completed to understand the mechanisms and factors affecting LSW injection. However, although numerous mechanisms have been proposed to describe the interactions in the target process, none have been widely accepted. In this study, waterflooding tests were used to investigate the advantages, disadvantages, and effect of LSW injection. In laboratory tests, two different brines and crude oil of one of Iran's southern reservoirs were used to assess the... 

    Effects of low-salinity water coupled with silica nanoparticles on wettability alteration of dolomite at reservoir temperature

    , Article Petroleum Science and Technology ; Volume 34, Issue 15 , 2016 , Pages 1345-1351 ; 10916466 (ISSN) Sadatshojaei, E ; Jamialahmadi, M ; Esmaeilzadeh, F ; Ghazanfari, M. H ; Sharif University of Technology
    Taylor and Francis Inc 
    Abstract
    Wettability alteration in porous media is one of the mechanisms for enhancing oil recovery through injecting low-salinity water into carbonate reservoirs, in which active ions can remove the carboxylic oil component from the rock surface, altering the rock's wettability toward a water-wet condition. This study investigated the concomitant effects of low-salinity water and hydrophilic SiO2 nanoparticles on oil-wet dolomite rock. Results revealed that low-salinity water coupled with hydrophilic nano-SiO2 in oil-wet dolomite rock remarkably affected the wettability alteration of the rock, showing that the simultaneous presence of ions in water and hydrophilic nano-SiO2 led to considerable... 

    Low salinity injection into asphaltenic-carbonate oil reservoir, mechanistical study

    , Article Journal of Molecular Liquids ; Volume 216 , 2016 , Pages 377-386 ; 01677322 (ISSN) Lashkarbolooki, M ; Riazi, M ; Hajibagheri, F ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    The impacts of salinity adjustment of displacing fluid have recently gained special attention to enhanced oil recovery (EOR). Different mechanisms have been studied widely in the literature while some of them are still subjugated to more scrutiny. The effects of diluted sea water on the interfacial properties of brine and asphaltenic-acidic crude oil and the wettability alteration of carbonate reservoir rock are investigated in this experimental observational work. The measurements of interfacial tension (IFT) and contact angle (CA) as two main parameters are studied. Besides, the effects of asphaltene and resin in the crude oil on the IFT values between the crude oil and aqueous solution... 

    Experimental investigation of inorganic scale deposition during smart water injection - A formation damage point of view

    , Article IOR NORWAY 2017 - 19th European Symposium on Improved Oil Recovery: Sustainable IOR in a Low Oil Price World, 24 April 2017 through 27 April 2017 ; 2017 ; 9789462822092 (ISBN) Ghasemian, J ; Mokhtari, R ; Ayatollahi, S ; Riahi, S ; Malekzade, E ; Sharif University of Technology
    Abstract
    Smart water injection is determined as an effective EOR process to change the wettability and interfacial tension for better micro/macro sweep efficiencies. This water contains reactive ions such as Mg ∧(2+), Ca ∧(2+) and SO-4 ∧(2-) which can act as potential determining ions and change the surface charge of calcite rocks. One of the major concerns in the execution of an effective waterflood, especially in tight carbonate reservoirs, is the incompatibility between the formation brine and the injecting water. This research work aims to investigate the most important challenge of waterflooding process related to the possible formation damage because of inorganic scale deposition during... 

    Investigating the synergic effects of chemical surfactant (SDBS) and biosurfactant produced by bacterium (Enterobacter cloacae) on IFT reduction and wettability alteration during MEOR process

    , Article Journal of Molecular Liquids ; Volume 256 , 2018 , Pages 277-285 ; 01677322 (ISSN) Hajibagheri, F ; Hashemi, A ; Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    In the current study, a novel approach which takes into account the effectiveness of both convectional surfactants and biosurfactants was investigated. The biosurfactant produced by Enterobacter cloacae strain was utilized concomitant with conventional surfactant (sodium dodecyl benzene sulfonate (SDBS)) to evaluate its capability to reduce the SDBS adsorption on rock surface (biosurfactant acts as sacrificial agent) or synergistically enhance the effectiveness of the SDBS. In this regard, the wettability alteration and interfacial tension (IFT) measurements and calculation of spreading coefficient were performed considering two different scenarios. In the first scenario, SDBS was added to... 

    The effect of nanoparticles on spontaneous imbibition of brine into initially oil-wet sandstones

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Volume 41, Issue 22 , 2019 , Pages 2746-2756 ; 15567036 (ISSN) Sobhani, A ; Ghasemi Dehkordi, M ; Sharif University of Technology
    Taylor and Francis Inc  2019
    Abstract
    In this paper, the effect of silica nanoparticles on oil production due to the spontaneous imbibition of brine into oil-wet sandstones has been studied. The imbibed fluids were NaCl 3 wt. % solutions containing various concentrations of nanoparticles and the recovered oil for each solution was compared. The results revealed that nanoparticles yielded more oil recovery. Nanofluid was used after brine imbibition, and the oil recovery increased from 17.8% to 40% while in the case of using the same nanofluid as the first imbibed fluid the oil recovery was 53%. Also, the results indicated that the oil recovery depends on nanoparticle concentrations. © 2019, © 2019 Taylor & Francis Group, LLC  

    An atomistic insight into the implications of ion-tuned water injection in wetting preferences of carbonate reservoirs

    , Article Journal of Molecular Liquids ; Volume 293 , 2019 ; 01677322 (ISSN) Koleini, M.M ; Badizad, M. H ; Ghatee, M. H ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    The efficiency of water flooding methods is known to improve by applying ion-tuned water injection. Although there is a consensus that such improvement happens through reversing reservoir wettability characteristics to more water-wet state, the true impact of ions is still ambiguous among contradictory debates. The well-known molecular dynamics (MD) simulation techniques would shed light on such ambiguities to gain deep atomic-scale understanding of the process. Results from MD simulations show that the presence of Na+ and Cl¯ ions leads to the formation of an electrical double layer in adjacency of calcite surface while Mg2+ ions dominantly make complexes with hydrocarbons throughout the... 

    Wettability alteration of oil-wet carbonate porous media using silica nanoparticles: Electrokinetic characterization

    , Article Industrial and Engineering Chemistry Research ; Volume 58, Issue 40 , 2019 , Pages 18601-18612 ; 08885885 (ISSN) Dehghan Monfared, A ; Ghazanfari, M. H ; Sharif University of Technology
    American Chemical Society  2019
    Abstract
    Application of nanoparticles for wettability alteration offers a practical approach to resolve some surface-related problems encountered in the nowadays technological process. Examples are underground/subsurface engineering implications, including the enhanced oil recovery from the oil-wet carbonate reservoirs. However, the common wettability evaluating techniques such as contact angle and flotation cannot be representative of the dynamic phenomena occurring at the pore scale and hence are unable to give accurate information about the process. Therefore, in the present work, the electrokinetic evaluations are utilized to explore the wettability alteration of initially oil-wet carbonate rock... 

    The stability and surface activity of environmentally responsive surface-modified silica nanoparticles: the importance of hydrophobicity

    , Article Journal of Dispersion Science and Technology ; Volume 41, Issue 9 , 2020 , Pages 1299-1310 Ghaleh, V.R ; Mohammadi, A ; Sharif University of Technology
    Taylor and Francis Inc  2020
    Abstract
    In this study, the effect of hydrophobicity of environmentally responsive surface-modified silica nanoparticles on the stability and surface activity of the nanoparticles is examined. To this end, n-propyl, n-hexyl, or n-octyl chains and methoxy poly(ethylene glycol) chains at various quantities were coated covalently on the surface of silica nanoparticles to regulate the hydrophobicity of the responsive nanoparticles. Various experimental tools such as stability analysis, interfacial-tension and contact-angle measurements, and emulsion formation were performed to investigate the effect of hydrophobicity. It became evident that the presence of the hydrophobic agents influences considerably... 

    Theoretical and experimental study of foam stability mechanism by nanoparticles: Interfacial, bulk, and porous media behavior

    , Article Journal of Molecular Liquids ; Volume 304 , 2020 Suleymani, M ; Ghotbi, C ; Ashoori, S ; Moghadasi, J ; Kharrat, R ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Foam flooding has been applied as a promising method in enhanced oil recovery to obviate the challenges of gas flooding such as fingering, channeling and overriding. However, long-term foam stability is crucial for mobility control. In this work, the effective mechanisms on foam stability in the presence of CaCO3 nanoparticles were assessed both theoretically and experimentally. The static and dynamic behaviors of cationic surfactant (HTAB) foam in the presence of CaCO3 nanoparticles with different hydrophobicity were evaluated. The CaCO3 nanoparticles were treated with a series of long-chain fatty acids to generate a range of wettability. Afterward, the underlying mechanisms were revealed...