Sharif Digital Repository

This work describes a novel Fe3O4@SiO2@polypyrrole magnetic nanocomposite and its application in the preconcentration of Cd(ii) and Ni(ii) ions. The parameters affecting the preconcentration procedure were optimised by a Box-Behnken design using response surface methodology. Three variables (extraction time, magnetic sorbent amount, and pH) were selected as the main factors affecting the sorption step, while four variables (type, volume and concentration of the eluent, and elution time) were selected as the main factors in the optimisation study of the elution step. Following the sorption and elution of analytes, the ions were quantified by FAAS. The limits of detection were 0.3 and 1.2 ng... 

A magnetic polyurethane (PU) nanocomposite was synthesized by an electrospinning technique and applied for isolation and preconcentration of fluoxetine from aquatic and biological samples. The nanocomposite was electrospun using a PU polymer solution containing the dispersed magnetic nanoparticles. The magnetic properties of iron nanoparticles, along with the use of an electrospinning technique, led to the formation of a suitable sorbent toward isolation of fluoxetine. The magnetic PU nanofibers could be subsequently removed from the sample solution by applying a permanent magnet. The scanning electron microscopy (SEM) image of the magnetic PU nanofibers confirms that their diameters are in... 

In recent years, there has been an increasing interest in the analysis of the major active components of saffron owing to their significant role in various industries, such as food, medicine and perfume. In other words, analysis of the major active components of saffron can give complete information about its chemical composition, which can be used as a reliable index for the quality control of different saffron samples (i.e., natural and commercial). The aim of the present work was to develop a simple, low cost, efficient and comprehensive strategy for the extraction and analysis of the bioactive components of saffron. In this regard, ultrasonic-assisted solvent extraction (UASE) combined... 

Fluopyram, flupyradifurone, and indaziflam are novel systemic pesticides developed by Bayer. Based on available data, these pesticides appears to have a favorable safety profile in the case of pesticide residue problems. Herein, we report an effective analytical method for the determination of novel pesticides were developed using ultra-high performance liquid chromatography with tandem mass spectrometry coupled with a quick, easy, cheap, effective, rugged, and safe procedure. These target compounds were extracted with acetonitrile and cleaned up with PSA, and were separated successfully between 10.2 and 18.3 min using a C18 chromatographic column connected to an electrospray ionization... 

Polystyrene is one of the best candidates as the extracting medium due to its high stability in different media and acceptable extraction capability. However, the hydrophobic nature and low wettability of polystyrene limits its application to non–polar analytes. To resolve this limitation, in this project, amine groups were chemically attached to the surface of magnetic polystyrene. The resulting hydrophilic magnetic particles were expected to be capable of extracting both polar and non–polar analytes. Non–steroidal anti–inflammatory drugs (NSAIDs) were chosen for testing the applicability of modified magnetic polystyrene according to the importance of their analysis and also their wide... 

A metal organic framework-polyaniline (MOF/PANI) nanocomposite was electrodeposited on a stainless steel wire and used as a solid phase microextraction (SPME) fiber coating. The electropolymerization process was carried out under a constant deposition potential and applied to the corresponding aqueous electrolyte containing aniline and MOF particles. The employment of MOFs with their large and small cages and 3-D structures in synthesizing a nanocomposite was assumed to be efficient constitutes to induce more non-smooth and porous structures, approved by scanning electron microscopy (SEM) images. Three different MOFs were incorporated to synthesize the desired nanocomposites and the... 

A horizontally oriented liquid-liquid-liquid microextraction (HOLLLME) setup was developed and applied for the isolation of two major estrogens from aquatic media. In contrast to the conventional procedure, in this setup the extracting microdrop was suspended from a horizontally positioned needle in order to provide much higher stability to the extracting phase. The developed HOLLLME approach was applied to isolate two major selected estrogens from aquatic media followed by high performance liquid chromatography-ultraviolet (HPLC-UV) determination. Estrogens were, initially, extracted from water samples into hexane and subsequently, the back extraction stage was performed with 6 μL of sodium... 

A high-temperature-resisant solid-phase microextraction (SPME) fiber was prepared based on polyetherimide (PEI) by the electrospinning method. The PEI polymeric solution was converted to nanofibers using high voltages and directly coated on a stainless steel SPME needle. The scanning electron microscopy images of PEI coating showed fibers with diameter range of 500-650 nm with a homogeneous and smooth surface morphology. The SPME nanofibers coating was optimized for PEI percentage, electrospinning voltage, and time. The extraction efficiency of the coating was investigated for headspace SPME of some environmentally important polycyclic aromatic hydrocarbons from aqueous samples followed by... 

In this study, a fast and sensitive flow injection μ-solid phase extraction (FI-μ-SPE) technique based on an electrospun polyaniline (PANI) nanocomposite in conjunction with gas chromatography-mass spectrometry (GC-MS) was developed. The PANI-based nanocomposite was synthesized by electrospinning of a solution containing polyvinyl alcohol (PVA)/PANI. The majority of PVA template was subsequently removed from the whole PVA/PANI nanofibers blend by exposing the electrospun nanocomposite to hot water. The homogeneity, porosity and characterization of the electrospun nanofibers were investigated by the scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. Due to... 

In this study, a fast and sensitive flow injection μ-solid phase extraction (FI-μ-SPE) technique based on an electrospun polyaniline (PANI) nanocomposite in conjunction with gas chromatography-mass spectrometry (GC-MS) was developed. The PANI-based nanocomposite was synthesized by electrospinning of a solution containing polyvinyl alcohol (PVA)/PANI. The majority of PVA template was subsequently removed from the whole PVA/PANI nanofibers blend by exposing the electrospun nanocomposite to hot water. The homogeneity, porosity and characterization of the electrospun nanofibers were investigated by the scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. Due to... 

We synthesized a titanium dioxide–polyaniline core–shell nanocomposite and implemented it as an efficient sorbent for the needle-trap extraction of some volatile organic compounds from urine samples. Polyaniline was synthesized, in the form of the emeraldine base, dissolved in dimethyl acetamide followed by diluting with water at pH 2.8, using the interfacial polymerization method. The TiO2 nanoparticles were encapsulated inside the conducting polymer shell, by adapting the in situ dispersing approach. The surface characteristics of the nanocomposite were investigated by Fourier transform infrared spectrometry, scanning electron microscopy, and transmission electron microscopy. After... 

A new and convenient format of single drop microextraction (SDME) was developed and applied for isolation of some selected aryloxyphenoxypropionate herbicides from aquatic media. In contrast to the conventional SDME procedure, in this set-up the extraction microdrop was positioned at the bottom of a conical vial in order to provide much higher stability for the organic extraction phase while a magnetic bar was used for stirring the aqueous solution. A simple magnet was used for positioning the bar on the top of the microdrop prior to stirring. The whole set-up led to the use of any volume of extraction solvent with unlimited stirring rates. Some important extraction parameters such as the...