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    Ethylenediamine-functionalized Zr-based MOF for efficient removal of heavy metal ions from water

    , Article Chemosphere ; Volume 264 , 2021 ; 00456535 (ISSN) Ahmadijokani, F ; Tajahmadi, S ; Bahi, A ; Molavi, H ; Rezakazemi, M ; Ko, F ; Aminabhavi, T. M ; Arjmand, M ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Ethylenediamine-functionalized Zr-based metal-organic framework (MOF, UiO-66-EDA) was prepared via Michael addition reaction to investigate its potential for adsorption of heavy metal ions from water. Specifically, the influence of agitation time, solution pH, the dosage of the adsorbent, initial metal ion concentration, temperature, and coexistence of other metal ions was investigated on the removal efficiency of UiO-66-EDA towards Pb(II), Cd(II), and Cu(II) metal ions. The pseudo-second-order kinetic model governed the adsorption of these ions onto the UiO-66-EDA. Langmuir isotherm model matched the experimental isotherm of adsorption with a maximum adsorption capacity of 243.90, 217.39,...