Sharif Digital Repository

Hybrid nanostructures combining semiconductor quantum dots and graphene are attracting increasing attention because of their optoelectronic properties promising for photovoltaic applications. We present a hot-injection synthesis of a colloidal nanostructure which we define as quasi core/shell PbS/graphene quantum dots due to the incomplete passivation of PbS surfaces with an ultrathin layer of graphene. Simulation by density functional theory of a prototypical model of a nonstoichiometric Pb-rich core (400 atoms) coated by graphene (20 atoms for each graphene sheet) indicates the possibility of surface passivation of (111) planes of PbS with graphene resulting in a decrease in trap states... 

Exploiting of the nanostructure arrays as a promising candidate for excitation of neural cells has been analyzed. Based on the importance of the coupling effect between electrode and neuron, a multiphyscis modeling approach has been proposed. The model incorporates theoretically both structural effects (size, geometry) and electrophysiological effects. The system of equations for proposed model has been solved numerically using Finite Element Method for Poisson equation and Finite Difference Method for Cable equation. In this regards we have combined the system of equations in COMSOL platform with Matlab interface accordingly. We have analyzed the effect of excitation of neuron with an extra... 

Silver nanostructures are very important agents in biomedical research, because of its unique activity against unfavorable processes in bioscience. In the current study, reagent-free facile preparation of silver nanoparticles (average diameter: 72 nm) and silver nanoparticles/ nanorods hybrid was reported via wet chemical synthesis method. Kappa-carrageenan (kC), a hydrophilic biopolymer with sulphate groups on its backbone, as capping agent was used in the reaction medium. Silver nanoparticles and silver nanoparticles/ nanorods formation was confirmed by SEM images. Further investigations were carried out using DLS data and GPC analysis  

A novel SPD process for manufacturing of high strength tubes and cylinders by accumulative spin-bonding (ASB) is proposed. It is demonstrated that due to incremental deformation in this process, high strain rate without considerable temperature rise is achieved. This is accompanied with a high value of Zener-Hollomon parameter as a characteristic of this SPD process. ASB was applied to a commercially pure aluminum up to four cycles and its effects on the microstructure and mechanical properties were examined by optical microscopy, TEM, EBSD, microhardness and tension tests. The results show that ultra-fine grains are developed during the process by formation of subgrains at early stages... 

The electronic transmission and conductance of a gapped graphene superlattice were calculated by means of the transfer-matrix method. The system that we study consists of a sequence of electron-doped graphene as wells and hole-doped graphene as barriers. We show that the transmission probability approaches unity at some critical value of the gap. We also find that there is a domain around the critical gap value for which the conductance of the system attains its maximum value  

Modified versions of the Zener drag equation were obtained by evaluating a non-random distribution of incoherent ceramic particles in a nano-crystalline material. Analytical investigation of particle-boundary correlation indicates that the limiting grain size would be proportional to fV -1/3 for fV larger than 2.96%. The limiting grain size can be obtained by a combination of random and non-random Zener drag pressure in the case of volume fractions smaller than 2.96%  

Nanostructured molybdenum oxide having a particle size in the range of 30-80 nm was prepared by potentiodynamic electrodeposition method, and the effects of H2SO4 concentration on its capacitive behavior were studied by cyclic voltammetry, galvanostatic discharge, and electrochemical impedance spectroscopy. Poor to fair capacitive behaviors were witnessed depending on the electrolyte concentration and conditions of charge/discharge. Increasing acid concentration to 0.02 M had favorable effect, while beyond that, the effect was detrimental. Capacitance around 600 F g-1 was recorded in the potential range of 0 to -0.55 V vs. Ag/AgCl  

Visible light-active BiOCl/BiVO4/mordenite and Ag/BiOCl/BiVO4 nanocomposite with a p–n heterojunction structure were prepared. Mordenite nanocrystals were synthesised using the hydrothermal method. Deposition and reduction methods were utilised to modify the Zeolite surface. The photocatalytic activities of the heterojunctions were investigated by scanning the change of Acid blue 92 (AB92) concentration under visible irradiation. The nanocomposites demonstrated improved efficiency for dye photodegradation. The activities are due to strong oxidative ability and efficient charge separation and transfer through the BiOCl/BiVO4 p–n junction. The photogenerated electron-holes react with species... 

Graphene oxide (GO) sheets with a low concentration (∼1 wt%) were deposited on surface of hydrothermally synthesized ZnO nanorod films. The deposited films were heat treated at 450 °C in order to achieve suitable GO/ZnO hybrid thin films for photocatalytic purposes. The photocatalytic activity of the nanocomposite films was investigated based on degradation of methylene blue (MB) dye which is a typical pollutant model. The GO/ZnO hybrid thin films could degrade higher MB (∼90%) than the bare ZnO nanorods (which showed only ∼75% degradation) after 450 min UV irradiation. A further significant improvement (resulting in a nearly complete degradation of MB) was achieved by exposing the GO/ZnO... 

Continuum-based modeling of nanostructures is an efficient and suitable method to study the behavior of these structures when the deformation can be considered homogeneous. This paper is concerned about multiscale nonlinear tensorial constitutive modeling of carbon nanostructures based on the interatomic potentials. The proposed constitutive model is a tensorial equation relating the second Piola-Kirchhoff stress tensor to Green-Lagrange strain tensor. For carbon nanotubes, some modifications are made on the planar representative volume element (RVE) to account for the curved atomic structure resulting a non-planar RVE. Using the proposed constitutive model, the elastic behavior of the... 

Porous network-like MnO2 thick films are successfully synthesized on a flexible stainless steel (SS) mesh using a simple and low-cost electrodeposition method followed by an electrochemical activation process. Morphology, chemical composition, and crystal structure of the prepared electrodes before and after the activation process are determined and compared by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) analyses. The results show that the implementation of the electrochemical activation process does not change the chemical composition and crystal structure of the films, but it influences the surface morphology of the MnO2... 

Visible light-active BiOCl/BiVO4/mordenite and Ag/BiOCl/BiVO4 nanocomposite with a p–n heterojunction structure were prepared. Mordenite nanocrystals were synthesised using the hydrothermal method. Deposition and reduction methods were utilised to modify the Zeolite surface. The photocatalytic activities of the heterojunctions were investigated by scanning the change of Acid blue 92 (AB92) concentration under visible irradiation. The nanocomposites demonstrated improved efficiency for dye photodegradation. The activities are due to strong oxidative ability and efficient charge separation and transfer through the BiOCl/BiVO4 p–n junction. The photogenerated electron-holes react with species... 

This article investigates the influence of porosity on free and forced vibration characteristics of a nanoshell reinforced by graphene platelets (GPL). The material properties of piece-wise graphene-reinforced composites (GPLRCs) are assumed to be graded in the thickness direction of a cylindrical nanoshell and estimated using a nanomechanical model. In addition, because of imperfection of the current structure, three kinds of porosity distributions are considered. The nanostructure is modeled using modified strain gradient theory (MSGT) which is a size-dependent theory with three length scale parameters. The novelty of the current study is to consider the effects of porosity, GPLRC and MSGT... 

The use of superhydrophobic surfaces is one the most promising methods for reducing the friction and increasing the flow rate in fluid transfer systems. Because in such systems the surface structure plays a key role, in this study, we explore the performance of the hierarchical nanostructures. These nanostructures are inspired by the superhydrophobic surface of the lotus leaf. We consider a flow between two walls with hierarchical nanostructures and simulate the system via the molecular dynamics method. The size of the nanostructures and the distance between them have been studied to find whether a design with a maximum flow rate exists. The nanostructures have two parts, a bigger part on... 

The use of superhydrophobic surfaces is one the most promising methods for reducing the friction and increasing the flow rate in fluid transfer systems. Because in such systems the surface structure plays a key role, in this study, we explore the performance of the hierarchical nanostructures. These nanostructures are inspired by the superhydrophobic surface of the lotus leaf. We consider a flow between two walls with hierarchical nanostructures and simulate the system via the molecular dynamics method. The size of the nanostructures and the distance between them have been studied to find whether a design with a maximum flow rate exists. The nanostructures have two parts, a bigger part on... 

For the rapid detection of hyperglycemia in human blood, we adopted a facile and two-step electrochemical procedure to prepare nickel/reduced graphene oxide (rGO) hybrid electrodes in the framework of a three-dimensional (3D) nanostructure. High-density and vertically-aligned nickel submicrorods with an average diameter of 155 ± 15 nm and a length of 7 ± 1 μm (an aspect ratio of about 40-50) were prepared by template-mediated electrochemical deposition techniques. Networks of rGO nanosheets between the rod-shaped arrays were formed by the cathodic electrophoretic deposition method. The synergistic effect of nickel morphology (planar and high-density rod-shaped arrays) and graphene oxide... 

Gold nanoparticles are potentially very attractive components for therapeutic delivery since they can be synthesized with any diameter from 1 to 200 nm to carry a payload of therapeutic molecules into a cell without triggering an immune response. Gold nanoparticles must undergo surface transformations before coupling to therapeutic molecules to become eligible for this purpose. It is now more understood that amine groups can bind to gold nanoparticles strongly, which has enabled surface modification of gold nanoparticles with amino acid lysine through its amine group. These lysine capped gold nanoparticles can further be coupled to therapeutic molecules for delivery purposes. In this study... 

The aim of this research is to conduct atomistic investigations of physical interaction analysis of nanoscale objects manipulation. The system consists of tip, particle and substrate. The manipulation tool moves with a constant speed while pushing the particle in a desired direction. The focus of the research is on ultra-fine metallic nanoparticles. To perform this research, Nose-Hoover dynamics and Sutton-Chen interatomic potential will be used to investigate the behavior of the aforementioned system which is made from different transition metals. The effects of size, material type and temperature on the success of the process have been investigated by planar molecular dynamics. © 2008 IEEE... 

Rosette-like boehmite nanostructures were prepared successfully via a simple hydrothermal process. The obtained material was characterized with X-ray powder diffractometry (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Using Scherrer formula, the average crystallite size of the obtained boehmite rosettes was measured to be about 8 nm. It was shown that boehmite nanopetals with average width of about 41 nm determined by TEM, were formed during the hydrothermal process and then self assembled due to weak hydrogen bonds to fabricate boehmite rosettes. The specific surface area of the obtained rosette-like nanostructures was calculated through BET... 

In this paper the electrodeposition of nickel on n-Si(111):H substrate, in the presence of sulphuric acid, was studied. Cyclic voltammetry has been used to characterize the electrochemical behavior of the system. The nickel deposits had a flower-like morphology with the spherical nanostructure nucleus, distributed uniformly on the surfaces of the prepared n-Si(111) substrate