Sharif Digital Repository

The effect of one of the surfactants such as Tiron, a compound based on the benzene molecule, on the morphology and chemical composition of zinc oxide deposits, produced from a zinc complex solution using two-stage chemical deposition (TSCD) technique, has been investigated. TSCD technique is a novel and simple chemical route for the deposition of ZnO film from aqueous solution. Zinc oxide films deposited on high purity alumina (HPA) as a substrate. The results show that the addition of Tiron changes the surface morphology and causes to form the fine-grained structure. With a dense and nodular-shape appearance, the film produced from the precursor of zinc complex-containing Tiron, is... 

This study aims at investigating the effect of the substrate material on growth mechanism and also microstructure of Ta2O5 thin films. For this purpose, atomic force microscopy, scanning electron microscopy, and interferometry analyses were implemented to reveal the influence of silicon wafer and amorphous BK7 glass substrates on the nucleation and growth mechanisms of Ta2O5 thin films deposited via the radio frequency magnetron sputtering technique. Results indicated that those films with finer morphologies had relatively higher nucleation densities. Compared with BK7 glass substrate, crystals formed on the silicon wafer were shown to be finer and had lower mean areas in more nucleation... 

The purpose of this study is to define a piecewise fatigue damage model (PFDM) for the prediction of damage in composite laminates under cyclic loading based on the continuum damage mechanics (CDM) model. Assuming that damage in fiber-reinforced plastic structures accumulates nonlinearly, a piecewise degradation growth function is defined and coupled with CDM and micromechanics approaches. The model divides the damage behavior of fiber, matrix, and fiber/matrix debonding at the ply scale, into three different stages. For generality, a fully multi-stage damage formulation on a single-ply level is employed. The unknown parameters of the PFDM are estimated according to obtained experimental... 

Nutrient disorder and presence of disease-causing agents in soilless media negatively influence the growth of muskmelon. To combat these issues, use of environmentally-friendly sanitation techniques is crucial for increased crop productivity. The study was conducted under greenhouse and field conditions to investigate the effect of two different sanitation techniques: steaming and formalin fumigation on various media’s characteristics and their impact on muskmelon yield. Media: jantar, guar, wheat straw and rice hull and peat moss of 10% air-filled porosity and sanitized with formalin and steaming. Steaming of guar, jantar, and wheat straw increased the phosphorus (P) and potassium (K)... 

Soil salinity threatens agricultural production worldwide by constraining plant growth and final crop yield. The early stages are most sensitive to salinity, in response to which salicylic acid (SA) has demonstrated beneficial effects in various plant species. Based on this, a maize (Zea mays L.) pot experiment was set up combining three levels of soil salinity (0, 6 and 12 dS m–1), obtained through NaCl addition, with three levels of SA (0, 300 and 600 mM), applied by leaf spraying 20 days after seedling emergence. Fifteen days later, the following traits were assessed: morphology (plant height, leaf number), growth (root and shoot dry weight), leaf water status [relative water content... 

The viability of electrical conductivity as a tool for describing the microstructure of sintered iron compacts was investigated, the sintering temperature being varied from dewaxing to high temperature sintering. The relationships between formation of sintered contacts, presence of lubricants, and mechanical properties were evaluated through determination of conductivity and effective load bearing cross-section Ac. The latter parameter was measured via quantitative fractography of specimens impact fractured at 77 K. The role of porosity and sintering temperature on grain growth in iron was also evaluated using quantitative metallography. It was found that the conductivity of pressed compacts... 

Second generation immigrant entrepreneurs (SGIEs) in developed economies have contributed to the emergence of new areas of business activity, especially in information technology, business services, and creative industries. An understanding of their growth strategies can shed light on the role of individual immigrants in the founding of potentially global firms competing with large multinational enterprises. Based on eleven case studies of SGIEs of Indian origin in the UK, our findings reveal that SGIEs are heterogeneous in their growth strategies contingent on their a) founding or succession context, and b) use of social ties. Founder SGIEs combining non-co-ethnic ties with non-family... 

The presence of nodules on the surface of cathode copper plates was the most important reason for the failure of the punch of mechanical clinching of copper cathode sheets. This study demonstrated a comprehensive investigation into the nodulation growth of copper cathodes in the electrorefining plant based on metallographic analysis. More than 15 random samples were selected from the top, middle, and bottom of the cathodes produced in the Khatoon Abad copper refinery, Iran. Studies were carried out based on the determination of growth modes including field oriented isolated crystal (FT), basis-oriented reproduction (BR), field-oriented texture (FT), and unoriented dispersion (UD). A scanning... 

This study aims at investigating the effect of the substrate material on growth mechanism and also microstructure of Ta2O5 thin films. For this purpose, atomic force microscopy, scanning electron microscopy, and interferometry analyses were implemented to reveal the influence of silicon wafer and amorphous BK7 glass substrates on the nucleation and growth mechanisms of Ta2O5 thin films deposited via the radio frequency magnetron sputtering technique. Results indicated that those films with finer morphologies had relatively higher nucleation densities. Compared with BK7 glass substrate, crystals formed on the silicon wafer were shown to be finer and had lower mean areas in more nucleation... 

Statistically based experimental designs were applied to screen and optimize the bioleaching of spent hydrocracking catalyst by Penicillium simplicissimum. Eleven factors were examined for their significance on bioleaching using a Plackett-Burman factorial design. Four significant variables (pulp density, sucrose, NaNO3, and yeast extract concentrations) were selected for the optimization studies. The combined effect of these variables on metal bioleaching was studied using a central composite design (CCD). Second-order polynomials were established to identify the relationship between the recovery percent of the metals and the four significant variables. The optimal values of the variables... 

The progressive-edge-growth (PEG) algorithm of Hu et al. is modified to improve the error floor performance of the constructed low-density parity-check (LDPC) codes. To improve the error floor, the original PEG algorithm is equipped with an efficient algorithm to find the dominant elementary trapping sets (ETS's) that are added to the Tanner graph of the under-construction code by the addition of each variable node and its adjacent edges. The aim is to select the edges, among the candidates available at each step of the original PEG algorithm, that prevent the creation of dominant ETS's. The proposed method is applicable to both regular and irregular variable node degree distributions.... 

The morphological characteristics and electronic structure of the BaTiO 3 films grown by pulsed-laser deposition technique have been investigated. AFM and FE-SEM images reveal columnar growth characteristic of these films. Utilizing spectrophotometer, optical band gap of the films were reckoned to be about 3.76 eV. Both dα/dE and PL vs. E plots reveal numerous luminance states in the gap. Despite the presence of many luminance faults in the gap, cations manage to preserve their electronic states  

A rapid, environmental friendly and low-cost method to prepare hydroxyapatite nanoparticles is proposed. In this method, hydroxyapatite is produced in a sonicated pseudo-body solution. The sonication time was found effective in the formation of the crystalline phase of nanoparticles. In our experimental condition, 15 min sonication resulted in the most pure hydroxyapatite phase. Also it was shown that growth temperature is a crucial factor and hydroxyapatite crystallizes only at 37 °C. The particles formed by sonication were generally smaller and more spherical than those obtained without sonication. Sonication increased the hydroxyapatite crystal growth rate up to 5.5 times compared to... 

Modified versions of the Zener drag equation were obtained by evaluating a non-random distribution of incoherent ceramic particles in a nano-crystalline material. Analytical investigation of particle-boundary correlation indicates that the limiting grain size would be proportional to fV -1/3 for fV larger than 2.96%. The limiting grain size can be obtained by a combination of random and non-random Zener drag pressure in the case of volume fractions smaller than 2.96%  

The climate change and human development in lake catchments have put these habitats in drying conditions, e.g. Aral Sea in Asia, Lake Chad in Africa, Lake Mead in USA, Lake Urmia in Iran, etc. These ecosystems play an important role in social, ecological, and economic activities. Lake Urmia, recognized as an international wetland in 1973 and located in Iran, which is the second largest hypersaline lake in the world, is in the same state. Lake Urmia biologically and ecologically is one of the most interesting places in the world. This lake is a habitat for various species. The lake's surface has shrunken from 6000 km2 to 900 km2 in 2013. The statistics indicate that the population has... 

The optimal feeder design in gravity casting processes is considered. The design problem is formulated as an additive, growth-like, evolutionary topology optimization problem. The initial design of the presented method is a casting part which is placed in a suitable environmental mould box. The method is composed of three stages: determining the feeder-neck connection point on the casting surface, constructing the feeder-neck and the feeder growth. During the growth stage, the feeder topology is changed gradually until satisfying some predefined criteria. The design of multiple feeders is also considered in this work. In the presented method, feeders are designed in a descending order of... 

The electrophoretic deposition (EPD) of chitosan on metallic substrates was investigated. The electrophoretic mobility of the natural biopolymer in aqueous solution as a function of pH was studied. Because the protonation/deporotonation of chitosan is pH-dependent, the electrophoretic mobility and deposition rate is shown to increase with increasing pH from 2.9 to 4.1. The film growth rate is estimated to vary in the range 0.02-0.08 μm/s depending on the pH value. At high growth rates (> 0.05 μm/s), a porous film is obtained due to hydrogen entrapment. The EPD method developed here is applicable for the surface modification of metal implants by chitosan to develop novel bioactive coatings. ©...