Sharif Digital Repository

A comparative investigation has been developed for the stability constants of several amino acid complexes with divalent metal ions, which have been determined by potentiometric pH titration. Depending on the metal ion-binding properties, vital differences in the building complexes were observed. The present study indicates that in some M(L) complexes, metal ions are arranged in carboxyl groups, but in other M(L)complexes, some metal ions are able to build chelate over amine groups. The results mentioned-above demonstrate that for some M(L) complexes, the stability constants are also largely determined by the affinity of metal ions for amine group. This leads to a kind of selectivity of... 

Objectives: The aim of this study was to investigate the effects of implant design on the apex area and on stress and stress patterns within surrounding bone. Methods: Three commercially available implants with the same diameter (3.5 mm), same length (10-11 mm), and same complement abutment were selected for modeling as follows: (1) flat apical design with light tapering degree, (2) dome-shaped apical design with light tapering, and (3) flat apical design with intense tapering in one-third of the apical area. According to human cone-beam computed tomography (CBCT), the bone was modeled using a cortical thickness of 2 mm and cancellous bone. Forces of 100 N and 300 N in the vertical and 15°... 

In recent years, there has been increasing interest in damaged DNA and RNA nucleobases. These damaged nucleobases can cause DNA mutation, resulting in various diseases such as cancer. Alkylating agents are mutagenic and carcinogenic in a variety of prokaryotic and eukaryotic organisms. The present study employs density functional theory (DFT/B3LYP) with the 6-311++G(d,p) basis set to investigate the effect of chemical damage in O-alkyl pyrimidines such as O4-methylthymine, O2-methylcytosine and O 2-methylthymine. We compared the intrinsic properties, such as proton affinities, gas phase acidities, equilibrium tautomerization and nucleobase pair's hydrogen bonding properties, of these... 

Background and purpose of the study. Carbon nanotubes (CNTs) are emerging drug and imaging carrier systems which show significant versatility. One of the extraordinary characteristics of CNTs as Magnetic Resonance Imaging (MRI) contrasting agent is the extremely large proton relaxivities when loaded with gadolinium ion (Gdn 3+) clusters. Methods. In this study equated Gdn 3+ clusters were loaded in the sidewall defects of oxidized multiwalled (MW) CNTs. The amount of loaded gadolinium ion into the MWCNTs was quantified by inductively coupled plasma (ICP) method. To improve water solubility and biocompatibility of the system, the complexes were functionalized using diamine-terminated... 

Through this work, a novel mathematical-based approach was proposed to develop reliable models for calculation of PVT properties of crude oils at various reservoir conditions. For this purpose, a new soft computing approach namely Least Square Support Vector Machine (LSSVM) modeling optimized with Coupled Simulated Annealing (CSA) optimization technique was implemented. The constructed models are evaluated by carrying out extensive experimental data reported in open literature. Results obtained by the proposed models were compared with the corresponding experimental values. Moreover, in-depth comparative studies have been carried out between these models and all other predictive models. The... 

In this paper, we investigated phase synchronization in delayed dynamical networks. Non-identical spiking Hindmarsh-Rose neurons were considered as individual dynamical systems and coupled through a number of network structures such as scale-free, Erdos-Rényi, and modular. The individual neurons were coupled through excitatory chemical synapses with uniform or distributed time delays. The profile of spike phase synchrony was different when the delay was uniform across the edges as compared to the case when it was distributed, i.e., different delays for the edges. When an identical transmission delay was considered, a quasi-periodic pattern was observed in the spike phase synchrony. There... 

The drift spectrum, as a new measure of earthquake-induced demands in structures, was developed using a uniform-stiffness continuous beam model. Practical limitations in the procedures based on such models have caused structural engineers to pay little attention to drift spectra. In this paper, a method is proposed to estimate the seismic-induced inter-story drift demands, using the modal analysis technique of lumped mass, non-uniform beam models. The proposed approach is simple and can overcome many deficiencies of the previous methods. It can take into account the very important effect of height-wise stiffness reduction on drift demands, without the numerical difficulties usually... 

Energy harvesters are used in today's Wireless Sensor Networks (WSNs) to harvest energy from the environment. Although an energy harvester can provide a supply source with a much greater lifetime than a battery, the amount of available energy for an energy harvesting system is a random variable. Furthermore, the proper management of energy harvesters has a considerable impact on reliability. It has been observed that cooperative error control mechanisms like Cooperative Automatic Repeat Request (C-ARQ) and Cooperative Hybrid ARQ (C-HARQ) can be used for improving the energy management and reliability in Energy Harvesting WSNs (EH-WSNs). Recently, the impact of C-ARC mechanism has been... 

In this article, we have used quantum and semiclassical models to analyse the electrical characteristics of gate all around silicon nanowire transistor (GAA SNWT). A quantum mechanical transport approach based on non-equilibrium Green's function (NEGF) method with the use of mode space approach in the frame work of effective mass theory has been employed for this analysis. Semiclassical drift diffusion mode space (DDMS) approach has also been used for the simulation of GAA SNWT. We have studied the short-channel effects on the performance of GAA SNWT and evaluated the variation of the threshold voltage, the subthreshold slope (SS), the leakage current and the drain-induced barrier lowering... 

The main aim of this work was to assess the ability of Bayesian multivariate adaptive regression splines (BMARS) and Bayesian radial basis function (BRBF) techniques for modelling the gas chromatographic retention indices of volatile components of Artemisia species. A diverse set of molecular descriptors was calculated and used as descriptor pool for modelling the retention indices. The ability of BMARS and BRBF techniques was explored for the selection of the most relevant descriptors and proper basis functions for modelling. The results revealed that BRBF technique is more reproducible than BMARS for modelling the retention indices and can be used as a method for variable selection and... 

This paper investigates the efficiency and performance of several of the fiooding techniques popular in secondary and enhanced oil recovery. These processes include water fiooding, immiscible and miscible gas fiooding, and several forms of water-alternating-gas (WAG) injection. The study is carried out numerically on a typical one-dimensional domain using an advanced high-resolution central scheme. Some performance indices such as oil cut drop, breakthrough time, and sweep efficiency were employed to evaluate the appropriateness of each injection strategy  

Recently, Shape Memory Alloys (SMAs) have been receiving more attention and further study, due to their ability to develop extremely large, recoverable strains and great forces. In this paper, three major models of SMA behavior, used in the literature, for studying the static performance of SMA components attributed to Tanaka, Liang and Rogers, and Brinson, have been analyzed and compared. The major differences and similarities between these models have also been emphasized and presented in this paper, based on the experimental data of the shape memory and superelastic behavior of an SMA wire. It is shown that these models all agree well in their prediction of the superelastic behavior of... 

Layers of cobalt and manganese oxides were co-deposited or deposited on top of each other or next to each other by potentiostatic method onto stainless steel substrate. Deposition potentials of 1 and -1 V for the anodic and cathodic depositions were employed. Specific capacitance values in the range of 38.5-78 F g -1 were found with cobalt oxide on top of manganese oxide having the lowest and manganese oxide on top of cobalt oxide having the highest capacitances. The usefulness of the electrodes was characterized by cyclic voltammetry, charge-discharge cycling, and electrochemical impedance spectroscopy in 2 M NaOH electrolyte for redox supercapacitor applications. The latter presented the... 

Endurance Time (ET) method is a time history based method for seismic evaluation of structures using intensifying dynamic excitation as the loading function. In this paper, application of this method in the analysis of steel tanks has been investigated. A methodology for practical application of ET method in seismic assessment of storage tanks has been presented. This methodology has been applied in three-dimensional nonlinear analysis of a particular anchored steel tank using Finite Element method, and results are compared with conventional codified design procedures. Results of the analyses indicate reasonable accuracy of the proposed method in estimation of seismic responses of steel... 

In the present study, two preconditioners proposed by Eriksson, and Choi and Merkel are implemented on a 3D upwind Euler flow solver on unstructured meshes. The mathematical formulations of these preconditioning schemes for the set of primitive variables Q→p 1=[ρ u v , w p] T are drawn and their eigenvalues and eigenvectors are compared with each others. A cell-centered finite volume Roe's method is used for discretization of the 3D preconditioned Euler equations. The accuracy and performance of these preconditioning schemes are examined by computing low Mach number flows over the ONERA M6 wing for different conditions  

Bolted Column Base Plate (BCBP) connections are widely used to connect steel columns to the concrete foundations. This paper conducts a parametric study on the initial stiffness of bolted base plate with Square Hollow Section (SHS) column connection, through an extended 3-D Finite Element Modeling (FEM). Different features of the connection such as material behavior, geometric details, typical contact phenomena and large displacements are also considered in the modeling. A comparison between experimental test and FEM is carried out to illustrate the ability of the numerical method to simulate the connection behavior. An analytical explanation on the initial stiffness of the connection is... 

Acute hypotension episodes are one of the hemodynamic instabilities with high mortality rate that is frequent among many groups of patients. Prediction of acute hypotension episodes can help clinicians to diagnose the cause of this physiological disorder and select proper treatment based on this diagnosis. In this study new physiological time series are generated based on heart rate, systolic blood pressure, diastolic blood pressure and mean blood pressure time series. Statistical features of these time series are extracted and patients whom are exposed to acute hypotension episodes in future 1 hour time interval and whom are not, are classified based on these features and with the aid of... 

Low energy consumption and fault tolerance are often key objectives in the design of real-time embedded systems. However, these objectives are at odds, and there is a trade-off between them. Real-time systems usually use system level energy reduction methods, i.e., dynamic voltage scaling (DVS) and dynamic power management (DPM). Also hard real-time systems often use replication to achieve fault tolerance. In this paper, we investigate the impact of system level energy reduction methods on both the reliability and energy consumption of hard real-time systems which use replication for fault tolerance. In this analysis, we have considered four various existing energy management methods: 1)... 

A new exponential model to depict the moment-rotation (M-θ) relationship of Bolted Endplate Connections (BEC) is proposed. The proposed model represents an approach to the prediction of M-O curves, taking into account the possible failure modes and the deformation characteristics of the connection elements. The presented model has three physical parameters, along with two curve-fitted factors. These physical parameters are generated from dimensional details of the connection, as well as the material properties. By employing simplified connection behavioral models to estimate the connection M-θ behavior, analytical expressions for evaluating major connection parameters, such as initial... 

There are two main scalable methods for streaming live video over the Internet: Content Delivery Networks (CDNs) and Peer-to-Peer (P2P) networks. Though both have their own problems, P2P streaming systems challenge delivering video with constant quality and CDNs approaches require deployment of large number of servers throughout the Internet that is costly. Recently, using hybrid architectures based on both CDN and P2P networks has shown to be an efficient approach for large-scale video distribution over the Internet. This paper is compared the performance of two main hybrid CDN-P2P architectures includes: (i) CDN-P2P unconnected mesh in which independent P2P mesh networks are constructed...