Sharif Digital Repository

The objective of this study was to investigate the synergistic effect of TBP on the system D2EHPA/kerosense/M2+ with respect to the extraction of some transitional metals. Although the presence of M2EHPA as an impurity in D2EHPA shifts the extraction curves to lower pH, empirical results show that the extraction curves shift to the right due to the addition of TBP and the counterbalance effect of M2EHPA. The results indicate that the equivalent concentration of D2EHPA decreases as a function of concentration of TBP because of the formation of hydrogen bonds between TBP and D2EHPA. Based on this finding, the D2EHPA equivalent concentration was determined by using a modifying factor for TBP... 

Single-walled carbon nanotubes (SWCNTs) emit near-infrared (NIR) fluorescence that is ideal for optical sensing. However, the low quantum yields diminish the sensor's signal-to-noise ratio and limits the penetration depths for in vivo measurements. In this study, we perform a systematic investigation of the plasmonic effects of Ag and Au nanoparticles of various geometries to tune and even enhance the fluorescence intensity of single-stranded DNA-wrapped SWCNTs (ssDNA-SWCNTs). We observe a chirality-dependent NIR fluorescence enhancement that varies with both nanoparticle shape and material, with Au nanorods increasing (7, 5) and (7, 6) chirality emissions by 80% and 60% and Ag nanotriangles... 

High-bainite dual phase (HBDP) steels with 34. vol.% ferrite were subjected to tensile strains of 1%, 3%, and 5% at intermediate temperatures (150-450. °C). Mechanical behavior of pre-deformed steels was then investigated at room temperature. A maximum value for both yield stress and ultimate tensile strength was observed for pre-deformed steels. A minimum elongation was also found in the same pre-deformed specimens at the range of 250-350. °C. It was found that dynamic strain aging (DSA) plays the major role in mechanical properties of pre-strained HBDP steels. The DSA indicator parameter (DSAP) was introduced to evaluate DSA mechanism. Maxima of DSAP were likewise observed at the range of... 

Re/Mo separation is studied by a new solvent extraction technique which is based on extraction mechanisms of the constituent metals. Based on McCabe-Thiele plots, a flow diagram has been proposed for separation and purification of Re over Mo. Re-recovery section of the diagram shows that Re is extracted when major amount of Mo is removed. For removal of the remained Mo, a two-stage extraction is required at pH = 2 and V a/V o = 1. In order to obtain Re, the resulted aqueous phase is stripped by adding sulfuric acid. According to the results, while more Re is extracted at less pH, optimum extraction of Mo happens at pH = 1.2. Re selectivity over Mo maximizes by approaching of the pH to zero  

This paper reports on the recovery of zinc, cobalt and manganese by two-step leaching of zinc-plants purification residue with sulfuric acid. The residue, hot filter press cake (HFC), contains 14 % ZnO, 4.8 % Co 3O4 and 22.9 % MnO. Effects of different parameters are determined and used to optimize the process. With acid to hot filter press cake (HFC) stoichiometry of 0.85, acid concentration of 30 g/L and temperature of 25°C, it took two minutes to separate zinc from zinc plant residue. Hydrogen peroxide (H2O2) was used as an oxidation agent. The most suitable acid concentration for leaching of both cobalt and manganese was 50 g/L. Recovery of cobalt and manganese increased with peroxide... 

In the present study, the thermodynamics and mechanisms of vanadium extraction by a mixture of bis-2-ethylhexyl phosphoric acid (D2EHPA) and tri-n butyl phosphate (TBP) from sulfate medium were investigated. It was found that the maximum extraction percent of vanadium occurs at pH 1.8 under ambient conditions; this phenomenon was ascribed to the predominant presence of cationic species of vanadium (VO2+) at this pH. Based on the Fourier Transform Infrared (FT-IR) spectrums, the POH bond of D2EHPA was found responsible for the extraction of VO2+ species through a cationic exchange mechanism. Employing the slope analysis method showed that the stoichiometric reaction... 

Forming limit diagrams (FLDs) are extensively used in industries, particularly the auto industry. The establishment of these diagrams using a predictive approach can lead to reduction in both cost and time. In the present work, Gurson-Tvergaard-Needleman (GTN), a porosity-based model, was used to predict the FLD of an interstitial-free steel via finite element simulation. Optimum values of the GTN model were obtained by applying a response surface methodology (RSM) based on central composite design. Results show that RSM is a good method for an appropriate determination of the GTN model parameters, such as initial void volume fraction, effective void volume fraction, critical void volume... 

Background/Objectives: One of the problems of tracked robots in ragged roads is to pass narrow obstacles. As a primary solution, the process of come back and pass another way is usually time consuming or impossible. Methods/Statistical Analysis: In this paper, first, we evaluate the usual solution for this problem, which is preparation of a drive system at the middle area and then by using of innovative problem solving method (TRIZ), by answering ISQ questionnaire and extracting some technical contradictions, we try to match them in contradiction matrix and finally by applying 40 innovative principles we solve these technical contradictions which lead us to the solution of the problem.... 

One of the most important courses in engineering curriculum is "engineering drawing". In fact, engineering drawing is the language of conversation and realization between engineers. This course consists of 3 parts: Projection theory, basic drawing and mechanical drawing. The most important part between these is projection theory because it supports one of human intelligences named "spatial ability" that is vital for an engineer. Otherwise, time limits, increasing of user demands and need to higher reliability, causes us to think about "problem prevention" instead of "problem solving". The tool helps us in this way is "failure mode and effects analysis" or FMEA. In this study, after... 

This paper presents a new approach for trajectory planning of manipulator robots based on Virtual Potential Field (VPF) in presence of static obstacles. In this method, a series of via points between starting point and goal point is obtained by traverse end-effector of manipulator in affected by different VPF while avoiding obstacles in the Cartesian space. An optimum trajectory is generated by using pattern search algorithm which determines strength of potential fields to minimize the value of desired objective function. Cubic splines are used to generate a smooth trajectory through path points in joint space that are obtained by inverse kinematics solution of corresponding points in the... 

Transportation has significant and long lasting economical, social and environmental impacts, and so is an important dimension of urban sustainability. Some attempts have been made to develop sustainable transport indicators, STI. A few studies actually apply STI to compare sustainability among various world cities. In this paper various world cities ranked in terms of urban sustainable transport composite index. The study database is created from UITP databank: "Millennium cities database for sustainable mobility" or MCDST. Firstly sustainable transportation indicators were selected by reviewing past researches. Some indicators are edited or redefined. Consequently 9 STI were developed, 3... 

In noise radars, measuring the cross-correlation between transmitted and received signals is a common method of signal processing. However, it brings a lot of unwelcome sidelobes that can mask weak echoes of far targets. There are many classical and modern methods of masking effect removal which are based on signal processing in the receiver side. In this study, a method of waveform design is presented and its ability to reduce masking effect is compared with that of radars using purely random waveforms. The method starts with choosing an arbitrary subsequence and continues with attaching new subsequences to the previous ones in a way that the sidelobe levels reduce. In addition, the... 

A common and well-known method of signal processing in noise radars is measuring the cross-correlation between transmitted and received signals. However, it creates a lot of undesirable sidelobes which can mask weak echoes of far targets. There are many methods of masking effect removal based on signal processing at the receiver side. In this study, a method of waveform generation based on the graph theory is presented and its ability to reduce masking effect will be compared with that of radars using purely random waveforms. The method tries to design a graph consisting of nodes each corresponds to a random subsequence. After generating the graph offline, output sequence is produced online... 

In noise radars, measuring the cross-correlation between transmitted and received signals is known as a common method of signal processing. However, it brings a lot of unwelcome sidelobes which can lean to masking weak echoes of far targets. There are many classical and modern methods of masking effect removal which are based on signal processing in the receiver side. A method of waveform design for decreasing this effect is presented and its efficiency is compared to purely random waveform generation method and CLEAN algorithm. Moreover, performance of collaborative using of receiver-based and transmitter-based techniques is considered  

Signal processing in noise radar is always done by calculating the cross-correlation between transmitted and received signals. Strong echoes of near targets present relatively high sidelobes in the correlation output, so they can conceal weak echoes of weak targets (masking effect). Many classical and modern methods for alleviating this effect have been offered, however, most of them are based on signal processing in the receiver side. In this paper, a new method of waveform design, able to decrease masking effect, is presented. Contrary to the other methods, this method keeps the matched filter structure in receiver unchanged and does not need performing any extra process in the receiver... 

In this paper, the effect of the main rotor of an armed helicopter on radar return signal and its modulation condition are considered. After analyzing references and experimental data, this paper proposes a new method based on inherent modulation in main rotor echo. This method is able to enhance the probability of detection. The simulation is performed for both simulated and practical echo signal. Simulation results confirm that our proposed scheme is effective. Moreover, a new domain for distinguishing and measuring the rotation feature of a rotary target is proposed. This paper is based on practical experiments (rotation domain)