Sharif Digital Repository

Sodium Hydroxide production industry is among the largest chemical industries that annually produces 66 million tons worldwide. NaOH which is produced through electrochemical cells needs to be further enriched. The use of membrane technology as a substitute for conventional processes has been a point of interest. Thin film composite membrane is among favorable membrane because of its ability to be customized layer by layer individually. In this thesis, for the purpose of making an optimized membrane for NaOH enrichment, we studied the preparation conditions and witnessed that by increasing MPD from 1.5 %wt. to 4.5%wt. The flux experiences a minimum at 3.5%wt, which is the maximum for... 

The synthesis and usage of TiO2/ZnO nanocomposite thin film in antibacterial activity against E-coli were experimented through a systematic research. TiO2/ZnO nanocomposite films can demonstrate different properties like gas sensing, self cleaning and treatment of the broad range of aqueous pollutants when it is exposed to light with wavelengths less than 400 nm. This phenomenon happens because of the photocatalytic reactions in the nanocomposite thin film which cause active species production on the surface of the thin film. The nanocomposite synthesis was based on sol-gel process in atmospheric pressure. In this study titanium dioxide is prepared by sol gel method from titanium... 

Hydrogen sulfide, H2S, is a toxic gas and has detrimental effects on human health and the oil and gas industry. Therefore, its identification is very important. According to the devastating effects of this gas, then, the general mechanisms have been studied for gas detection. In addition, by highlighting the benefits of the multilayer nanostructure electrochemical sensors, an applicable and efficient method for the industrial production of these sensors has been investigated. In this regard, the sol-gel method is used to prepare the SnO2-CuO multilayer thin film and the advantages of this method was compared to PVD method. Also sensor properties of both deposition methods have been... 

In this study TiO2/SiO2 thin films were prepared by sol-gel method from Tetra isopropylortho Titanate(TIPT) as the principle of TiO2 material with Tera ethoxysilane(TEOS) as the principle of SiO2 material to achieve high scratch-resistant , antibacterial and self-cleaning surface area under the effect of various percentage of SiO2 . Film deposition was carried out using a dip-coating technique and heat-treatment was used at 700ºC to achieve crystalline of films with excellent adherence the of substrate.
The surface morphology of the films has been observed by Scanning Electron Microscope (SEM) and the tribological properties of the surface were investigated by Atomic Force Microscope... 

This thesis is concerned with the synthesis and characterization of high porous Ti based on thin films and the effect of polymer agents on their photocatalytic properties. Ti films can demonstrate different properties like self -cleaning and treatment of broad range of aqueous pollutants when it is exposed to light of wavelength less than 400 nm. This is due to photocatalytic reaction occurring on film surface which results in film superhydrophilicity and the active oxygen species production. This active sites and radicals will cause oxidize organic pollutants and microbe adherent to the material surface.
In this study Ti thin films have been prepared by the sol-gel method from... 

Different parts of this research are focused on developing FO membranes and improving their performance. For this purpose, thin film composite (TFC) membranes with fixed composition of polyethersulfone/polyamide (PES/PA) have been used to investigate the effect of nanocomposites containing transition metal dichalcogenides (TMDs) on their performance. The support layer in all cases is PES, which is prepared through the phase inversion process and does not contain any nanofillers. The modification process takes place in the polyamide layer by dispersing the desired nanoparticles in the aqueous monomer solution necessary to form this active layer. Identification and characterization of... 

The aim of this thesis was to study and fabricate stable inks of Cu2SnS3 (CTS), Cu2ZnSnS4 (CZTS) and Cu3SbS4 (CAS) copper-based chalcogenide nanoparticles (NPs) and their application in solar cells. Inorganic semiconductors with p-type conductivity, high stability, high hole mobility (compared to organic type), and the ability to synthesize and deposition by simple low temperature solution-based methods have the potential to provide suitable alternative for hole-transporting material (HTM) in perovskite solar cells (PSCs) and the photo-absorbers in thin film solar cells (TFSCs). The ability to adjust energy levels and optoelectrical properties is another advantage of these compounds. In... 

Solar cells, as a part of photovoltaics (PV) industry, have a significant share in the renewable energy market. Perovskite solar cells (PSCs) and thin film solar cells (TFSCs) achieved 23% and 22% power conversion efficiencies (PCEs) respectively. However, the PV industry still faces challenges like “high manufacturing costs” and “stability”. Among the strategies to overcome these challenges are substitution of the costly materials with cheaper, more abundant ingredients along with utilizing inexpensive deposition methods like printing rather than vacuum-based methods such as evaporation and sputtering. Carbon materials attract more attention in the solar cell research community for their... 

The broad range of applicability of nano devices particularly in electronics, optoelectronics, and micro/ nano-electro- mechanical systems has drawn the attentions of the industrial and scientific communities of various disciplines. This work is devoted to study the effect of surface and interface elasticity in the analysis of the mechanical behavior of ultra-thin objects in the presence of some statical or dynamical loadings. Based on the fact that the surface-volume ratio increases in nano-scale, description of the behavior of such a small structure via usual classical theories, which generally neglect the surface/interface effect, ceases to hold. In the present study, first, a... 

In this research, a homogeneous elastic half-space with transversely isotropic behavior, reinforced by an isotropic thin membrane is investigated under static loading with an analytical approach. The membrane is considered as an infinite plane with a thickness of negligible and buried at the arbitrary depth from the surface of the half-space, also its flexural strength is neglected and only the in-plane stiffness is considered for it. The reinforced half-space is investigated under several concentrated and distributed static loads, which are applied to the surface of the half-space or buried at the depth of the membrane. The membrane is first modeled as a three-dimensional elastic layer and... 

In this study, an analytical solution is presented for anti-plane scattering of Love waves by a surface-breaking crack normal to the free surface of an ultra-thin layer bonded to a semi-infinte medium within the surface/interface elasticity theory. The Fourier transform techniques are used to formulate the corresponding mixed-boundary value problem as a singular integral equation of the Cauchy type which is solved numerically. Mode III dynamic stress intensity factor at the crack tip, crack face and crack mouth opening displacements, the reflection coefficient at large distances from the crack face, and the stress field on the interface are computed and plotted for different valued of... 

Thin film solar cells have low efficiency compared to crystalline silicon solar cells; however, they are low-cost and flexible. In manufacturing these solar cells, thin films are deposited at high temperatures (higher than 200℃) on a thick metal, plastic, or glass substrate using sputtering and plasma enhanced chemical vapor deposition (PECVD) methods. Since the thin films and substrate have different thermal expansion coefficients, cooling the system from deposition temperature to room temperature induces thermal residual stresses in both the films and substrate. In addition, these stresses, especially those induced in the amorphous silicon layer can change the carrier mobility and band gap... 

Evaporation and condensation of thin films can rupture or stabilize thin film .We show that evaporation hastens dewetting of a thin film. Dewetting over nanometric downward step causes pinning of the contact line near the step. This phenomena is not permanent and after certain time that contact angle reaches to its critical value depinnnig happens. We also study the effect of the step size, contact angle, film thickness, slip and evaporation on the depinning time of the contact line. We show that depinnig time has a reverse relation with the rate of evaporation  

This study investigates three-dimensional modeling of nanodroplets over chemically patterned surfaces. The pattern can be established by changing the contact angle on the surface. The problem is studied numerically by solving the thin film equations.Both the long-range and short-range inter-molecular interactions are considered. The numerical procedure is validated by using the theoretical studies. The effects of parameters such as the size of the droplets, the gradient of the surface, and the slip coefficient on the dynamics and speed of droplets and the shape of them during the motion are inspected.By examining the dynamics of the system it is revealed that the velocity of the droplets... 

Thin films of materials, in order to have magnificent structure and properties, can use in complicated technology such as; electronic, optic and magnetic systems. Printed interconnects can be made by the deposition of suspensions of metal nanoparticles (e.g., silver and gold) followed by thermal sintering. The nanoparticle sintering process involves atomic diffusion resulting in shrinkage. As a result, the interconnects are prone to residual stresses generated during the thermal sintering process. The residual stress can cause cracks and delamination in the thin films and can cause permanent geometrical changes in the underlying substrates which may affect the functionality of the... 

Thin liquid films on solid substrates are of considerable relevance in widespread of natural and technological fields. Examples are eye irrigation, biological cell interaction, tertiary oil recovery, coating, painting, lubrication, integrated circuits, micro- and nano-electronic devices, to name just a few. It is well known that liquid films are not always stable and there are verities of factors that may destabilize and expose the film to dynamical processes which leads to removal of the liquid from the substrate, the phenomenon so-called dewetting, either by nucleation or spinodal mechanisms. In many cases dewetting is destructive but there are several situation in which dewetting turns... 

Herein, cupric oxide (CuO)/graphitic carbon nitride (g-C3N4) is synthesized under microwave irradiation for enhanced photoelectrochemical (PEC) performance and photostability. A facile, one-pot method was utilized to directly deposit the nanocomposite onto FTO from a solution containing copper precursor and urea. Possible mechanisms of CuO/g-C3N4 formation and PEC performance improvement were examined via XRD, FTIR, FESEM, XPS, UV-Vis, and PL. Controlled amounts of urea determined the morphological evolution of CuO and the formation of a protective carbon layer, while its excess quantity converted to g-C3N4 in the presence of CuO. Through heat treatment of the nanocomposite, carbon-doped... 

Considering the importance of biocompatibility of implantable prothesis’, metallic alloys have weaker corrosion resistance than ceramics. In order to extend usage of nanomaterials to improve the bio-properties of materials, Nano-structured ceramic coatings are being suggested to improve corrosion resistance and biocompatibility of prosthesis. Meanwhile, very good properties of TiN, such as corrosion resistance and mechanical properties as a thin film coating are undeniable. In this study, TiN and Ti2N thin film were deposited on Ti-based substrate, using PVD and Magnetron sputtering at different argon to nitrogen ratio. The crystal structure of the films was examined using Grazing XRD... 

The main purpose of this research was simultaneous doping of carbon and nickel in the structure of barium strontium titanate, in order to investigate its dielectric and optical properties. Powders and films of BST, was synthesized by the sol-gel method in six different compositions: without any dopant, 0.04mol nickel dopant, 0.04mol nickel dopant accompanied by different amounts of carbon (0.01, 0.02, 0.03 and 0.04 mol). Suspensions were dip coated on alumina and quartz substrates. Structural features and chemical bonds, were studied through thermal analysis, XRD, FT-IR, FESEM and AFM. For electrical and optical properties, LCR-meter and UV-Vis were used. XRD and FESEM proved that nickel... 

In this project, the goal is to form gold nanoparticles on glass surface using Sol-Gel method, to create the appropriate physical and optical properties. To reach this purpose, the main point is to form the stable gel as a network of nanoparticles on glass surface. After coating, physical properties, surface properties and morphology were investigated. To investigate the absorption rate, the optical spectrum reflex had been appeared through 500-550 nm using UV-Visible test. Also, to observe morphology, particle size and distribution on the surface, the thin films have been tested via FESEM. Using a polymer template for gold nanoparticles, the structure of nanoparticles optimized...