Sharif Digital Repository

Fractured carbonate reservoirs are mostly oil-wet to intermediate-wet. Due to the negative capillary pressure of the matrix poor spontaneous imbibition of reservoir brine occurs in such reservoirs, and water flooding leads into early break through due to the high conductivity of the fracture network. Some surfactants have the ability to change the wettability of rock matrix toward water-wet state by adsorbing onto the rock surface. The phenomenon can result in spontaneous imbibition improvement and thereby increasing water flooding efficiency and recovery from fractured carbonate reservoirs. In this thesis the effect of some surfactants on the wettability of Iranian carbonate reservoir rocks... 

There are a lot of Fractured reservoirs around the world that have large portion of oil production. These reservoirs have complex structure and fractures have important role in production but the remaining oil in matrix causes that the oil recovery decreases. One of the most important factors in these reservois are wettability. Because most of the fractured reservoirs are oil wet and water injection process in these reservoirs are not effective and chemical EOR methods such as surfactant flooding method is used. Surfactant improve oil recovery by two reasons: 1- reduction of interfacial tension between oil and water . 2-Wettability alteration of matrix. The porpose of this project is... 

The aim of this research is to study the effect of surfactant type and the concentration reactants on the size, shape and magnetic properties of iron-gold core-shell magnetic nanoparticles (NPs) useable for biomedical application. The reverse micelle procedure was employed to synthesize iron NPs using two surfactants of CTAB and SDS. A gold shell with a thickness in the range of 10 to 40 nm was induced by reverse micelle method in order to prevent oxidation of the iron core. The size and morphology of NPs were studied by transition electron microscopy (TEM). It was found that the size of NPs increases by the increasing the reactants concentration while the morphology of the NPs was not... 

Today, due to limited number of light oil reservoirs, enhanced recovery from heavy oil reservoirs is taken into consideration. During the early production from heavy oil reservoirs, due to high viscosity, only a small amount (about 5%) of the oil can be produced; also after water injection operation due to unfavorable mobility ratio of water and oil, sorely more than about 10% of the original oil can be produced. On the other hand, fractured reservoirs represent about 20% of the world's oil reserves, while over 60% of the world's remaining oil reserves are in fractured reservoirs. Water flooding process leaves very high amounts of oil as remaining oil in these reservoirs too. One of the... 

Application of nanotechnology in the field of heat transfer has increased recently. The need to increase heat transfer rate yet decrease the size of cooling equipment, brought about lots of attention to thermal properties of Nanofluids. Nanofluid is the suspension of nanometer-sized solid particles in base liquid. Research on convective heat transfer of nanofluids which is only two decades old, shows great potential in increasing heat transfer rate. Although there is a remarkable research on thermal conductivity of Nanofluids, negligible research was conducted on combined Nanofluids . Developed Theory for thermal conductivity of combined nanofluid can be used to modeling the thermal... 

Nowadays, due to limitation of production from conventional oil reservoirs, enhanced recovery from heavy oil reservoirs is of great concern. However, production from these energy resources is not a simple task and production using common technologies is not easily exploitable. Heterogeneous structure and also high surface tension between injected fluid and reservoir oil are of the main challenges during water flooding processes in heavy oil reservoirs. The high surface tension force causes a large part of the oil remains in the reservoir after the water flooding operation. One method for overcoming this problem is the use of surfactants that reduces capillary forces and consequently... 

Improving efficiency of heat exchangers has always been an important concern for the industry. Pulsating heat pipes are novel and efficient technology in the field of heat transfer. Pulsating heat pipes are widely used in solar water heaters, solar desalination systems, air conditioning systems, cooling of electronical boards, etc. these applications explain the necessity of performing this study in our country. In this research, thermal performance of open loop pulsating heat pipes using two operating fluids (ferrofluid with surfactant and aluminum microfluid) is experimentally investigated. Start-up and steady thermal performance of pulsating heat pipes charged with these two operating... 

The purpose of this research is producing one phase silica superhydrophobic coating by sol-gel method and drying temperature less than 200 degrees. For preparing micrometer and nanometer scaled hierarchical structure based on silica, TEOS precursor and Fumed Silica nanoparticles were used by density of 43/30 cc/lit and 6/52 gr/lit in order to provide desired roughness in the range of 40 nm. Moreover, HMDS surface modifying agent was used for reducing the surface energy of coating, which is not a danger to the environment in comparison to the same substances. The best Contact Angle is 155 degree and the best Sliding Angle is less than 5 degree. For instance, it was created with the... 

Water base drilling fluids are the most common drilling fluids in oil and gas operations and biopolymers are the requisite additives used in such kind of fluids frequently. Unfortunately, at harsh conditions of HPHT the polymers undergo thermal degradation which cause serious loss in fluid rheological and filtration properties. Accordingly, this will induce operational pitfalls and tremendous cost. The power of economy along with environmental regulations force us to search for reasonable chemically benign additives to fulfill this need. Nanoparticles are the most promising additives proposed in this study to address this challenge. Regarding their unique exclusive properties, they are able... 

Acidizing efficiency depends on various factors such as formation properties, reservoir and stimulation fluid types and injection scenario. Among these factors, heterogeneity of reservoir’s formation (layered reservoirs and permeability variation versus depth) strongly affect acidizing performance. Accordingly, applying a reliable technique that distribute stimulation fluid uniformly is essential. The aim of carbonate matrix acidizing is to improve fluid flow specially in low permeability zones. Stimulation fluid cannot enter into the low permeability layer due to existence of high permeability layers which are in contact with low permeability ones. So, the stimulation fluid should be... 

Surface phenomena is one of the fundamental branches of science that has many applications in industries related to multiphase processes. One of the most important issues of this knowledge is inter-phase transport phenomena in contacting gas - liquid and liquid – liquid systems. Multiphase systems generally include dispersions such that in many cases are associated with the relative motion between the continuous and dispersed phase. One of the most widely used inter-phase flow systems is dispersion of gas bubbles in the bulk of liquid. The overall efficiency of these systems is often determined by the characteristics of the gas phase. In order to understand the dynamic behavior of such... 

Surface phenomena and dynamic interfacial properties plays a significant role in multiphase gas-liquid & liquid-liquid processes applied in different industrial applications. However, current laboratory equipment and represented methods for dynamic and unsteady state condition caused by motivation of interface of two phases (like rising bubble), in purpose of qualitative investigation of interphase properties are not satisfying enough. Also, common modeling methods are represented with lots of modified assumptions which are not validated properly with experimental results. In current thesis, with development of laboratory tools and applying the “rising bubble method” for investigating the... 

Imbibition process is known to be an important recovery mechanism in naturally fractured reservoirs with water-wet matrix blocks that are imposed to water influx from an active aquifer or water flooding. Matrix blocks which are subjected to water flooding or water invasion from active aquifers do not become immersed in water at once, but they experience gradual rising of water in fracture. But most of imbibition studies are performed under conditions of totally immersed cores in static aqueous phase. Surfactants are known to reduce residual oil saturation by decreasing interfacial tension (IFT) between oil and water. On the other hand, considerable reduction of IFT due to surfactant... 

Surface phenomena and dynamic Interfacial properties play an important roles in gas- liquid and liquid-liquid multiphase process from various industrial applications to understand fundamental phenomena. However, there is no experimental equipment and efficient methods for quantitative and detail investigation of interfacial properties under fast and non-equilibrium dynamic condition due to mobility and refreshing of interface (such as rising bubble). Also existing models accompanied with a lot of simplifications which is not yet validated with a proper experimental data. development of laboratory equipment base on measuring momentary capillary pressure and presenting a new experimental... 

Understanding the properties of crude oil and the phenomena arising from this precious matter has always been of considerable importance. One of these important phenomena is emulsion, which is well-known in a great number of crude oil-related processes such as drilling, well completion, production, transportation and even the processing units in the refinery. One of the most important properties of crude oils and their emulsions is their flow or in other words their rheology. Therefore, in this project has also been tried to investigate the rheological behavior of crude oil and water in crude oil emulsion, experimentally and theoretically. The experiments were carried out using two crude... 

Always, understanding the properties of crude oil and related phenomena of that has been noticeable matter. Surface tension is one of the important fluid properties and the evaluation of that is essential in oil industry especially in enhanced oil recovery method (EOR) and transport of crude oil by using emulsions.
In this research, interfacial tension (IFT) was measured via pendant drop method. The effect of three parameters was investigated on IFT for creating of stable oil/water emulsion. These parameters were temperature, concentration of surfactants, and salinity. They were varied between 25-65 ᵒC, 0.05-0.2 gr and 5000ppm respectively. It was used two types of surfactant; acid... 

The success of matrix acid production operations and its proper efficiency is one of the main challenges for oil and gas companies. The heterogeneity of the reservoir formation (especially the permeability difference) in the area around the well due to the presence of different reservoir layers results in the non-uniform distribution of acid among them and adds acidizing challenges. In order to improve production conditions, stimulation fluid transfer to the low permeability layer, which is the main target of acidizing. In this study, a new generation of chemical diverter, called Viscoelastic Surfactant, has been used. These materials have two components of elastic and viscous behavior, and... 

Interest in the study of evaporation of liquid droplets is associated with a variety of practical applications, ranging from fuel burning and intensification of heat and mass transfer processes to formation of nanostructures. The study of the evaporation of liquid droplets is a fundamental problem, and it is the subject of a large number of works. However, in droplet evaporation processes, there are still many fundamental issues requiring more in-depth studies. In this study, the effect of the presence of hydrophilic silica nanoparticles and cationic (CTAB), anionic (SDS) and nonionic (TX-100) surfactants separately and in combination on the evaporation rate of water in a pendant droplet... 

In this experimental work terminal velocity, velocity profile and aspect ratio of bubble with 1.49 mm diameter which ascend in pure water and infected by surfactant nonionic C10DMPO and surfactant ionic SDS in regime that surface tension is dominant, have been considered. Observations showed that with respect to entering nozzle, bubbles with this diameter have two initial stable shape; spherical and extended form on surface for horizontal needle and vertical nozzle. Results are (1) Bubbles with initial spherical shape had lower terminal velocity and higher aspect ratio with respect to bubbles with initial extended form, (2) Spherical bubble had aspect ratio about 1 at whole bubble column... 

Asphaltine particle precipitation may lead to serious problems in petroleum industry; including wellbore transmissibility reduction. One of the proposed remedial methods is to make a use of the microorganisms which are able to consume the heavy hydrocarbon chains.
Hydrophobicity of a cell surface is one of the parameters which greatly affect the microorganism adhesion to water insoluble hydrocarbons, in which results a higher hydrocarbon biodegradation. Consequently as the hydrophobicity of a cell surface increases; the microorganism tendency to bond with the hydrocarbon molecule enhances. The presence of a surface active agent, as an instance a chemical surfactant, will affect the...