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Storage of Information in Chemical Compounds
, M.Sc. Thesis Sharif University of Technology ; Shafiee, Afshin (Supervisor)
Abstract
Regarding the notable progress in communication and competition theories as well as natural sciences, the study of the concepts of information has displayed more attention in recent years.Information, entropy and energy are interrelated concepts. In one hand one can infer that entropy is a quantitation measure of information and on the other hand systems which carry information can accumulated energy.Here, we are going to survey the qualitation as well as quantitation aspects of information with concentration on the behavior of chemical agents as information processors
Effect of Chemical Composition on Atomic Structure and Mechanical Properties of Mg-Zn Glass Alloys Using Molecular Dynamics Simulation
, M.Sc. Thesis Sharif University of Technology ; Tavakoli, Rohollah (Supervisor)
Abstract
In this research, Mg-Zn bulk metallic glasses have been investigated using molecular dynamics simulation. In order to study the structure of this alloy, coordination number, short and medium order of chemical range, Voronoi analysis, glass conversion temperature and atomic pair distribution function have been used. According to the results, the full icosahedral structure with IS connection type in comparison with other structures has an essential role in the stability of the system during cooling and creating medium-scale areas. The results show that the ability to form glass depends on the chemical composition and cooling rate. In this research, the cooling rate is considered to be 1011 K/s...
Estimation of the Compressive Strength of GGBFS based Alkali-Activated Concrete
, M.Sc. Thesis Sharif University of Technology ; Toufigh, Vahab (Supervisor)
Abstract
Ground granulated blast furnace slag (GGBFS) based alkali-activated concrete (GAAC) is one of the eco-friendly alternatives of traditional concrete, which uses industrial byproducts instead of ordinary Portland cement (OPC). Besides environmental benefits, substituting OPC concrete with GAAC has some economic advantages, while it successfully meets the concrete structural requirements in both mechanical and durability characteristics. Despite this fact, employing GAAC in the construction industry has been limited due to a lack of standard mix design code.This study aims to develop an accurate prediction model for the compressive strength of GAAC by employing the most appropriate machine...
Investigation of photocatalytic performance of TiO2 network and fiber geometries
, Article Desalination and Water Treatment ; Volume 57, Issue 50 , 2016 , Pages 23644-23650 ; 19443994 (ISSN) ; Sadrnezhaad, S. K ; Kheilnejad, A ; Sharif University of Technology
Taylor and Francis Inc
2016
Abstract
In typical photocatalytic processes slurry reactors are used in which catalyst particles have to be separated from the solution after the process ends which means much higher time and costs. Hence, immobilizing process is carried out on the catalyst to overcome this problem. In this work, fiber and network geometries were produced by particle precipitation on substrates. The obtained structures were characterized by XRD, SEM, and Brunauer–Emmett–Teller analyses. Photocatalytic performance of the samples was investigated by methyl orange degradation and also by hydrogen generation from water/methanol splitting. From the SEM images, the size range of the TiO2 particles in the network...
Facile one-pot synthesis of polytypic (wurtzite–chalcopyrite) CuGaS2
, Article Applied Physics A: Materials Science and Processing ; Volume 122, Issue 3 , 2016 , Pages 1-10 ; 09478396 (ISSN) ; Mirkazemi, S. M ; Tahir, M. N ; Iraji Zad, A ; Ghasemzadeh, R ; Tremel, W ; Sharif University of Technology
Springer Verlag
2016
Abstract
Abstract: In this investigation, monodisperse CuGaS2 nanoparticles intended for use as visible-light-absorbing materials were synthesized using a facile one-step heating method that involved dissolving the precursors copper chloride, gallium acetylacetonate, and thiourea in a solvent consisting of either oleylamine alone or a combination of oleylamine, oleic acid, and 1-octadecene. The shapes of the resulting nanoparticles were either elongated, polygonal, or a mixture of both, depending on whether the crystal structure of the nanoparticles was predominantly wurtzite, predominantly chalcopyrite, or a more balanced mixture of both wurtzite and chalcopyrite (i.e., the nanoparticles were...
MCM-41-SO3H as an efficient reusable nano-ordered heterogeneous catalyst for the synthesis of divers 1- & 5-substituted 1H-tetrazoles
, Article Scientia Iranica ; Volume 26, Issue 3 C , 2019 , Pages 1463-1473 ; 10263098 (ISSN) ; Eslami, M ; Ghadirian, N ; Sharif University of Technology
Sharif University of Technology
2019
Abstract
An improved and efficient method for the synthesis of 1- & 5-substituted 1Htetrazole derivatives was described in the presence of nano-ordered MCM-41-SO3H as an effective heterogeneous catalyst. This metal-free protocol, [2 + 3] cycloaddition of sodium azide to various nitriles or ethyl N-phenyl formimidate intermediate under mild reaction conditions, provides a wide range of 1H-tetrazoles in good to excellent yields. The catalyst was reused five times without significant loss of catalytic activity. © 2019 Sharif University of Technology. All rights reserved
MCM-41-SO3H as an efficient reusable nano-ordered heterogeneous catalyst for the synthesis of divers 1- & 5-substituted 1H-tetrazoles
, Article Scientia Iranica ; Volume 26, Issue 3 C , 2019 , Pages 1463-1473 ; 10263098 (ISSN) ; Eslami, M ; Ghadirian, N ; Sharif University of Technology
Sharif University of Technology
2019
Abstract
An improved and efficient method for the synthesis of 1- & 5-substituted 1Htetrazole derivatives was described in the presence of nano-ordered MCM-41-SO3H as an effective heterogeneous catalyst. This metal-free protocol, [2 + 3] cycloaddition of sodium azide to various nitriles or ethyl N-phenyl formimidate intermediate under mild reaction conditions, provides a wide range of 1H-tetrazoles in good to excellent yields. The catalyst was reused five times without significant loss of catalytic activity. © 2019 Sharif University of Technology. All rights reserved
Terahertz time domain spectroscopy for mixture detection: A quantitative study
, Article 4th International Conference on Millimeter-Wave and Terahertz Technologies, MMWaTT 2016, 20 December 2016 through 22 December 2016 ; 2017 , Pages 17-19 ; 21570965 (ISSN); 9781509054145 (ISBN) ; Yahyaei, B ; Kouhanestani, M. K ; Mousavi, M ; Darbani, M. R ; Majde, A. E ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2017
Abstract
Terahertz spectroscopy is a useful and an efficient method for detection of pure materials and also mixture compounds. In the present study the terahertz spectra of the α-lactose, high explosives RDX and also the binary mixture of mentioned materials has been obtained in the transition mode. The obtained spectra of the pure materials were in a very good agreement with literatures in the range of 0.1 to 1.5 terahertz. The spectra of mixture samples which show the specific fingerprint characters of each component, declare that terahertz spectroscopy can be used effectively for the detection of explosives and chemical compounds even in the mixture samples. © 2016 IEEE
Supercritical synthesis and in situ deposition of PbS nanocrystals with oleic acid passivation for quantum dot solar cells
, Article Materials Chemistry and Physics ; Volume 156 , 2015 , Pages 163-169 ; 02540584 (ISSN) ; Simchi, A ; Aashuri, H ; Sharif University of Technology
Elsevier Ltd
2015
Abstract
Colloidal quantum dot solar cells have recently attracted significant attention due to their low-processing cost and surging photovoltaic performance. In this paper, a novel, reproducible, and simple solution-based process based on supercritical fluid toluene is presented for in situ growth and deposition PbS nanocrystals with oleic-acid passivation. A lead precursor containing sulfur was mixed with oleic acid in toluene and processed in a supercritical fluid condition at different temperatures of 140, 270 and 330 °C for 20 min. The quantum dots were deposited on a fluorine-doped tin oxide glass substrate inside the supercritical reactor. Transmission electron microscopy, X-ray diffraction,...
Superhydrophobic surfaces with a dual-layer micro- and nanoparticle coating for drag reduction
, Article Energy ; Volume 125 , 2017 , Pages 1-10 ; 03605442 (ISSN) ; Moosavi, A ; Nouri Borujerdi, A ; Daeian, M. A ; Vafaeinejad, S ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
We propose a facile and cost effective method for fabricating superhydrophobic surfaces with significant drag reduction in a wide velocity range. A dual structure superhydrophobic aluminum surface with a hydrophobic Al2O3micro- and nanoparticle coating and also another superhydrophobic surface with a nanoparticle layer coating are fabricated. Then, the resulted drag from each of these surfaces is measured carefully in different velocities and compared with the drag of the as-received aluminum surface. Our results reveal that the surface with the dual structure experiences drag reduction in a wider velocity range compared with the nanoparticle coated sample. Drag reduction of the dual...
Aqueous-phase reforming of glycerol for production of alkanes over Ni/CexZr1-xO2 nano-catalyst: Effects of the support's composition
, Article Renewable Energy ; Volume 108 , 2017 , Pages 417-424 ; 09601481 (ISSN) ; Kazemeini, M ; Larimi, A. S ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
The aqueous phase reforming (APR) reaction of glycerol considered to be environmentally green. It converted polyols into value added products including; H2 and alkanes. Ni species known for its capability of producing alkane-rich gas under the APR process conditions might be utilized for this purpose. In this research, the conversion of glycerol into alkanes demonstrated using 10wt% Ni/CexZr1-xO2 (with x = 0, 0.3, 0.5, 0.7 and 1) catalysts. In order to better understand the behavior of these materials, they were evaluated physio-chemically through the; XRD, BET, H2-TPR, H2-Chemisorption and TEM analyses. Moreover; performances of the synthesized materials were determined through their...
Seasonal trends, chemical speciation and source apportionment of fine PM in Tehran
, Article Atmospheric Environment ; Volume 153 , 2017 , Pages 70-82 ; 13522310 (ISSN) ; Hosseini, V ; Zare Shahne, M ; Bigdeli, M ; Lai, A ; Schauer, J. J ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
Frequent air pollution episodes have been reported for Tehran, Iran, mainly because of critically high levels of fine particulate matter (PM2.5). The composition and sources of these particles are poorly known, so this study aims to identify the major components and heavy metals in PM2.5along with their seasonal trends and associated sources. 24-hour PM2.5samples were collected at a main residential station every 6 days for a full year from February 2014 to February 2015. The samples were analyzed for ions, organic carbon (including water-soluble and insoluble portions), elemental carbon (EC), and all detectable elements. The dominant mass components, which were determined by means of...
Effects of physicochemical characteristics of magnetically recoverable biocatalysts upon fatty acid methyl esters synthesis from oils
, Article Renewable Energy ; Volume 116 , 2018 , Pages 613-622 ; 09601481 (ISSN) ; Kazemeini, M ; Singh, G ; Arpanaei, A ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
This study reports the importance of physicochemical characteristics of the core-shell structured polymer-coated Fe3O4 cluster@SiO2 nanocomposite particles for designing the biocatalysts used for transesterification of soybean oil. To demonstrate this issue, two different types of polymer molecules such as polyethylenimine (PEI) and polyacrylic acid (PAA) each with two different molecular weights are employed. The highest fatty acid methyl esters (FAMEs) synthesis yield values are achieved by the lipases immobilized onto the low- and high-molecular-weight PEI-coated particles as compared to those of the low- and high-molecular-weight PAA-coated particles (i.e., ∼64.8% and ∼73.1% versus...
A theoretical investigation into the effects of functionalized graphene nanosheets on dimethyl sulfoxide separation
, Article Chemosphere ; Volume 297 , 2022 ; 00456535 (ISSN) ; Alizadeh, M ; Hasanzadeh, A ; Khataee, A ; Azamat, J ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
The potential of carbon-based nanosheet membranes with functionalized pores is great as water treatment membranes. Using the molecular dynamic simulation technique, the dimethyl sulfoxide (DMSO) separation from the water/DMSO binary solution is investigated, and the functionalized graphene nanosheets are used as a membrane. This membrane was functionalized by –F (fluorine) and –H (hydrogen) functional groups. For the separation of DMSO, external hydrostatic pressures up to 100 MPa were applied to the considered systems. The separation mechanism was based on molecular size. Multiple analyses were done to study the capability of considered membranes for the separation of DMSO molecules from...
Biocatalysts in microbial electrolysis cells: A review
, Article International Journal of Hydrogen Energy ; Volume 41, Issue 3 , 2016 , Pages 1477-1493 ; 03603199 (ISSN) ; Mardanpour, M. M ; Yaghmaei, S ; Sharif University of Technology
Elsevier Ltd
Abstract
Microbial electrolysis cells (MECs) are bioelectrochemical reactors in which chemical energy stored in organic compounds are converted to hydrogen through biocatalytic oxidation by microorganisms. The performance of MECs is highly affected by microbial communities that are impartible parts of this technology. A better understanding of microbial interactions and competitions mechanisms, has aided the comprehension of ideas and guidelines for cost effective commercial scales design. In this study, a comprehensive review of current knowledge in the microbial characterization, enrichment, and evaluation of effective parameters of microbial community in microbial electrolysis cells for typical...
Double network hydrogel of sodium alginate/polyacrylamide cross-linked with POSS: Swelling, dye removal and mechanical properties
, Article International Journal of Biological Macromolecules ; Volume 129 , 2019 , Pages 187-197 ; 01418130 (ISSN) ; Akbari, A ; Eftekhari Sis, B ; Sharif University of Technology
Elsevier B.V
2019
Abstract
In this work, for the first time, we presented a novel design strategy to fabricate a new type of Octa-aminopropyl polyhedral oligomeric silsesquioxane hydrochloride salt (OA-POSS)-based Alg/PAAm DN gels, consisting of PAAm gel as the first chemical network and Alg/OA-POSS gel as the second chemical-physical network. Incorporation of OA-POSS nanoparticles with various feed ratio into the second network not only led to form strong coordination interactions but also in comparison to the other Alg/PAAm gels demonstrated superior mechanical properties. pH, temperature, contact time and salt effects parameters were studied on the swelling and dye removal properties of the synthesized DN hybrid...
Injectable in situ forming kartogenin-loaded chitosan hydrogel with tunable rheological properties for cartilage tissue engineering
, Article Colloids and Surfaces B: Biointerfaces ; Volume 192 , 2020 ; Chen, Y ; Wang, D ; Bagheri, R ; Solouk, A ; Wu, H ; Sharif University of Technology
Elsevier B.V
2020
Abstract
Limited regeneration capacity of cartilage can be addressed by tissue engineering approaches including localized delivery of bioactive agents using biomaterials. Although chitosan hydrogels have been considered as appropriate candidates for these purposes, however, their poor mechanical properties limit their real applications. Here, we develop in situ forming chitosan hydrogels with enhanced shear modulus by chemical modification of chitosan using N-(β-maleimidopropyloxy) succinimide ester (BMPS). Moreover, we utilize β-Glycerophosphate (β-GP) in the hydrogels for achieving thermosensitivity. We investigate the effects of BMPS, β-GP and chitosan concentration on rheological and swelling...
Encapsulation of spinel CuCo2O4 hollow sphere in V2O5-decorated graphitic carbon nitride as high-efficiency double Z-type nanocomposite for levofloxacin photodegradation
, Article Journal of Hazardous Materials ; Volume 423 , 2022 ; 03043894 (ISSN) ; Shokri, A ; Moradi, M ; Kakavandi, B ; Rahman Setayesh, S ; Sharif University of Technology
Elsevier B.V
2022
Abstract
In this study, spinel CuCo2O4 (CCO) with a hierarchical hollow sphere morphology was encapsulated in V2O5-decorated ultra-wrinkled graphitic carbon-nitride (VO-UCN) for the first time via a facile glycerol-assisted solvothermal method in the interest of developing a novel high-efficiency double Z-type nano-photocatalyst (denoted as VO-UCN@CCO). The remarkable physicochemical features of the as-prepared nano-photocatalysts were verified using diverse characterization techniques including TGA, XRD, FT-IR, FE-SEM, TEM, BET, UV–vis DRS, PL, EIS, and transient photocurrent techniques. Herein, VO-UCN@CCO nanocomposite was employed for the photodisintegration of levofloxacin (LVOF) antibiotic under...
Green products from herbal medicine wastes by subcritical water treatment
, Article Journal of Hazardous Materials ; Volume 424 , 2022 ; 03043894 (ISSN) ; Tavakoli, O ; Sarkhanpour, R ; Sajadi, S. M ; Zarrintaj, P ; Rabiee, N ; Akhavan, O ; Lima, E. C ; Saeb, M. R ; Sharif University of Technology
Elsevier B.V
2022
Abstract
Herbal medicine wastes (HMWs) are byproducts of medicine factories, which are mainly landfilled for their environmental problems. Only bearing in mind the contamination and concerns caused by the COVID-19 pandemic and environmental emissions, the worth of herbal medicine wastes management and conversion to green products can be understood. In this work, subcritical water treatment was carried out batch-wise in a stainless tube reactor in the pressure range of 0.792–30.0 MPa, varying the temperature (127–327 °C) and time (1–60 min) of extraction. This resulted in new and green material sources, including organic acids, amino acids, and sugars. Amazingly, at very low extraction times (below 5...
Triethylamine removal using biotrickling filter (BTF): effect of height and recirculation liquid rate on BTFs performance
, Article International Journal of Environmental Science and Technology ; Volume 14, Issue 8 , 2017 , Pages 1615-1624 ; 17351472 (ISSN) ; Sotoudeheian, S ; Bayat, R ; Sharif University of Technology
Center for Environmental and Energy Research and Studies
2017
Abstract
This study investigated the removal of triethylamine using a biotrickling filter. The influence of affecting parameters, such as height and recirculation liquid rate (VL) on contaminant removal efficiency, was examined in detail. The results demonstrated that in the constant empty bed residence time (EBRT), when VL was increased, the removal efficiency (RE) increased. Also, for a specific VL, increasing EBRT could also increase RE values. However, it seems that an increasing VL is a more cost-effective way to enhance RE as compared to an increasing EBRT. The obtained outcomes represented that for a constant EBRT, an increase in inlet loading (IL) could decrease RE. For lower ILs, the removal...