Synthesis of Transition Metal Nanocatalysts (Pd, Ni, Co) and Their Application in Regioselective Carbon-carbon and Carbon-heteroatom Bond Formation, Ph.D. Dissertation Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
Due to many vast application of C-C bond formation in the areas including bioactive compounds and natural products, over the past few years, the C-C coupling reactions have become a versatile tool in organic synthesis.First, a two-metal catalyst (CoFe2O4) was synthesized and its catalytic activity was evaluated in unsymmetrical thioether synthesis which offered an odorless, ligand-free and aryl halide-free rout for the formation of desired products. The catalyst was recovarable and was able to catalyze the reaction for 10 runs with retention of catalytic activity.In the next step, three-metal catalyst (CoCuFe2O4) was synthesized using the co-precipitation method and characterized.Then, these...
Cataloging briefSynthesis of Transition Metal Nanocatalysts (Pd, Ni, Co) and Their Application in Regioselective Carbon-carbon and Carbon-heteroatom Bond Formation, Ph.D. Dissertation Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
Due to many vast application of C-C bond formation in the areas including bioactive compounds and natural products, over the past few years, the C-C coupling reactions have become a versatile tool in organic synthesis.First, a two-metal catalyst (CoFe2O4) was synthesized and its catalytic activity was evaluated in unsymmetrical thioether synthesis which offered an odorless, ligand-free and aryl halide-free rout for the formation of desired products. The catalyst was recovarable and was able to catalyze the reaction for 10 runs with retention of catalytic activity.In the next step, three-metal catalyst (CoCuFe2O4) was synthesized using the co-precipitation method and characterized.Then, these...
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