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Photocatalytic conversion of methane into methanol over the MoO 3(010) surface using a simulation method

Moshfegh, A. Z ; Sharif University of Technology | 2004

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  1. Type of Document: Article
  2. DOI: 10.1142/S0218625X04005871
  3. Publisher: 2004
  4. Abstract:
  5. In this investigation, we have studied the kinetics and mechanism of photocatalytic conversion of methane into methanol reaction over the MoO 3(010) surface using a computer simulation method. Methane and oxygen as the reactants are used at room temperature and atmospheric pressure under UV photoirradiation of the catalyst. According to our data analysis, the order of methanol formation reaction with respect to CH4 and O 2 was determined to be l = 0.30 and m = -1.03, respectively. The highest methanol formation rate (TOF) value was obtained at about 0.05 molecule/s.site in a range of 25-35 W/cm2 incident light intensity with energy hv ≥ Eg. The selectivity of CH3OH was increased with increasing partial pressure of CH4, while the selectivity of CHOH was decreased. The effect of light intensity on the CH3OH selectivity was also studied under different PCH4/PO2 ratios, namely 0.9, 1.5 and 2.6. The highest CH3OH selectivity was obtained at 1.5 ratio
  6. Keywords:
  7. Methane ; Methanol ; MoO3(010) ; Photocatalytic ; Simulation
  8. Source: Surface Review and Letters ; Volume 11, Issue 1 , 2004 , Pages 33-39 ; 0218625X (ISSN)
  9. URL: https://www.worldscientific.com/doi/10.1142/S0218625X04005871