Investigation of Performance and Improvement of the Activity of MOF-based Catalysts in CO Oxidation Reaction, Ph.D. Dissertation Sharif University of Technology ; Ghotbi, Cyrus (Supervisor) ; Karimi Sabet, Javad (Supervisor)
Abstract
Different catalysts have been proposed for CO oxidation reaction and still many researches are performed to obtain a catalyst with high activity and stability. In this study, MOFs of CuBTC, MIL-101(Cr), and NH2-MIL-101(Cr) and active metal of Pd have been selected and their performances have been investigated in CO oxidation reaction. MOFs have been synthesized by hydrothermal method. Pd loading has been performed by impregnation method in various pH and in aqeous palladium nitrate solution and palladium nitrate solution in nitric acid. To reveal the effect of the nature of noble metal, activity of 1% Pt/MIL has been investigated. Amine-functionalized MIL-101(Cr) has been synthesized by...
Cataloging briefInvestigation of Performance and Improvement of the Activity of MOF-based Catalysts in CO Oxidation Reaction, Ph.D. Dissertation Sharif University of Technology ; Ghotbi, Cyrus (Supervisor) ; Karimi Sabet, Javad (Supervisor)
Abstract
Different catalysts have been proposed for CO oxidation reaction and still many researches are performed to obtain a catalyst with high activity and stability. In this study, MOFs of CuBTC, MIL-101(Cr), and NH2-MIL-101(Cr) and active metal of Pd have been selected and their performances have been investigated in CO oxidation reaction. MOFs have been synthesized by hydrothermal method. Pd loading has been performed by impregnation method in various pH and in aqeous palladium nitrate solution and palladium nitrate solution in nitric acid. To reveal the effect of the nature of noble metal, activity of 1% Pt/MIL has been investigated. Amine-functionalized MIL-101(Cr) has been synthesized by...
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