An Investigation on the Pulse Electrodeposition of Ni-TiO2/TiO2 Multilayer Structures, Ph.D. Dissertation Sharif University of Technology ; Dolati, Abolghasem (Supervisor) ; Ghorbani, Mohammad (Supervisor)
Abstract
Electrocodeposition of Ni-TiO2 nanocomposite single layers and Ni-TiO2/TiO2 multilayers from Watts bath containing TiO2 sol has been carried out on copper substrate. Cyclic voltammetry and chronoamperometry techniques were applied to study the influence of nickel sulfate and TiO2 sol concentrations on the electrochemical behavior of Ni-TiO2 deposition by direct current. The results clearly showed that at lower sulfate concentrations, the electrodepostion is a diffusion controlled process. Besides, the nucleation mechanism of the nanocomposites at low overpotentials followed the progressive system while at higher overpotentials, it was found to be instantaneous with three-dimensional growth...
Cataloging briefAn Investigation on the Pulse Electrodeposition of Ni-TiO2/TiO2 Multilayer Structures, Ph.D. Dissertation Sharif University of Technology ; Dolati, Abolghasem (Supervisor) ; Ghorbani, Mohammad (Supervisor)
Abstract
Electrocodeposition of Ni-TiO2 nanocomposite single layers and Ni-TiO2/TiO2 multilayers from Watts bath containing TiO2 sol has been carried out on copper substrate. Cyclic voltammetry and chronoamperometry techniques were applied to study the influence of nickel sulfate and TiO2 sol concentrations on the electrochemical behavior of Ni-TiO2 deposition by direct current. The results clearly showed that at lower sulfate concentrations, the electrodepostion is a diffusion controlled process. Besides, the nucleation mechanism of the nanocomposites at low overpotentials followed the progressive system while at higher overpotentials, it was found to be instantaneous with three-dimensional growth...
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