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water-in-oil-emulsion
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Investigation of the IFT Behavior of Foamy Oil or Water in Oil Emulsions at Reservoir Condition in Water Based EOR Techniques
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabedin (Supervisor) ; Taghikhani, Vahid (Supervisor)
Abstract
Foamy oil reservoirs and reservoirs which have water in oil emulsions have some difficulties through production with water based enhanced oil recovery techniques. Study of IFT of these oils may improve production of these reservoirs, especially for water based techniques which are most popular techniques. In this study, IFT of these oils were studied in reservoir condition. Effects of pressure, temperature and water composition were investigated. These effects were studied through Pendant drop technique and VIT apparatus
Experimental Study and Modeling of Rheological Behavior of Crude Oils and W/O Emulsions in the Presence of Surfactants
,
M.Sc. Thesis
Sharif University of Technology
;
Ramazani Saadatabadi, Ahmad
(Supervisor)
;
Taghikhani, Vahid
(Supervisor)
;
Ghotbi, Cyrus
(Supervisor)
Abstract
Understanding the properties of crude oil and the phenomena arising from this precious matter has always been of considerable importance. One of these important phenomena is emulsion, which is well-known in a great number of crude oil-related processes such as drilling, well completion, production, transportation and even the processing units in the refinery. One of the most important properties of crude oils and their emulsions is their flow or in other words their rheology. Therefore, in this project has also been tried to investigate the rheological behavior of crude oil and water in crude oil emulsion, experimentally and theoretically. The experiments were carried out using two crude...
Transport of Water/Foamy Oil Emulsion in Poruos Media
, M.Sc. Thesis Sharif University of Technology ; Massihi, Mohsen (Supervisor) ; Ayatollahi, Shahaboddin (Supervisor)
Abstract
Water in oil emulsion usually forms during natural water encroachment or enhanced oil recovery processes due to the reaction between asphaltenic and naphthenic acid part of oil with brine in some heavy oil reservoirs. This results in major production challenges because of high w/o emulsion viscosity which leads to significant pressure drops. Therefore, it is essential to investigate the dominant mechanisms of w/o emulsion flow in porous media to overcome the production challenges. In the present study, w/o emulsion behavior is investigated through both static and dynamic tests. The w/o emulsion was prepared through mixing of a crude with brine using magnet stirrer. Emulsion stability...
Investigation of Formation Damage and its Remediation Caused by Wellbore Fluids by Using Micromodel
, M.Sc. Thesis Sharif University of Technology ; Mahani, Hassan (Supervisor)
Abstract
Various methods have been developed to improve the production capacity of hydrocarbon wells, one of the most successful method is hydraulic fracture. This method, despite improving well production and increasing production levels in a reservoir, causes secondary damages such as water blockage, which is a result of the leakage of fracturing fluid into the fracture matrix and the deformation of the reservoir. This damage can reduce the production rate of a well. Studies prior to this study have mainly examined the damages caused by the leakage of fracturing fluids on a core scale. In most of these studies, damages has been studied only by measuring the pressure and changes in the permeability...
The effect of dispersed phase salinity on water-in-oil emulsion flow performance: A micromodel study
, Article Industrial and Engineering Chemistry Research ; Volume 56, Issue 15 , 2017 , Pages 4549-4561 ; 08885885 (ISSN) ; Ayatollahi, S ; Rezaei, N ; Masihi, M ; Sharif University of Technology
American Chemical Society
2017
Abstract
In this work, the effect of brine salinity on water-in-oil emulsion flow performance in porous media is studied as it imposes a significant challenge to oil production in the petroleum industry. A crude oil sample from an Iranian oilfield and synthetic brine with different salinities (40-140 g/L salt) are used. The results show that the emulsion viscosity and interfacial tension increase slightly with salinity, while they do not considerably affect the flow behavior. The emulsion stability analysis shows that larger w/o emulsion droplets are formed for higher brine salinity, which potentially block more pore spaces through straining and interception mechanisms. This phenomenon resulted in...
Microscopic Investigation of the Effect of Low Salinity Waterflooding on Asphaltene Precipitation and Deposition Using Microfluidic Method
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahabodin (Supervisor) ; Mahani, Hassan (Supervisor)
Abstract
Water injection, as one of the conventional methods to increase the oil recovery factor has always been at the center of research works for Enhanced Oil Recovery (EOR). The conducted studies show that by controlling the amount and type of ions in the injected water, the recovery efficiency can be improved. In the meantime, most of the investigations are focused on the interaction between water/rock/oil to trace the wettability alteration. However, these interactions especially between the injected water and the oil phase, would lead to change of surface charge distribution of the reservoir rock. Besides, this effect can change some of the characteristics of the fluid phases, especially in...
The effect of brine salinity on water-in-oil emulsion stability through droplet size distribution analysis: A case study
, Article Journal of Dispersion Science and Technology ; 2017 , Pages 1-13 ; 01932691 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Abstract
Water-in-oil emulsion usually forms during waterflooding in some heavy oil reservoirs. The composition and salinity of the injected water critically affect the w/o emulsion droplet size distribution, which control the emulsion stability and emulsion flow in porous media. The aim of the present work is to assess the effect of different sea water salinities on w/o emulsion stability through microscopic imaging. Therefore, w/o emulsions were prepared with different sea water samples, which were synthesized to resemble Persian Gulf, Mediterranean, Red Sea, and North Sea water samples. The results showed that log-normal distribution function predicts very well the experimental data to track the...
The effect of brine salinity on water-in-oil emulsion stability through droplet size distribution analysis: a case study
, Article Journal of Dispersion Science and Technology ; Volume 39, Issue 5 , 2018 , Pages 721-733 ; 01932691 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Taylor and Francis Inc
2018
Abstract
Water-in-oil emulsion usually forms during waterflooding in some heavy oil reservoirs. The composition and salinity of the injected water critically affect the w/o emulsion droplet size distribution, which control the emulsion stability and emulsion flow in porous media. The aim of the present work is to assess the effect of different sea water salinities on w/o emulsion stability through microscopic imaging. Therefore, w/o emulsions were prepared with different sea water samples, which were synthesized to resemble Persian Gulf, Mediterranean, Red Sea, and North Sea water samples. The results showed that log-normal distribution function predicts very well the experimental data to track the...
A mechanistic understanding of the water-in-heavy oil emulsion viscosity variation: effect of asphaltene and wax migration
, Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 608 , 2021 ; 09277757 (ISSN) ; Hemmati, M ; Safari, M ; Rahimi, A ; Rahmani, O ; Aminpour, S. M ; Beiranvand Pour, A ; Sharif University of Technology
Elsevier B.V
2021
Abstract
The role of emulsions as a prevalent phenomenon is broadly investigated in the petroleum industry since forming the emulsion has many severe harmful implications. Heavy components of crude oil such as wax and asphaltene make the water-in-oil (w/o) emulsion more stable, while the role of these components on the emulsion viscosity has not been fully understood. In this regard, to find a proper demulsifier to break these emulsions, it is necessary to know the mechanisms of emulsion formation by heavy oil components. In this study, the effects of waxy-oil and asphaltenic-oil on w/o emulsion were investigated by measuring volume and viscosity of the formed emulsion after an elapsed time, followed...
Experimental investigation of rheological and morphological properties of water in crude oil emulsions stabilized by a lipophilic surfactant
, Article Journal of Dispersion Science and Technology ; Volume 34, Issue 3 , Feb , 2013 , Pages 356-368 ; 01932691 (ISSN) ; Ramazani, S. A. A ; Taghikhani, V ; Ghotbi, C ; Sharif University of Technology
2013
Abstract
Rheological behavior of two crude oils and their surfactant-stabilized emulsions with initial droplet sizes ranging from 0.5 to 75 μm were investigated at various temperatures under steady and dynamic shear testing conditions. In order to evaluate the morphology and Stability of emulsions, microscopic analysis was carried out over three months and average diameter and size distribution of dispersed droplets were determined. The water content and surfactant concentration ranged from 10 to 60% vol/vol and 0.1 to 10% wt/vol, respectively. The results indicated that the rheological properties and the physical structure and stability of emulsions were significantly influenced by the water content...
Contribution of water-in-oil emulsion formation and pressure fluctuations to low salinity waterflooding of asphaltic oils: A pore-scale perspective
, Article Journal of Petroleum Science and Engineering ; Volume 203 , 2021 ; 09204105 (ISSN) ; Sakhaei, Z ; Salehinezhad, R ; Mahani, H ; Riazi, M ; Sharif University of Technology
Elsevier B.V
2021
Abstract
During the low salinity waterflooding (LSWF) of a viscous asphaltic oil reservoir, fluid-fluid interactions have a large influence on the fluid flow, pore-scale events, and thus oil recovery efficiency and behavior. In-situ water-in-oil (W/O) emulsion formation is a consequence of crude oil and brine interfacial activities. Despite the published studies, the pore-scale mechanisms of W/O emulsion formation and the role of injected brine salinity, injection rate, and pore-scale heterogeneity on emulsion formation and stability requires a deeper understanding. To address these, a series of static and dynamic micro-scale experiments were performed. The salinity dependent oil-brine interactions...