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    Correlation of viscosity of aqueous solutions of alkanolamine mixtures based on the Eyring's theory and Wong-Sandler mixing rule

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 32, Issue 2 , 2013 , Pages 9-17 ; 10219986 (ISSN) Ahmad Kelayeh, S ; Ghotbi, C ; Taghikhani, V ; Jalili, A ; Sharif University of Technology
    2013
    Abstract
    A viscosity model, based on Eyring's absolute rate theory combined with a cubic PR equation of state and Wong-Sandler mixing rule, has been proposed in order to correlate viscosities of aqueous solutions of alkanolamine mixtures at atmospheric pressure and different temperatures. In the proposed method, the energy and size parameters in studied Equation of State (EoS) have been obtained using the Wong - Sandler (WS) mixing rule combined with the NRTL and Wilson Gibbs equations. The NRTL and Wilson parameters for aqueous solutions of alkanolamine mixtures have been correlated using measured viscosity data at atmospheric pressure and different temperatures. The overall average deviation... 

    Reservoir oil viscosity determination using a rigorous approach

    , Article Fuel ; Vol. 116, issue , 2014 , p. 39-48 Hemmati-Sarapardeh, A ; Shokrollahi, A ; Tatar, A ; Gharagheizi, F ; Mohammadi, A. H ; Naseri, A ; Sharif University of Technology
    Abstract
    Viscosity of crude oil is a fundamental factor in simulating reservoirs, forecasting production as well as planning thermal enhanced oil recovery methods which make its accurate determination necessary. Experimental determination of reservoir oil viscosity is costly and time consuming. Hence, searching for quick and accurate determination of reservoir oil viscosity is inevitable. The objective of this study is to present a reliable, and predictive model namely, Least-Squares Support Vector Machine (LSSVM) to predict reservoir oil viscosity. To this end, three LSSVM models have been developed for prediction of reservoir oil viscosity in the three regions including, under-saturated, saturated... 

    Fast spectral solutions of the double-gyre problem in a turbulent flow regime

    , Article Applied Mathematical Modelling ; Volume 66 , 2019 , Pages 745-767 ; 0307904X (ISSN) Naghibi, S. E ; Karabasov, S. A ; Jalali, M. A ; Sadati, S. M. H ; Sharif University of Technology
    Elsevier Inc  2019
    Abstract
    Several semi-analytical models are considered for a double-gyre problem in a turbulent flow regime for which a reference fully numerical eddy-resolving solution is obtained. The semi-analytical models correspond to solving the depth-averaged Navier–Stokes equations using the spectral Galerkin approach. The robustness of the linear and Smagorinsky eddy-viscosity models for turbulent diffusion approximation is investigated. To capture essential properties of the double-gyre configuration, such as the integral kinetic energy, the integral angular momentum, and the jet mean-flow distribution, an improved semi-analytical model is suggested that is inspired by the idea of scale decomposition... 

    A mechanistic understanding of the water-in-heavy oil emulsion viscosity variation: effect of asphaltene and wax migration

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 608 , 2021 ; 09277757 (ISSN) Piroozian, A ; Hemmati, M ; Safari, M ; Rahimi, A ; Rahmani, O ; Aminpour, S. M ; Beiranvand Pour, A ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    The role of emulsions as a prevalent phenomenon is broadly investigated in the petroleum industry since forming the emulsion has many severe harmful implications. Heavy components of crude oil such as wax and asphaltene make the water-in-oil (w/o) emulsion more stable, while the role of these components on the emulsion viscosity has not been fully understood. In this regard, to find a proper demulsifier to break these emulsions, it is necessary to know the mechanisms of emulsion formation by heavy oil components. In this study, the effects of waxy-oil and asphaltenic-oil on w/o emulsion were investigated by measuring volume and viscosity of the formed emulsion after an elapsed time, followed...