Sharif Digital Repository

Zirconia Toughened Alumina (ZTA) Nanocomposites were prepared using Nano sized Zirconia (ZrO2) powders doped with 3% mol of yttria (Y 2O3) nanopowders. Diffusion of α-alumina (Al 2O3) nanoparticles as well as yttria into the Zirconia lattice network drives monoclinic - tetragonal martensitic transformation. Zirconia toughened alumina (ZTA) composites containing different amount of partially stabilized Zirconia (PSZ) 5, 10, 15 and 20% mol, were prepared via wet mixing and axial pressing. After sintering at different temperatures,1450, 1550 and 1650 °C, phase change in the samples were monitored. X-ray diffraction patterns showed that at constant composition, tetragonal zirconia was increased... 

Yttria-stabilized tetragonal zirconia polycrystals (Y-TZP) have been widely applied in fixed partial prostheses as well as dental uses i.e. a substructure for crowns. However, Y-TZP has limited applications, which is due to the presence of defects in its microstructure introduced during the manufacturing process. Accordingly, due to Y-TZP limitations, the novel (X)Y-TZP- 20Al2O3-(80-X) SiO2 (X = 65, 70 and 75) ceramic nanocomposites were successfully fabricated via the powder metallurgy method. X-ray diffraction (XRD) patterns of commercial powders showed the stabilization of monoclinic zirconia (ZM) by increasing the silica content. In order to determine the fracture load and micro-bending... 

Depending on the type of dopant metal, many kinds of zircon based pigments are produced and blue vanadium pigment is the most important one of them. In this study, blue zircon ceramic pigments were synthesized from intermediate product, resulting from decomposition of zircon sand with NaOH. In this regard, various amounts of sulfuric acid, water, NH4VO3 as colorant, NaF as mineralizer and extra quartz were added to the prepared Na 2ZrSiO5. Role of quartz was to omit the repercussions of presence of free zirconia in the composition. The main objective of this work is to assess various reactions at different temperatures during blue pigment synthesis. Phase analysis was done by X ray...