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    Development of plasma and/or chemically induced graft co-polymerized electrospun poly(vinylidene fluoride) membranes for solute separation

    , Article Separation and Purification Technology ; Volume 108 , 2013 , Pages 196-204 ; 13835866 (ISSN) Savoji, H ; Rana, D ; Matsuura, T ; Tabe, S ; Feng, C ; Sharif University of Technology
    2013
    Abstract
    Nanofiber membranes were fabricated by electrospinning poly(vinylidene fluoride). The electrospun nanofiber membranes were further modified by grafting of acrylic acid (AA) and methacrylic acid (MAA) over the surfaces of the membranes. Plasma AA graft was attempted only, and the results indicated the partial membrane pore filling with grafted AA. For MAA grafting, chemically induced polymerization using benzoyl peroxide and hydrogen peroxide was attempted. The combination of plasma and chemically induced MAA graft polymerization was also attempted. The membranes were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and static contact angle (SCA)... 

    Performance of sea water dilution on the surface free energies of the crude oils in water-flooded carbonate rock

    , Article Journal of Adhesion Science and Technology ; 2017 , Pages 1-10 ; 01694243 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    Although several investigations have studied the low-salinity water injection (LSWI) performance during the past decades, the effect of crude oil type on the interfacial tension (IFT) and wettability alteration is still in dark. In this regard, this study is aimed to obtain the thermodynamic energies including adhesion, cohesion and spreading coefficient during LSWI. To achieve this goal, IFT and static contact angle values of three different crude oils (i.e. light, medium and heavy) are measured as a function of sea water salinity. The obtained results revealed that the dilution of sea water can change the wettability of reservoir rock from oil wet state towards water wet state, while crude... 

    Application of a water based nanofluid for wettability alteration of sandstone reservoir rocks to preferentially gas wetting condition

    , Article Journal of Molecular Liquids ; Volume 232 , 2017 , Pages 351-360 ; 01677322 (ISSN) Erfani Gahrooei, H. R ; Ghazanfari, M. H ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    Condensate and water banking around gas condensate wells result in vital well deliverability issues. Wettability alteration of near wellbore region to gas wetting condition is known to be the most novel and the only permanent method, to improve condensate well productivity. In this work, a water based nanofluid is used to change the wettability of sandstone reservoir rocks from strongly liquid wetting to intermediate gas wetting condition. Static contact angle measurements demonstrated significant increase of liquid phase contact angle as a result of chemical treatment with SurfaPore M nanofluid. The characteristics of SurfaPore M adsorption on sandstone rock are quantified through kinetic... 

    Performance of sea water dilution on the surface free energies of the crude oils in water-flooded carbonate rock

    , Article Journal of Adhesion Science and Technology ; Volume 32, Issue 12 , 2018 , Pages 1359-1368 ; 01694243 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Taylor and Francis Ltd  2018
    Abstract
    Although several investigations have studied the low-salinity water injection (LSWI) performance during the past decades, the effect of crude oil type on the interfacial tension (IFT) and wettability alteration is still in dark. In this regard, this study is aimed to obtain the thermodynamic energies including adhesion, cohesion and spreading coefficient during LSWI. To achieve this goal, IFT and static contact angle values of three different crude oils (i.e. light, medium and heavy) are measured as a function of sea water salinity. The obtained results revealed that the dilution of sea water can change the wettability of reservoir rock from oil wet state towards water wet state, while crude... 

    Wettability alteration of calcite rock from gas- repellent to gas-wet using a fluorinated nanofluid: A surface analysis study

    , Article Journal of Natural Gas Science and Engineering ; Volume 83 , 2020 Azadi Tabar, M ; Shafiei, Y ; Shayesteh, M ; Dehghan Monfared, A ; Ghazanfari, M. H ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Wettability alteration analysis form gas-repellent to gas-wet with the aid of chemical agents has been subjected of numerous studies. However, fundamental understanding of the effect of surface tension of liquid on repellency strength, the change in the intermolecular forces due to the adsorption of nanoparticles onto the rock surfaces, and exposure of treated rock in brine are not well discussed in the available literature. In this study, X-ray diffraction, Atomic Force Microscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were applied to characterize the treated and fresh samples. Dynamic and static contact angle measurements were then combined with six methods...