Sharif Digital Repository

Coinage metal clusters are of great importance for a wide range of scientific fields, ranging from microscopy to catalysis. Despite their clear fundamental and technological importance, the experimental structural determination of copper clusters has attracted little attention. We fill this gap by elucidating the structure of cationic copper clusters through infrared (IR) photodissociation spectroscopy of Cu n + -Ar m complexes. Structures of Cu n + (n = 3-10) are unambiguously assigned based on the comparison of experimental IR spectra in the 70-280 cm -1 spectral range with spectra calculated using density functional theory. Whereas Cu 3 + and Cu 4 + are planar, starting from n = 5, Cu n +... 

A fully electrically tunable microwave photonic filter is realized by the implementation of delay lines based on frequency-Time conversion. The frequency response and free spectral range (FSR) of the filter can be engineered by a simple electrical tuning of the delay lines. The method has the capability of being integrated on a silicon photonic platform. In the experiment, a 2-Tap tunable microwave photonic filter with a 3-dB bandwidth of 2.55 GHz, a FSR of 4.016 GHz, a FSR maximum tuning range from -354 MHz to 354 MHz and a full FSR translation range is achieved  

Unlike gold and silver, aluminum shows a localized surface plasmon resonance (LSPR) over a wide spectral range from ultraviolet (UV) to the visible region. Herein, we demonstrate a new process to optically couple TiO2 nanotubes (NTs) with a high-strength aluminum substrate, to achieve a synergistic enhancement of photocatalytic antibacterial effects through controlled LSPR of aluminum. The high-strength aluminum substrate was produced by tubular channel angular pressing (TCAP). Their LSPR was tailored through the formation of superficial nano-concave arrays (NCAs) with desired concave diameters. A layer of aligned TiO2 NTs was fabricated on the surface of aluminum nano-concave arrays (Al...