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    Enzymatic and soil burial degradation of corn starch/glycerol/sodium montmorillonite nanocomposites

    , Article Polymers from Renewable Resources ; Volume 11, Issue 1-2 , 2020 , Pages 15-29 Ostadi, H ; Gilak Hakimabadi, S ; Nabavi, F ; Vossoughi, M ; Alemzadeh, I ; Sharif University of Technology
    SAGE Publications Ltd  2020
    Abstract
    In this study, effects of glycerol (10, 20, and 30 wt%) and Sodium Montmorillonite (Na-MMT) (0%, 2.5%, and 5%) contents on the degradation of corn starch polymers were investigated. Films were prepared by casting corn starch solution using a modified method to enhance the nanoclay distribution. Biodegradability studies were performed by enzymatic and burial tests using pristine and enriched soils. The biodegradability of samples in pristine soil was faster, and all samples were fully degraded in 6 months. The effect of nanoparticles on the mass reduction in degradation was more pronounced than that of glycerol. In all glycerol concentrations, Na-MMT addition increased tensile strength. FTIR... 

    Semi-IPN carrageenan-based nanocomposite hydrogels: Synthesis and swelling behavior

    , Article Journal of Applied Polymer Science ; Volume 118, Issue 5 , 2010 , Pages 2989-2997 ; 00218995 (ISSN) Mahdavinia, G. R ; Marandi, G. B ; Pourjavadi, A ; Kiani, G ; Sharif University of Technology
    2010
    Abstract
    Inclusion of nano-clays into hydrogels is an efficient approach to produce nanocomposite hydrogels. The introduction of nano-clay into hydrogels causes an increase in water absorbency. In the present work, Nanocomposite hydro-gels based on kappa-carrageenan were synthesized using sodium montmorillonite as nano-clay. Acrylamide and meth-ylenebisacrylamide were used as monomer and crosslinker, respectively. The structure of nanocomposite hydrogels was investigated by XRD and SEM techniques. Swelling behavior of nanocomposite hydrogels was studied by varying clay and carrageenan contents as well as methylenebisacrylamide concentration. An optimum swelling capacity was achieved at 12% of sodium...