Sharif Digital Repository

We present a new TiO2 morphology, featuring high surface area and open structure, synthesized by a two-step chemical route for the manufacture of dye-sensitized solar cells (DSSCs). This construct is sets of intertwined one-dimensional (1D) nanostructures (i.e., nanotubes), so-called skein-like nanotubes (NTs). Such morphology is produced by a combination of TiC oxidation and hydrothermal processes. The mesoporous TiO2 nanoparticles, as the product of TiC oxidation operation, is used as the precursor of hydrothermal process to grow the skein-like NTs. The effect of processing parameters of TiC oxidation and hydrothermal processes is studied. The skein-like morphology enables to eliminate the... 

Lithium intercalation is a convenient method to prepare few-layer and single-layer MS2 (M=Mo, W) nanosheets. This method is, however, very time-consuming (few days) and it is difficult to control the reaction parameters. To overcome these drawbacks, we have proposed a method to use an Li battery set-up to significantly reduce the reaction time (few hours) and electrochemically intercalate lithium ions into MS2 layers in a controllable manner. Atomic force microscopy (AFM), scanning electron microscopy (SEM) and Raman spectroscopy results revealed that MoS2 and WS2 single-layer (thickness of ~ 1 nm) nanosheets with the 1T phase were prepared after intercalation in an Li battery set-up.... 

Lithium intercalation is a convenient method to prepare few-layer and single-layer MS2 (M=Mo, W) nanosheets. This method is, however, very time-consuming (few days) and it is difficult to control the reaction parameters. To overcome these drawbacks, we have proposed a method to use an Li battery set-up to significantly reduce the reaction time (few hours) and electrochemically intercalate lithium ions into MS2 layers in a controllable manner. Atomic force microscopy (AFM), scanning electron microscopy (SEM) and Raman spectroscopy results revealed that MoS2 and WS2 single-layer (thickness of ~ 1 nm) nanosheets with the 1T phase were prepared after intercalation in an Li battery set-up.... 

Molecular structural mechanics is implemented to model vibrational behavior of defect free single-layered graphene sheets (SLGSs) at constant temperature. To mimic these two-dimensional layers, zigzag and armchair models with cantilever and bridge boundary conditions are adopted. Fundamental frequencies of these nano structures are calculated, and it is perceived that they are independent of the chirality and aspect ratio. Effects of point mass and atomistic dust on the fundamental frequencies are also considered in order to investigate the possibility of using SLGSs as sensors. Results of exhibit the principle frequencies are highly sensitive to the added mass in the order of 10-6fg.... 

A nanoscale logic NOR gate has been theoretically designed by magnetic flux inputs in a Z-shaped graphene nanoribbon composed of an armchair ribbon device sandwiched between two semi-infinite metallic zigzag ribbon leads. The calculations are based on the tight-binding model and iterative Green's function method, in which the conductance as well as current-voltage characteristics of the nanosystem are calculated, numerically. We show that the current and conductance are highly sensitive to both the magnetic fluxes subject to the device and the size of the system. Our results may have important applications for building blocks in the nanoelectronic devices based on graphene nanoribbons  

Molecular structural mechanics is implemented to model the vibrational behavior of defect-free single-layered graphene sheets (SLGSs) at constant temperature. To mimic these two-dimensional layers, zigzag and armchair models with cantilever and bridge boundary conditions are adopted. Fundamental frequencies of these nanostructures are calculated, and it is perceived that they are independent of the chirality and aspect ratio. The effects of point mass and atomistic dust on the fundamental frequencies are also considered in order to investigate the possibility of using SLGSs as sensors. The results show that the principal frequencies are highly sensitive to an added mass of the order of 1 0-... 

Based on the linear fluid-solid interaction (FSI) model and classical shell theories, vibration behavior of sandwich cylindrical shells subjected to external incompressible or compressible fluid flow is investigated. The sandwich shell includes the same outer and inner face sheets made of carbon nanotube (CNT) reinforced composites and a metal foam core. The effective mechanical properties of CNT reinforced composites are obtained using the extended rule of mixture. Also, the porosity distribution through the foam thickness is assumed to be in the form of a trigonometric function. Equations of motion and corresponding boundary conditions are derived according to the Donnell's, Love's and... 

In the previous researches, several theoretical equations were presented for calculation of buildup factor of the single layer shields. Also, the theoretical equations were offered for the two-layered shield that consist of the known materials. For other possible modes of the multi-layered shield, the buildup factor are usually calculated via experimental or simulated data. The purpose of present study is the extraction of the new theoretical equation for the gamma ray buildup factor of three-layered spherical shield made of water, concrete and iron based on the Monte Carlo calculation. To this end, the gamma ray buildup factor of the three-layered spherical shield is calculated via... 

Molecular structural mechanics is implemented to model vibrational behavior of defect free single-layered graphene sheets (SLGSs) at constant temperature. To mimic these two-dimensional layers, zigzag and armchair models with cantilever and bridge boundary conditions are adopted. Fundamental frequencies of these nano structures are calculated, and it is perceived that they are independent of the chirality and aspect ratio. Effects of point mass and atomistic dust on the fundamental frequencies are also considered in order to investigate the possibility of using SLGSs as sensors. Results of exhibit the principle frequencies are highly sensitive to the added mass in the order of 10-6 fg.... 

Within the elasticity formulation the most general displacement field for hygrothermal problems of long laminated composite plates is presented. The equivalent single-layer theories are then employed to determine the global deformation parameters appearing in the displacement fields of general cross-ply, symmetric, and antisymmetric angle-ply laminates under thermal and hygroscopic loadings. Reddy's layerwise theory is subsequently used to determine the local deformation parameters of various displacement fields. An elasticity solution is also developed in order to validate the efficiency and accuracy of the layerwise theory in predicting the interlaminar normal and shear stress... 

We investigate the possibility of frequency conversion in time-varying metasurfaces, composed of graphene microribbon arrays (GMRAs) with time-periodic modulation of their conductivity. We present a quasi-static model for the interaction of light with a temporally modulated metasurface, as well as an accurate analytical treatment of the problem of time-varying GMRAs. Results coming from numerical simulations are also available. We provide corrections to a previous related proposal for frequency conversion and refute the possibility of attaining frequency shifts not equal to an integral multiple of modulation frequency. Contrary to the preceding results, our findings show that efficient... 

Free-edge effects in laminated, circular, cylindrical shell panels subjected to hygrothermal loading are studied by utilizing displacement-based technical theories. Starting from the most general displacement field of elasticity for long, circular, cylindrical shells, appropriate reduced displacement fields are determined for laminated composite shell panels with cross-ply and antisymmetric angle-ply layups. An equivalent single-layer shell theory is used to analytically determine the constant parameters appearing in the reduced displacement fields. A layerwise shell theory is then employed to analytically determine the local displacement functions and the boundary-layer interlaminar... 

In this work, a new structure of single layer armchair graphene nanoribbon field effect transistor with the Stone–Wales (SW) defect (SWGNRFET) is studied. The simulations are solved with Poisson–Schrödinger equation self-consistently by using Non-Equilibrium Green Function (NEGF) and in the real space approach. The energy band structure is obtained by approximation tight-binding method. The results show that displacement of a defect in the width of the channel of the new structure is led to 50% increase in ION/IOFF ratio only by rotating of a C–C (Carbon–Carbon) bond with similar behavior. But, a remarkable increase of 300% in ION/IOFF ratio is obtained by a “dual center” defect. The results... 

In this work, single- and double-layer electromagnetic wave absorbers were prepared by as-prepared MWCNTs/BaTiO3/pitted carbonyl iron composites. MWCNT/BaTiO3 (MW/BTO) was prepared via sol-gel method whereas the carbonyl iron particles (CI) were corroded via pitting corrosion method. The structural, microstructural, magnetic and microwave absorption properties of the composites were evaluated via X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) methods. CST studio software was employed to simulate the microwave absorption characteristics of double-layer absorbers. Moreover, the effects of... 

Background: Titanium (Ti) implants are commonly coated with hydroxyapatite (HA). However, HA has some disadvantages such as brittleness, low tensile strength and fracture toughness. It is desirable to combine the excellent mechanical properties of ZrO 2 and the chemical inertness of Al 2O 3 with respect to the purpose of this project which was coating Ti implants with HA-ZrO 2-Al 2O 3 to modify the surface of these implants by adding ZrO 2 and Al 2O 3 to HA. The purpose of this study was to evaluate the efficacy of hydroxyapatite coating nonocomposite. Methods: From September 2009 to January2011, functionally graded HA-Al 2O 3-ZrO 2 and HA coatings were applied on Ti samples. HA-Al 2O 3-ZrO... 

The nonlinear vibrational properties of single layer graphene sheets (SLGSs) are investigated using a membrane model. The nonlinear equation of motion is considered for the SLGSs by including the effects of stretching due to large amplitudes. The equation of motion is numerically solved utilizing the finite difference method for SLGSs with different initial and boundary conditions, sizes and pretensions. It is concluded that the nonlinear fundamental frequency of SLGSs increases by increasing the pretension and initial velocity. In addition, it is observed that an increase in the pretension weakens the effects of the initial velocity on the fundamental frequency, such that the fundamental...