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    Investigating Wettability Alteration During MEOR Process

    , M.Sc. Thesis Sharif University of Technology Soleymani, Fatemeh (Author) ; Ayatollahi, Shahab (Supervisor) ; Kariminia, Hamid Reza (Supervisor)
    Abstract
    Microbial enhanced oil recovery (MEOR) is a collection of techniques that utilize microorganisms and their metabolic products to improve the recovery of crude oil from reservoir rock. From the advantages of this method, independency to the oil price and environmental benign can be mentioned. Many mechanisms have been proposed to contribute on MEOR, but still there is no enough knowledge about the mechanisms that causes inabilities in manipulating the process to get more oil production.
    In the present study, the effect of a native type of bacteria, Enterobacter cloacae, on the glass surfaces wettability which were aged in expose of model oil with different asphaltene concentration was... 

    Spotlight on kinetic and equilibrium adsorption of a new surfactant onto sandstone minerals: A comparative study

    , Article Journal of the Taiwan Institute of Chemical Engineers ; Volume 50 , May , 2015 , Pages 12-23 ; ISSN: 18761070 Arabloo, M ; Ghazanfari, M. H ; Rashtchian, D ; Sharif University of Technology
    Abstract
    This paper presents a state of the art review of adsorption models for a new plant-based surfactant adsorption onto sandstone minerals. The adsorption data at both kinetic and equilibrium modes were obtained from batch experiments. Four adsorption kinetic models, five two-parameter, and six three-parameter equilibrium models were used for interpretation of the obtained data. Among the two and three-parameter isotherm models applied, the Jovanovic and the Khan isotherms showed the best fit, respectively. And the pseudo-second order model presented a better fit than other kinetic models. Finally, a computer-based modeling approach was developed and used for predicting the kinetics of... 

    Spotlight on kinetic and equilibrium adsorption of a new surfactant onto sandstone minerals: A comparative study

    , Article Journal of the Taiwan Institute of Chemical Engineers ; Volume 50 , May , 2015 , Pages 12-23 ; 18761070 (ISSN) Arabloo, M ; Ghazanfari, M. H ; Rashtchian, D ; Sharif University of Technology
    Taiwan Institute of Chemical Engineers  2015
    Abstract
    This paper presents a state of the art review of adsorption models for a new plant-based surfactant adsorption onto sandstone minerals. The adsorption data at both kinetic and equilibrium modes were obtained from batch experiments. Four adsorption kinetic models, five two-parameter, and six three-parameter equilibrium models were used for interpretation of the obtained data. Among the two and three-parameter isotherm models applied, the Jovanovic and the Khan isotherms showed the best fit, respectively. And the pseudo-second order model presented a better fit than other kinetic models. Finally, a computer-based modeling approach was developed and used for predicting the kinetics of... 

    Phase behavior and interfacial tension evaluation of a newly designed surfactant on heavy oil displacement efficiency; effects of salinity, wettability, and capillary pressure

    , Article Fluid Phase Equilibria ; Vol. 396, issue , June , 2015 , p. 20-27 ; ISSN: 03783812 Dehghan, A. A ; Masihi, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    This work aims to discuss the results of wide ranges of laboratory investigations to evaluate the performance of a newly-formulated surfactant for heavy oil reservoirs in order to improve the microscopic sweep efficiency after water flooding processes. In the first part, the specific behavior of the formulated surfactant including its salinity tolerance, interfacial tension, and optimum performance window was determined. Then, the application of surfactant solutions in real sandstone reservoir rocks was assessed for both oil-wet and water-wet cases. Besides, the effect of changing the capillary and viscous forces and interfacial tension on the residual phase saturations were characterized.... 

    Phase behavior and interfacial tension evaluation of a newly designed surfactant on heavy oil displacement efficiency; effects of salinity, wettability, and capillary pressure

    , Article Fluid Phase Equilibria ; Volume 396 , 2015 , Pages 20-27 ; 03783812 (ISSN) Dehghan, A. A ; Masihi, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier  2015
    Abstract
    This work aims to discuss the results of wide ranges of laboratory investigations to evaluate the performance of a newly-formulated surfactant for heavy oil reservoirs in order to improve the microscopic sweep efficiency after water flooding processes. In the first part, the specific behavior of the formulated surfactant including its salinity tolerance, interfacial tension, and optimum performance window was determined. Then, the application of surfactant solutions in real sandstone reservoir rocks was assessed for both oil-wet and water-wet cases. Besides, the effect of changing the capillary and viscous forces and interfacial tension on the residual phase saturations were characterized.... 

    Wettability modification, interfacial tension and adsorption characteristics of a new surfactant: Implications for enhanced oil recovery

    , Article Full ; Volume 185 , 2016 , Pages 199-210 ; 00162361 (ISSN) Arabloo, M ; Ghazanfari, M. H ; Rashtchian, D ; Sharif University of Technology
    Elsevier Ltd  2016
    Abstract
    This paper concerns with the interfacial tension (IFT), wettability modification and adsorption behavior of a new plant-based surface active agent, Zizyphus Spina Christi, onto sandstone minerals which has been rarely attended in the available literature. Both kinetics and equilibrium adsorption data were obtained from batch mode tests. It was revealed that Freundlich isotherms matched better fit to the equilibrium data which implied that multilayer coverage of Zizyphus Spina Christi onto the sandstone particle surfaces was more likely to occur. Analysis of experimental kinetic data based on intraparticle diffusion model disclosed that the intraparticle diffusion mechanism is not the only... 

    Toward a hydrocarbon-based chemical for wettability alteration of reservoir rocks to gas wetting condition: implications to gas condensate reservoirs

    , Article Journal of Molecular Liquids ; Volume 248 , 2017 , Pages 100-111 ; 01677322 (ISSN) Erfani Gahrooei, H. R ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Recently, wettability alteration has been much attended by researchers for studying well productivity improvement in gas condensate reservoirs. Previous studies in this area only utilized water/alcohol based chemicals for this purpose. While, hydrocarbon nature of the blocked condensate in retrograde gas reservoirs, may motivate application of hydrocarbon based chemical agents. In this study, a new hydrocarbon based wettability modifier is introduced to alter wettability of carbonate and sandstone rocks to preferentially gas wetting condition. Static and dynamic contact angle measurements, spontaneous imbibition and core flooding tests were conducted to investigate the effect of proposed...