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    Organic Pollutants Degradation in Wastewater by Ultraviolet Irradiation Process Using Nano-structured Catalyst in a Batch Reactor

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Shahin (Author) ; Kazemeini, Mohammad (Supervisor) ; Mahmoodi, Niyaz Mohammad (Supervisor) ; Baghalha, Morteza (Supervisor)
    Abstract
    Environmental issues and lack of drinking water had forced researchers to find some alternatives in order to wastewater treatment. Since dyes are used in a variety of industrial application such as textile, pharmaceutical, etc.; therefore, wastewater of these factories makes several environmental problems. Using catalysis under UV- irradiation (photocatalysis) is one of the cases that is used in wastewater treatment which the catalyst stimulated under UV- irradiation and this process degraded dyes. In this work, reactive red 198 degradation is investigated with MIL-53(Fe) and MIL-100(Fe) and in the literature section, the methods that was implemented by other researchers is studied.... 

    Activated carbon/metal-organic framework nanocomposite: Preparation and photocatalytic dye degradation mathematical modeling from wastewater by least squares support vector machine

    , Article Journal of Environmental Management ; Volume 233 , 2019 , Pages 660-672 ; 03014797 (ISSN) Mahmoodi, N. M ; Abdi, J ; Taghizadeh, M ; Taghizadeh, A ; Hayati, B ; Shekarchi, A. A ; Vossoughi, M ; Sharif University of Technology
    Academic Press  2019
    Abstract
    Herein, Kiwi peel activated carbon (AC), Materials Institute Lavoisier (MIL-88B (Fe), and AC/MIL-88B (Fe) composite were synthesized and used as catalysts to degrade Reactive Red 198. The material properties were analyzed by the FTIR, BET-BJH, XRD, FESEM, EDX, TGA, and UV–Vis/DRS. The BET surface area of AC, MIL-88B (Fe) and AC/MIL-88B (Fe) was 1113.3, 150.7, and 199.4 m2/g, respectively. The band gap values (Eg) estimated by Tauc plot method, were obtained 5.06, 4.19 and 3.79 eV for AC, MIL-88B (Fe) and AC/MIL-88B (Fe), respectively. The results indicated that the AC/MIL-88B (Fe) composite had higher photocatalytic activity (99%) than that of pure AC (79%) and MIL-88B (Fe) catalysts (87%).... 

    Preparation of novel and highly active magnetic ternary structures (metal-organic framework/cobalt ferrite/graphene oxide) for effective visible-light-driven photocatalytic and photo-fenton-like degradation of organic contaminants

    , Article Journal of Colloid and Interface Science ; Volume 602 , 2021 , Pages 73-94 ; 00219797 (ISSN) Bagherzadeh, B ; Kazemeini, M ; Mahmoodi, N. M ; Sharif University of Technology
    Academic Press Inc  2021
    Abstract
    Herein, MIL-101(Fe), CoFe2O4, novel binary (MIL-101(Fe)/CoFe2O4, MIL-101(Fe)/GO and CoFe2O4/GO), and ternary (MIL-101(Fe)/CoFe2O4/(3%)GO and MIL-101(Fe)/CoFe2O4/(7%)GO) magnetic composites based upon the MIL-101(Fe) were synthesized. The XRD, FESEM, TEM, EDX, BET-BJH, FTIR, VSM, DRS, PL, EIS and other electrochemical analyses were applied to characterize samples. The MIL/CoFe2O4/(3%)GO demonstrated the best performance compared to other samples for visible light photocatalytic and photo-Fenton-like degradation of Direct Red 23 (DtR-23), Reactive Red 198 (ReR-198) dyes as well as Tetracycline Hydrochloride (TC-H) antibiotic. Degradation of dyes using the ternary composite after 70 min of...