Sharif Digital Repository

Patterns formed by the flow of an inhomogeneous fluid (suspension) over a smooth inclined surface were studied. It was observed that fractal patterns form. There exists a threshold angle for the inclination above which global fractal patterns are formed. This angle depends on the particle size of the suspension. We observed that there are two fractal dimensions for these patterns, depending on the area from which the pattern is extracted. If the pattern is taken from the top which only consists of the beginning steps of the pattern forming, one finds two fractal dimensions, i.e. 1.35-1.45 and 1.6-1.7, in which the first one is dominant while, if the entire pattern is taken, then a fractal... 

This paper is a continuation of our previous paper (part 1; 10.1021/ef401857t), which discussed the roles of different phenomena effecting the deposition of asphaltene from model oil systems and before the onset of asphaltene precipitation. The study in this paper is to understand the depositional tendency of asphaltene using a quartz crystal microbalance with dissipation (QCM-D) measurements and their corresponding modeling for real crude oil systems with emphasis after the onset of asphaltene precipitation  

The influence of deep cryogenic treatment on wear resistance and tool life of M2 HSS drills in high-speed dry drilling configuration of carbon steels was studied. The experimental results indicated 77 and 126% improvement in cryogenic-treated and cryogenic- and temper-treated drill lives, respectively. The results of wear rate test were in agreement with drill life test. Chemical composition of chips were also reported to show the onset of seizure in drilling test and the consequence of seizure in promoting dissolution wear by diffusion mechanism. Wear resistance improvement was mainly attributed to the resistance of cryogenically treated drills against diffusion wear mechanism, due to the... 

The age-hardening behavior and microstructure of selected samples of a Ni-Co alloy were studied using hardness testing, optical microscopy, and scanning and transmission electron microscopy. The final microstructure of the material was found to be sensitive to the temperature of the solution treatment. This approach may be used to optimize the microstructure of the alloy for different applications. © 2007 Acta Materialia Inc  

Fixtured sintering of up to 5 hours at 1223 to 1323 K is successfully used to diminish the dimensional change of NiTi memory alloys produced from mixtures of elemental Ni and Ti powders packed and pressed at room temperature under 400, 500, and 600 MPa pressure. The improvements obtained can help near-net-shape technology via powder metallurgy that overcomes the traditional casting problems such as oxygen, nitrogen, hydrogen, and carbon absorption and intermetallic compound precipitation, which lower the workability and the homogeneity of the final alloy. The effects of compaction pressure, sintering time, and sintering temperature on dimensional change, porosity, hardness, and morphology of... 

In this paper, results of an investigation on strain hardening mechanisms of aged AEREX350 alloy during room temperature compression testing are reported. TEM studies were conducted on commercial samples aged at 850 °C both before and after deformation in a strain range of 0.15-0.27. It was found that only coherent γ′ precipitates with L12 structure formed in these samples prior to deformation. TEM studies also showed twin intersections in the deformed samples. Based on these observations, it is suggested that the high strain hardening rate of the aged material in this strain range is mainly related to the formation of intersecting deformation twins. This is attributed to the decrease in the... 

Among the asphaltene flow assurance issues, the most major concern because of asphaltene is its potential to deposit in reservoir, well tubing, flow lines, separators, and other systems along production lines causing significant production losses. Hence, the focus of this study is to understand the depositional tendency of asphaltene using quartz crystal microbalance with dissipation (QCM-D) measurements. The results are presented in two consecutive papers, with this paper (part 1) dealing with model oil systems. The depositing environment is varied by changing the system temperature, asphaltene polydispersity, solvent (asphaltene stability), depositing surface, and flow rate. This paper... 

The current study proposes a simple constitutive model that integrates the kinetics of precipitation during static aging and the kinetics of precipitate dissolution during preheating to deformation temperature to predict the hot flow behavior of AA6063 alloy. The model relates the flow behavior of the age-hardenable alloy to the alloy chemistry, thermal history as well as deformation temperature, strain, and strain rate by means of a physically based model. Different aging conditions, including supersaturated solid solution and overaging conditions with different deformation parameters, were assessed. Each part of the model was in good agreement with those of experimental and other model... 

The production of robust joints after diffusion brazing necessitates the advanced understanding of phase transformations during the bonding process. This paper aims to investigate the solidification and the solid state precipitation during diffusion brazing of wrought IN718 nickel base superalloy using Ni-15Cr-4B (wt-%) filler alloy. It was found that intermetallics containing eutectic type microconstituents were formed in the joint centreline by solidification which is controlled by segregation behaviour of B and its low solubility in Ni rich solid solution. In addition, extensive Cr-Mo-Nb rich precipitates were formed in the substrate region by solid state precipitation induced by B... 

Highly porous nanocrystalline alumina was synthesized using two different precipitation processes and precipitating agents, which were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and porosimetry analyses. Different precipitating agents yielded nanocrystalline alumina catalysts with different morphologies and textural properties. Batch precipitation using sodium bicarbonate at constant pH resulted in a highly porous nanocrystalline γ-alumina catalyst, having surface area of 351.47 m2 g-1, total pore volume of 1.68 cm3 g -1 and mean pore diameter of 19.17 nm. The mean crystallite size was also determined to be 3.8 nm, based on the XRD results. Catalytic... 

Submicron sized polyacrylamide particles were prepared via modified precipitation polymerization method. Experimental design based on Taguchi approach was employed to study the influence of the polymerization composition including monomer (acrylamide), crosslinker (methylenebisacrylamide), initiator (azobisisobutyronitrile), and modifier (polyvinylpyrrolidone, K-30), on the size and morphology of the particles. Varying the polymerization composition, submicron-particles with sizes ranging between 100 and 600 nm were achieved. In all the cases, polydispersity index (PDI) of the particle size was found to be almost 1 indicating uniformity of the particle size. The concentration of crosslinker... 

A double-layer SnO2/ZnO gas sensor was produced by utilisation of SnOSUB align=right2 and ZnO thin films. Top layer consisted of SnOSUB align=right2 produced by a sol gel-controlled annealing technique. Bottom coating consisted of ZnO thin film precipitated by Two-Stage Chemical Deposition (TSCD) from an aqueous zinc-containing solution. Both top and bottom coatings were analysed by SEM, XRD, EDAX and AAS. Gas sensitivity of the SnO2/ZnO double layer was determined by electrical resistance measurements. Although sensitivity was slightly reduced by double-layer formation, selectivity and stability were considerably improved by combination of the two thin layers. The existence of an... 

One of the methods to increase the hardness of metals, mostly used in aerospace and automobile industries, where light parts with high strength is needed, is precipitation hardening. Nano-precipitates can strongly influence the mechanical properties of materials, especially in a dynamic case. In the present work, attempts have been made so as to make Nano-particles dynamically precipitate in IF steels. Investigating the structure by the means of SEM and AFM resulted in understanding that the precipitates were in nano-size. The micro-hardness of samples was measured as well. © BHR Group 2007 Industrial Processes for Nano and Micro Products  

The evolution of primary and secondary γ′ precipitates in the high γ′ volume fraction Rene 80 Ni based superalloy has been examined during aging at elevated temperatures for periods up to 1750 h. While the increase in average dimension of particles followed the cube rate Lifshitz, Slypzof and Wagner (LSW) law, rt-3-r0 -3=kt, there were significant discrepancies between the experimental and theoretical particle size distributions (PSDs) and inconsistency with the kinetic constants associated with the two populations of particles. These differences are attributed to the influence of elastic coherency strains which have not been considered in conventional capillarity driven coarsening models.... 

Rene-80, as an alloy for production of the jet turbine blades, shows high mechanical properties as well as microstructure stability during the high temperature engine operation. In this study we tried to have a deep insight on the microstructure of the cast Rene-80 and the evolution of microstructure during the different stages of the relatively complex GE class-A heat treatment. Although the solution heat treatment homogenized the chemical alloy segregation resulted from the casting to some extent, it did not cause all the casting γ′ particles to dissolve completely in the matrix. Primary aging caused growth in the residue particles as well as growth of the new precipitated particles, which... 

The mechanical properties of Mg-4wt.% Zn alloy single crystals along the [0001] orientation were measured through micropillar compression at 23 °C and 100 °C. Basal slip was dominant in the solution treated alloy, while pyramidal slip occurred in the precipitation hardened alloy. Pyramidal dislocations pass the precipitates by forming Orowan loops, leading to homogeneous deformation and to a strong hardening. The predictions of the yield stress based on the Orowan model were in reasonable agreement with the experimental data. The presence of rod-shape precipitates perpendicular to the basal plane leads to a strong reduction in the plastic anisotropy of Mg. © 2020 Elsevier B.V  

The mechanical properties of Mg-4wt.% Zn alloy single crystals along the [0001] orientation were measured through micropillar compression at 23 °C and 100 °C. Basal slip was dominant in the solution treated alloy, while pyramidal slip occurred in the precipitation hardened alloy. Pyramidal dislocations pass the precipitates by forming Orowan loops, leading to homogeneous deformation and to a strong hardening. The predictions of the yield stress based on the Orowan model were in reasonable agreement with the experimental data. The presence of rod-shape precipitates perpendicular to the basal plane leads to a strong reduction in the plastic anisotropy of Mg. © 2020 Elsevier B.V  

Patterns formed by the flow of an inhomogeneous fluid (suspension) over a smooth inclined surface were studied. It was observed that fractal patterns are formed. There exists a threshold angle for the inclination above which global fractal patterns are formed. This angle depends on the particle size of the suspension. We observed that there are two fractal dimensions for these patterns, depending on the area from which the pattern is extracted. If the pattern is taken from the top which only consists of the beginning steps of the pattern forming, one finds two fractal dimensions, i.e. 1.35-1.45 and 1.6-1.7, in which the first one is dominant. And if the entire pattern is taken, then fractal... 

A deterministic model based on the discrete population balance equation (PBE) is used to examine the precipitation of barium sulfate nanoparticles in nonionic inverse microemulsion systems. It is shown that coagulation can have a significant effect at low initial reactants concentration. The simulation results show that a bimodal particle size distribution (PSD) observed in experimental analysis reported in the literature cannot be predicted by neglecting the coagulation effect. A coagulation kernel is proposed that takes into account the effect of interparticle forces through the Fuchs' stability ratio. The effect of electrolyte concentration on the surfactant headgroup area is also... 

Asphaltene precipitation problems manifest themselves in different stages of oil reservoirs production. Experimental and modeling investigations are, therefore, employed as promising tools to assist in predictions of asphaltene precipitation problems and selection of proper production facilities. This study concerns experimental and modeling investigations of asphaltene precipitation during natural production and gas injection operations for a heavy Iranian crude oil at reservoir conditions. First, with design and performance of high pressure-high temperature experiments, asphaltene precipitation behavior is comprehensively investigated; the effects of pressure and temperature are fully...